• 제목/요약/키워드: rate dependency

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Effect of Organo Nanoclay and Catalyst on the Polyesterification between Adipic Acid and Diethylene Glycol (Adipic Acid와 Diethylene Glycol의 Polyesterification에 대한 유기나노점토와 촉매의 영향)

  • Park, Kyung-Kyu;Shin, Sung-Wook;Oh, Min-Ji;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.37-44
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    • 2011
  • Effect of organo nanoclay (Cloisite 30B) on the polyesterification of adipic acid (AA) with diethylene glycol(DEG) was investigated with p-toluene sulfonic acid (p-TSA) (Br${\phi}$nsted acid) and butylchlorotin dihydroxide (Lewis acid) catalyst at 383 and 423 K. The initial [OH]/[COOH] molar ratio was two and the concentration of the catalysts in the reactants was 0.14 mol% based on the total reactants. The kinetics of the polyesterification was interpreted with the conversion data that was calculated from the acid values of the reactant-product mixture. The reaction rate of the polyesterification, which was catalyzed with p-TSA, exhibited the second-order dependency on AA concentration. When Butylchlorotin dihydroxide was used, the reaction rate revealed the first-order dependency on AA concentration. The activation energy of the reactions catalyzed with p-TSA and Butylchlorotin dihydroxide were calculated at 42.2 and 63.8 kJ/mol, respectively. Addition of 5 wt% Cloisite 30B to the reactant significantly diminished the activity of p-TSA, so the reaction rate decreased and the activation energy was calculated at 72.9 kJ/mol. Butylchlorotin dihydroxide catalyst maintained its activity regardless of the addition of Cloisite 30B to the reactant and the activation energy was calculated to 61.8 kJ/mol. Lewis acid catalyst, butylchlorotin dihydroxide, was more effective than Br${\phi}$nsted acid catalyst for the esterification of AA with DEG.

A Speech Translation System for Hotel Reservation (호텔예약을 위한 음성번역시스템)

  • 구명완;김재인;박상규;김우성;장두성;홍영국;장경애;김응인;강용범
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.4
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    • pp.24-31
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    • 1996
  • In this paper, we present a speech translation system for hotel reservation, KT_STS(Korea Telecom Speech Translation System). KT-STS is a speech-to-speech translation system which translates a spoken utterance in Korean into one in Japanese. The system has been designed around the task of hotel reservation(dialogues between a Korean customer and a hotel reservation de나 in Japan). It consists of a Korean speech recognition system, a Korean-to-Japanese machine translation system and a korean speech synthesis system. The Korean speech recognition system is an HMM(Hidden Markov model)-based speaker-independent, continuous speech recognizer which can recognize about 300 word vocabularies. Bigram language model is used as a forward language model and dependency grammar is used for a backward language model. For machine translation, we use dependency grammar and direct transfer method. And Korean speech synthesizer uses the demiphones as a synthesis unit and the method of periodic waveform analysis and reallocation. KT-STS runs in nearly real time on the SPARC20 workstation with one TMS320C30 DSP board. We have achieved the word recognition rate of 94. 68% and the sentence recognition rate of 82.42% after the speech recognition tests. On Korean-to-Japanese translation tests, we achieved translation success rate of 100%. We had an international joint experiment in which our system was connected with another system developed by KDD in Japan using the leased line.

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Detection of Privacy Information Leakage for Android Applications by Analyzing API Inter-Dependency and the Shortest Distance (API간 상호 의존성 및 최단거리 분석을 통한 안드로이드 애플리케이션의 개인정보 유출 탐지 기법)

  • Kim, Dorae;Park, Yongsu
    • Journal of KIISE
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    • v.41 no.9
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    • pp.707-714
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    • 2014
  • In general, the benign apps transmit privacy information to the external to provide service to users as the malicious app does. In other words, the behavior of benign apps is similar to the one of malicious apps. Thus, the benign app can be easily manipulated for malicious purposes. Therefore, the malicious apps as well as the benign apps should notify the users of the possibility of privacy information leakage before installation to prevent the potential malicious behavior. In this paper, We propose the method to detect leakage of privacy information on the android app by analyzing API inter-dependency and shortest distance. Also, we present LeakDroid which detects leakage of privacy information on Android with the above method. Unlike dynamic approaches, LeakDroid analyzes Android apps on market site. To verify the privacy information leakage detection of LeakDroid, we experimented the well-known 250 malicious apps and the 1700 benign apps collected from Android Third party market. Our evaluation result shows that LeakDroid reached detection rate of 96.4% in the malicious apps and detected 68 true privacy information leakages inside the 1700 benign apps.

