• The Journal of Engineering Research
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• v.3 no.1
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• pp.223-233
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• 1998

The kinetic and mechanism of the hydrothermal reaction between lime and quartz used solid state reaction equations have been investigated. Hydrothermal reaction on the starting materials was carried out in an autoclave that quartz mixed with calcium hydroxide in CaO/$SiO_2$ ratio of 0.8-1.0 for 0.5-8 hour at saturated steam pressure of $180-200^{\circ}C$. The rate of reaction was given from the ratio of uncombined lime and quartz content to the total lime and quartz content. The rate of reaction was obtained the results by the Jander's equation $[1-(1-\alpha)^{1/3}]^N=Kt$. The reaction of lime is controlled mainly by the dissolution such as N=1, and the reaction of quartz is controlled mostly by the diffusion such as $N\risingdotseq2$. The rate of hydrothermal reaction in the calcium silicate hydrates system is suggested to be determined generally by the mass transfer through the product laver formed around the reactant particles. The rate equation for whole hydrothermal reaction is shown that it is converted into the rate determining step by the diffusion from the boundary reaction such as approximately $N=1-2$.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.7
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• pp.529-536
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• 2020

Reaction Control System of the third stage of the Korean Space Launch Vehicle II conducts roll control and 3 axis control throughout third stage engine start, satellite separation, and collision and contamination avoidance maneuver. Reaction control system consumes its propellant in each thruster operation. Hence, loading of proper amount of the propellant is important for mission success. It is needed to have a rough estimation method of propellant consumption during the flight. In this paper, we developed a energy equation using pressure and temperature data which are acquired in the on-board reaction control system. We constructed a test system which is similar with the on-board reaction control system to verify the energy equation. Test results using deionized water were compared with estimated propellant consumption. We also conducted an error analysis of the energy equation. We also presented the propellant consumption result of a system level operation test.

• Journal of applied mathematics & informatics
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• v.22 no.1_2
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• pp.1-20
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• 2006

This paper presents the interior penalty discontinuous Galerkin finite element methods (DGFEM) for solving the rotating disk electrode problems in electrochemistry. We present results for the simple E reaction mechanism (convection-diffusion equations), the EC' reaction mechanism (reaction-convection-diffusion equation) and the ECE and $EC_2E$ reaction mechanisms (linear and nonlinear systems of reaction-convection-diffusion equations, respectively). All problems will be in one dimension.

• Journal of environmental and Sanitary engineering
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• v.17 no.1
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• pp.69-74
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• 2002

This study explored for treatment processes by investigating the treatment efficiency and reaction mechanism through oxidation reaction using UV and $O_3$ as oxidant in compensate the wastewater containing nitrobenzene that is non biodegradable organic. Also by modeling these reactions, we try to step explanation of optimum reaction rate and reaction mechanism as the development of the computer program predictable the reaction rate by modeling the reaction. By using this model, after kinetic constant for each reaction from an experimental data is made an optimization and for hardly contribute to reaction rate in reaction kinetic equation is made an ignorance and suppose the simplified reaction mechanism, examined the propriety of computer simulation model and simplified reaction mechanism by comparing and inspecting the reaction kinetic constant and masstransfer coefficient. An investigation results for destructional treatment of nitrobenzene in the wastewater as non-biddegradable organic using UV, $O_3{\;}O_2{\;}H_2O_2-UV$ as oxidant.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.7
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• pp.637-646
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• 2001

VOC(Volatile Organic Compound) removal characteristics in continuous flow reactors have been numerically investigated. The photocatalytic reaction have been simulated with the binding constant and the reaction rate constant obtained from experimental data for the constant-volume batch reactor, and then VOC abatement in continuous flow reactors with the same conditions as those of batch reactor has been analyzed. The standard 4\kappa-\varepsilon$ model and mass conservation equation have been employed for numerical calculation, and heterogeneous reaction rate has been used in terms of the boundary condition of the conservation equation. in the case of the continuous flow reactor, reaction characteristics have been estimated with various inlet velocities and with different number of baffles. The result shows that the concentration distribution and flow patterns are strongly affected by the inlet velocity, and that with the increased inlet velocity, VOC removal rate is increased, while removal efficiency is decreased. This result may be useful in the design of reactors with improved VOC removal efficiency.

