• Title/Summary/Keyword: rate constant(k)

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Consolidation Characteristics at the Constant Rate of Strain(CRS) Test (일정변형률(CRS) 시험에서의 압밀특성)

  • Lee, Dal-Won;Kim, Si-Jung
    • Korean Journal of Agricultural Science
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    • v.37 no.3
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    • pp.491-499
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    • 2010
  • This study was carried out to investigate the consolidation characteristics of the remolded clay by the oedometer and the constant rate of strain(CRS) consolidation tests. As the rate of strain increases, the settlement rapidly decreased. As the ratio of the sand in the specimen increases, its effect on the rate of strain to the settlement was reduced. As the effective stress increased, the void ratio decreased, while the rate of strain increased, it did not show a clear variation. The reduction of the void ratio was shown to be less than the oedometer test. The coefficient of vertical consolidation with effective stress showed very large variation around preconsolidation stress, but the rate of strain did not provide significant effects. The rate of strain with effective stress gradually decreased at all tests and mixed ratio of sand. The rate of strain at the constant rate of strain tests showed smaller than in the oedometer test. The coefficient of consolidation at the constant rate of strain tests showed much more increase than in the oedometer test. The ratio of the vertical coefficient of consolidation by the odometer and the constant rate of strain tests showed a large difference according to various tests method and mixing ratio. Therefore, it is recommended that careful attention should be paid to designing the soft ground improvement.

Estimation of Source Strength and Deposition Constant of Nitrogen Dioxide Using Compartment Model (구획모델을 이용한 주택에서 이산화질소의 발생강도 및 감소상수 동시 추정)

  • Yang Won-Ho;Son Bu-Soon;Sohn Jong-Ryeul
    • Journal of Environmental Health Sciences
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    • v.31 no.4 s.85
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    • pp.260-265
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    • 2005
  • Indoor air quality might be affected by source strength of indoor pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate the source strength and deposition constant by application of multiple measurements. For the total duration of 60 days, indoor and outdoor $NO_2$ concentrations every 3 days were measured in 30 houses in Seoul, Asan and Daegu. Using a compartment model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated. Subsequently, the source strength and deposition constant were estimated. Natural ventilation was $1.80{\pm}0.42\;ACH,\;1.11{\pm}0.50\;ACH,\;0.92{\pm}0.26\;ACH$ in Seoul, Asan and Daegu, respectively. Calculated deposition constant(K) and source strength of $NO_2,$ in this study were $0.98{\pm}0.28\;hr^{1}\;and\;16.28{\pm}7.47\;ppb/h,$ respectively.

Effect of acoustic wave on the evaporation/combustion of suspended droplet (음파가 고정액적의 증발/연소에 미치는 영향에 관한 연구)

  • Han, Jae-Seob;Kim, Seon-Jin;Kim, Yoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.6 no.3
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    • pp.53-60
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    • 2002
  • This paper presents the results of the experimental investigation on the effect of acoustic wave on the combustion of suspended A-1 jet fuel droplets in atmospheric pressure. Experimental results indicate that A-1 jet fuel droplet burning rate constants $k_c$ were independent of initial droplet size and the relative evaporation/burning-rate constant $k_{e'}k_c$(ratio of the acoustically disturbed evaporation/burning-rate constant to the undisturbed evaporation/burning-rate constant) increased remarkably 1.2~1.51times, 1.04~1.42times, for frequency below 100Hz, and sound pressure level above 80dB.

Study on the Design of Contraceptive Agent(I) (피임제(避妊劑) 제형(製型) 개발(開發)에 관(關)한 연구(硏究)(I))

  • Kim, S.H.;Choi, J.S.;Baik, C.S.
    • Journal of Pharmaceutical Investigation
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    • v.11 no.3
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    • pp.14-20
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    • 1981
  • One of the major objectives in the developments of a progesterone I.U.D. is to prepare devices which release drug at a constant rate for extended periods. A constant release rate is achived by maintaining drug concentration at a constant valve via the introduction of rate limiting membrane to solute diffusion at the surface of the devices. In this study, progesterone dispersed at monolithic device were prepared from polyhydroxy ethyl methacrylate. Constant release rate were obtained with device which were soaked in on ethanol-hexan solution. The release rate was dependant upon the concentration of the ethanolic solution in the soaking solution. This devices offer significant potential for futher development of hydrogel in the intrauterine contraception device for controlled release of progesterone.

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A Modified Fractional Step Method of Keeping a Constant Mass Flow Rate in Fully Developed Channel and Pipe Flows

  • You, Jong-Woo;Choi, Hae-Cheon;Yoo, Jung-Yul
    • Journal of Mechanical Science and Technology
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    • v.14 no.5
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    • pp.547-552
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    • 2000
  • The objective of this paper is to present a modified fractional step method of keeping a constant mass flow rate in spatially periodic flows, because original fractional step methods do not precisely keep the mass flow rate constant in time. In the modified method, the mean and fluctuating pseudo-pressure gradients are separately obtained at each time step. This method is successfully applied to channel and pipe flows and shown to be suitable for maintaining a constant mass flow rate in time.