Evaluation of Abrasive Wear Face Using SAW (표면탄성파를 이용한 마모 표면부의 평가)

  • Kwon, Sung-D.;Yoon, Seok-S.;Song, Sung-J.;Lee, Young-Z.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.2
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    • pp.193-197
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    • 2002
  • The frequency dependency of the Rayleigh surface wave was investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in the abrasion specimens, which was explained in view of the residual stress distribution. The peak intensity of the backward radiation profile decreased and the right half width of the profile increased with an increase of the variational rate of residual stress for the scuffing specimen. The peak intensity was also affected by the surface wave scattering during the propagation around the micro-damages. The peak angle might depend on not only the amount of residual stress but also the micro-structure. The result observed in this study demonstrates the high potential of the backward radiated ultrasound as a tool for the nondestructive evaluation of the subsurface gradients of materials.

Study for independence of hits in professional baseball games (프로야구 경기에서 안타의 독립성에 대한 연구)

  • Kim, Byungsoo;Park, Youngwook;Jang, Nayoung
    • Journal of the Korean Data and Information Science Society
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    • v.24 no.6
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    • pp.1421-1428
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    • 2013
  • In this paper, we would like to test whether the hit at a particular bat has a dependency with the hitting results at the previous bats in professional baseball games. For this purpose, we used the 2011 Korean Baseball League data. We find out that the hitting percentage at a particular bat has no dependency with the hit at the previous bat, after reviewing the conditional probability of hit at each bat and the lift. From the independence test of hits at consecutive bats, and hit at a particular bat with no hits at previous bats, we can conclude that hits at particular bats are not dependent on the hits at previous bats in most cases. Hence, we can safely conclude that a hit at a particular bat is statistically independent from the hits at the previous bats.

A Study on Taxi Drivers' Smoking Behavior, Self-efficacy and Expectation Level of Success in Smoking Cessation (택시기사들의 흡연실태 및 금연에 대한 자기효능감과 성공기대)

  • Son, Haeng-Mi;Kim, Chun-Mi
    • Research in Community and Public Health Nursing
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    • v.16 no.4
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    • pp.517-526
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    • 2005
  • Purpose: The purpose of this study is to find taxi drivers' smoking behavior, self-efficacy and expectation level of success in smoking cessation. It will provide useful information for developing nursing interventions in health promotion programs. Method: The subjects of this study were 271 taxi drivers in Seoul and its metropolitan area. Data were collected using a self-reported questionnaire asking smoking history, smoking behaviors, health problem, stages of change for smoking cessation, self-efficacy and the expectation level of success in smoking cessation. Data were analyzed through descriptive statistics. Pearson's correlation, Mann-Whitney U test, Kruskal-Wallis test and Cronbach's a. Results: Of the taxi drivers, 83.8% were current smokers. Stages of change were as follows: 45.8% were in the precontemplation stage, 26.2% in the contemplation stage, 13.7% in the maintenance stage, 12.2% in the preparation stage and 1.5% in the action stage. In addition. 20.3% of the subjects reported health problems such as hypertension, heart disease, diabetes mellitus and respiratory disease. The expectation level of success in smoking cessation was positively related with self-efficacy. There were statistically significant differences in the expectation level of success in smoking cessation according to the number of cigarettes per day and nicotine dependency. In addition. there were statistically significant differences in self-efficacy according to the number of cigarettes per day, duration of smoking (years) and nicotine dependency. Conclusion: The results of this study suggest that taxi drivers' health problems and smoking rate were serious. Therefore more systematic health promotion programs for smoking cessation should be developed and executed by health care specialists at individual taxi companies.