• Journal of the Korean Chemical Society
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• v.61 no.1
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• pp.25-28
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• 2017

Solvolyses with the reaction center being the sulfur of 4-(chlorosulfonyl)biphenyl ($C_6H_5C_6H_4SO_2Cl$, 1) was studied under solvolytic conditions and the extended Grunwald-Winstein equation was applied. The thirty five kinds of solvents gave a reasonable extended Grunwald-Winstein plot with a correlation coefficient (R) of 0.940. The sensitivity values (l = 0.60 and m = 0.47) of 1 were smaller than those obtained for benzenesulfonyl chloride ($C_6H_5SO_2Cl$, 2; l = 1.10 and m = 0.61) proposed to undergo dissociative $S_N2$ mechanism. These l and m values for the solvolyses of 1 can be considered to support a $S_N2$ pathway with some ionization reaction. The activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$, were determined and they are also in line with values expected for a bimolecular reaction. The kinetic solvent isotope effect (KSIE) of 1.26 is also in accord with a bimolecular mechanism, probably assisted by general-base catalysis.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.155-163
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• 1999

A numerical study for simulating a swirling pulverized coal combustion in axisymmetric geometry is done here by applying the weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard ${\kappa}-{\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase for soot. The eddydissipation model is employed for the reaction rate for gaseous mixture, and the single-step first-order reaction model for the devolatilization process for coal. By comparing the numerical results with experimental ones, the models used here are confirmed and found to be one of good alternatives for simulating the combustion as well as radiative characteristics.

• Transactions of the Korean Society of Mechanical Engineers
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• v.1 no.4
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• pp.171-181
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• 1977

This paper is aiming at calculating NOx concentration, which is one of the harmhul components of emission from the gasoline engine, formed in the combustor through the presess of combustion. Instantaneous temperature and concentration of each components for each division can be determined by the solution of simulatneous equation of reaction equation and equation of energy conservation, inputting the estimated temperature with a considerably wide rage of temperature. After determining instantaneous temperature and instantanous concentration of each components, the nonequilibrium calculation is performed based on the reaction kinetics in order to determine NOx concentration. To summarize the result abtained from the above method ;through the passage of NO concentration, NO concentration is the highest in the first division and it is gradually decreasing through the following divisions In the final division, NO concentation is the lowest.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.757-761
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• 2008

The aerostat dynamic equation of motion has been built including the tether cable dynamic effects. A numerical program to solve the derived equation of motion has been developed. The dynamic motion of the 32m aerostat has been analyzed under discrete gust and continuous turbulence. The aerostat behaviors under discrete gust which represents a deterministic approach for determining design loads for manned aircraft are solved to verify the effect of aerostat mechanical properties on the aerostat dynamic behavior. Continuous turbulences are simulated for each given altitude, translational mean wind velocity and gust intensity. Dynamic behaviors of the 32m aerostat are simulated for each continuous turbulence conditions. Translational and vertical velocity and pitching behavior and tether reaction force are monitored for each simulation.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.1
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• pp.154-161
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• 1997

This paper presents the method to eliminate the constraint reaction in the Lagrange multiplier form equation of motion by using a generalized coordinate driveder from the velocity constraint equation. This method introduces a matrix method by considering the m dimensional space spanned by the rows of the constraint jacobian matrix. The orthogonal vectors defining the constraint manifold are projected to null vectors by the tangential vectors defined on the constraint manifold. Therefore the orthogonal projection matrix is defined by the tangential vectors. For correcting the generalized position coordinate, the optimization problem is formulated. And this correction process is analyzed by the quasi Newton method. Finally this method is verified through 3 dimensional vehicle model.