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Stabilizing Effect of Ginseng Saponin and Water Extract on Malate Dehydrogenase from Pigeon Breast Muscle (인삼사포닌 및 인삼수용성 추출물이 비둘기 가슴근육으로부터 분리된 Malate Dehydrogenase에 미치는 안정화효과)

  • Kim, Du-Ha;Sin, Mun-Hui;Hong, Sun-Geun
    • Journal of Ginseng Research
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    • v.7 no.1
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    • pp.88-93
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    • 1983
  • Studies were carried out to elucidate the protein stabilizing effect of ginseng. Malate dehydrogenase (EC 1.1.1.37) was used as a protein and the rate constant of the enzyme inactivation was determined under the heat denaturation condition. There was an optimum pH for the enzyme stability, the rate constant of the enzyme inactivation was minimum at BH 8.8. The rate constant was increased at lower and higher pH regions than the optimum pH. The inactivation reaction followed the Arrehnius law and the activation energy was measured as 36.8kcal/mole. The reaction rate was not affected by the enzyme concentration and thus it was assumed to be unimolecular first order reaction. The water extract of red ginseng decreased the rate constant of Malate dehydrogenate under heat inactivation condition to stabilize the enzyme activity. Purified ginseng saponin also stabilized the enzyme against heat inactivation.

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Prediction of the Constant Water Inflow Rate in a tunnel using Takahashi문s method (Takahashi의 수문학적 기법을 이용한 터널내의 항상 용수량의 예측)

  • Lim, Goo; Kim, Dal-Sun;Yoon, Ji-Sun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.181-188
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    • 2002
  • Water flow rate into the tunnel usually determined by numerical analyses and mathematical formulas using water levels and permeability is obtained only a few limited districts of the whole tunneling site. However, underground is not a homogeneous but complicated mass. Therefore these methods can't reflect structural and geological aspects. In this study, assuming that the mountain stream in droughty season is to be the same as baseflow of its basin, hydrological method is applied to predict the constant water flow rate into the tunnel on construction field. Prediction of constant water inflow rate is performed on each section of tunnel construction field divided into 20 sections.

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Theoretical Calculation of Parabolic Rate Constant for High-Temperature Oxidation of Metals (금속의 고온 산화동안 포물선 속도상수의 이론적 계산)

  • Kim, Insoo;Cho, Weol Dong
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.5
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    • pp.282-285
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    • 2001
  • Based on the mass balance of anion and cation fluxes, the parabolic rate constant ($K_p$) of oxide grown during the high-temperature oxidation of metal is theoretically calculated. It is assumed that the diffusion of oxygen anion and metal cation through oxide scale obeys the Fick's 1st law, the growth of oxide is controlled by the diffusion of ions, electrical potential gradient as driving force for diffusion of ions is ignored, and oxidation occurs within an existing oxide layer. Then, the parabolic rate constant can be expressed by $K_p=[2{\rho}_{MmOn}{M^2}_{MmOn}(mD_oC_o{^e}+nD_MC_M{^e})/nm]$.

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Evaporation Rate of Lead in Molten Copper Alloy by Gas Injection (가스취입에 의한 용융 동 합금 중 납의 증발속도)

  • Kim, Hang-Su;Jeong, Seong-Yeop;Jeong, U-Gwang;Yun, Ui-Han;Son, Ho-Sang
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.68-74
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    • 2002
  • The lead has to be removed for the recycling of copper alloy. The lead cannot be removed from the copper alloy by oxidation. It can be removed by the evaporation because of its high vapor pressure. However, rare information is found on removal of lead from copper alloy. The purpose of present work is to provide a fundamental knowledges on the removal of lead from the copper alloy by evaporation. Gas injection was made in molten copper alloy, and the evaporation rate of lead was measured. The influence of Ar gas flow rata(2~4 L/min), initial contents of lead(2~4wt%Pb), temperature(1200~140$0^{\circ}C$) was investigated based on the thermodynamic and the kinetics. The rate constant is increased with increasing flow rate of Ar and temperature. Though amount of lead removed is increased with higher initial lead concentration, the rate constant is not changed significantly. The activation energy is estimated from the temperature dependence of the rate constant. Also removal of lead from the copper by adding chloride was made for the comparison.

Estimating Diffusion-Controlled Reaction Parameters in Photoinitiated Polymerization of Dimethacrylate Macromonomers

  • Choe, Youngson
    • Macromolecular Research
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    • v.11 no.5
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    • pp.311-316
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    • 2003
  • The kinetics of photoinitiated polymerization of dimethacrylate macromonomers have been studied to determine the diffusion-controlled reaction parameters using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). A predicted kinetic rate expression with a diffusion control factor was employed to estimate an effective rate constant and to define the reaction-controlled and diffusion-controlled regimes in the photopolymerization. An effective rate constant, k$_{e}$, can be obtained from the predicted kinetic rate expression. At the earlier stages of polymerization, the average values of kinetic rate constants do not vary during the reaction time. As the reaction conversion, $\alpha$, reaches the critical conversion, $\alpha$$_{c}$, in the predicted kinetic expression, the reaction becomes to be controlled by diffusion due to the restricted mobility of dimethacrylate macromonomers. A drop in value of effective rate constant causes a drastic decrease of reaction rate at the later stages of polymerization. By determining the effective rate constants, the reaction-controlled and diffusion-controlled regimes were properly defined even in the photopolymerization reaction system.m.m.