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Effect of Fiscal and Non-fiscal Variables on Regional Economy: The Case of 16 Wide-area Autonomous Communities in Korea (재정변수 및 비재정변수가 지역경제에 미치는 영향: 16개 시도를 중심으로)

  • Park, Wan Kyu;Kim, Du-Su
    • Journal of the Economic Geographical Society of Korea
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    • v.17 no.3
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    • pp.554-566
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    • 2014
  • This paper analyses the relationship between regional economic power defined as GRDP per capita and various socioeconomic variables such as fiscal variables(revenue, expenditure, etc.) as well as nonfiscal variables(population, ratio of old population, unemployment rate, dependency ration) using the pooling data of 16 local governments from 1998 to 2012. To put it concretely, following the Granger causality test, regression analysis has been done with the regional economic power being the dependent and variables which have either one or two direction causality being independent variables. And test of cumulative effects has been done with variables showing statistical significance in the regression analysis. Local tax revenues per capita, expenditures of social development per capita and median age have positive effects, while dependency ratio has negative effect on regional economy. And national subsidy per capita, local tax revenues per capita, expenditures of social development per capita and median age all have cumulative effects on regional economy.

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Study on Factors of Vacant Houses's Occurrence using Spatio-Temporal Model (시공간 종속성을 고려한 빈집발생 요인 추정에 관한 연구)

  • You-Hyun KIM;Donghyun KIM
    • Journal of the Korean Association of Geographic Information Studies
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    • v.26 no.2
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    • pp.20-41
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    • 2023
  • Recently, urban shrinkage due to low birth rate and aging population and the decline of local cities are causing a new urban problem of empty houses. This study examines the distribution of vacant homes using spatial panel data collected from 2015 to 2019 at local administraitve districts and estimates the factors of vacant house occurrence using a spatial panel model considering spatio-temporal dependency. As a result, the spatio-temporal dependence of vacant houses was identified and it was estimated using spatial panel model not OLS model. Based on the spatial panel model, it was found that the most influential factor in the occurrence of vacant houses was the housing-related factor. This result shows that policy considerations for housing supply are necessary for the management of vacant housing as well as population movement and poor infrastructure.

Loading Rate Effect on the Lateral Response of H-Shape Steel Column (재하속도가 H-형강 기둥부재의 횡방향 거동에 미치는 영향)

  • Park, Minseok;Kim, Chul-Young;Han, Jongwook;Chae, Yunbyeong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.6
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    • pp.637-644
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    • 2021
  • Dynamic response of structures can be evaluated experimentally by conducting cyclic loading tests. It has been known that steel materials are rate-dependent and the lateral response of a structure is significantly affected by the presence of axial force. However, the rate-dependency of steel column structures subjected to both axial and lateral loads has not been sufficiently studied yet due to the difficulty of controlling the axial force in a real-time manner during test. This study introduces an advanced way to apply the axial load in real-time to a column specimen using the adaptive time series (ATS) compensator and the flexible loading beam (FLB), where the H-shape steel columns made of SS275 are used for monotonic and cyclic loading tests with various loading rates with axial loads. The lateral strength and post-yield response of the steel columns are compared for each of monotonic and cyclic loading tests. The estimating equation of yield stress of various strain rate has proposed and finite element analysis were performed for comparison.

Rheological Properties of Rehydrated Suspensions of Freeze Dried Kochujang Powders (동결건조 분말고추장의 재수화시 리올로지 특성)

  • Kim, Suk-Shin;Chang, Kyu-Seob;Yoon, Han-Kyo;Lee, Sang-Kyu;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.81-88
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    • 1987
  • Rheological properties of rehydrated suspensions of two kinds of freeze dried Kochujang powders, processed at different freezing rates, were compared with raw Kochujang using Brookfield wide-gap rotational viscometer at $25^{\circ}C-60^{\circ}C$. Shear rates ranged from $0.1965\;sec^{-1}$ to $1.9650\;sec^{-1}$ and solid content ranged from 47% to 56%. Rehydrated suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang exhibited pseudoplastic behaviors with yield stress and presented thixotropic properties which followed the second-order kinetic behavior proposed by Tiu. Suspensions of Kochujang powders exhibited considerably higher decaying rates than raw Kochujang. The dependency of the equilibrium structure parameter on the shear rate was weak, and there were no significant differences among the values of structure parameters of three samples. The temperature dependency of the apparent viscosity of Kochujang suspension was fully expressed by Arrhenius equation and activation energies of suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang were 2.21, 2.18, and 2.32 Kcal/g.mole respectively. Consistency indices of three samples increased with solid content and decreased with temperature. Flow behavior indices of three samples showed no considerable dependency on the temperature and solid content. There were no significant differences in the rheological properties between two Kochujang powders.

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