• 제목/요약/키워드: rate constant(k)

검색결과 3,147건 처리시간 0.031초

Zinc-ferrite의 용해 속도론에 미치는 황산 용액의 온도와 농도의 영향 (Effect of Solution Temperature and Bath Concentration on the Kinetics with Dissolution Reaction of Zinc-Ferrite)

  • 오이식;김천조
    • 자원리싸이클링
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    • 제12권4호
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    • pp.30-37
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    • 2003
  • 황산 용액에서 Zinc-ferrite의 용해에 대한 반응속도론을 황산 용액의 반응온도와 농도 변화에 대해 조사하였다. 반응율(R)과 겉보기 반응 속도상수(K)는 황산 용액의 온도와 농도가 클수록 증가한다. Zinc-ferrite의 반응속도는 반응초기에서 $1-(1-K)^{1/3}=Kt$와 같은 속도식을 적용할 수 있다. 용해에 대한 활성화 에너지는 황산 용액의 농도에 관계없이 약 16.3kcal/mole 이다. Zinc-ferrite가 황산 용액에서 용해할 때는 Zinc-ferrite의 화학 양론적 조성으로 용해되며, Fe 또는 Zn의 단독으로는 용해되지 않는다.

상수형 고장률 관리도 (Control Chart for Constant Hazard Rate)

  • 이재만;차영준;홍연웅
    • Journal of the Korean Data and Information Science Society
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    • 제10권2호
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    • pp.437-444
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    • 1999
  • 상수형 고장률을 갖는 시스템에 대하여 일정한 구간별로 비복원(복원)으로 시스템의 고장여부를 관찰하여 얻은 수명자료를 이용한 시스템 고장률 관리도를 제안하고 OC곡선(operating-characteristic curve)을 이용하여 제안된 관리도의 성능을 고찰하였다.

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Evaluations of vital signs and echocardiographic left ventricular function after the constant rate infusion of lidocaine and/or ketamine in Beagle dogs

  • Kim, Ye-Won;Choi, Miru;Kim, Tae-Jun;Hyun, Changbaig
    • 대한수의학회지
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    • 제55권4호
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    • pp.215-219
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    • 2015
  • Cardiopulmonary depression of long-term constant rate infusion (CRI) administration of multiple analgesic drugs is important, especially in critically ill dogs. Therefore, this study was conducted to evaluate the effects of lidocaine, ketamine or combined lidocaine-ketamine combination CRI treatment on vital signs and left ventricular (LV) function in healthy dogs. Six adult Beagle dogs were administered either ketamine (initial loading dose of 0.5 mg/kg followed by $10{\mu}g/kg/min$ CRI), lidocaine (initial loading dose of 2 mg/kg followed by 0.025 mg/kg/min CRI), or combined lidocaine-ketamine intravenously. Arterial blood pressure (BP), heart rate (HR), respiratory rate (RR), body temperature (BT) and echocardiographic LV dimensions were measured before administration of medications, immediately after administration of drugs, and then every 10 min for 2 h. There were no significant changes in HR, RR, BT and BP after the administration of either lidocaine CRI, ketamine CRI, or combined lidocaine and ketamine CRI. There were also no significant changes in LV dimensions and stroke volume. The results revealed that treatment with either lidocaine, ketamine or combined lidocaine-ketamine may not cause cardiopulmonary suppression in healthy dogs.

복합형 냉풍건조기 실험에 대한 검토 (Study in the Mixed Cooling Dryer Experiment)

  • 최진영;김세환;박승태;이정호
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.254-259
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    • 2009
  • The mixed cooling dryer has been developed significantly by adopting both advantages of cooling dryers and desiccant dryers. In this study, it is introduced that the desired effect, such as drying rate period reduction and energy-saving, could be achieved only by adding the desiccant dryer if an existing cooling dryer is used. The experiment should be conducted for quite long time due to the material selection, so it is regrettable that there are not enough data.

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에탄올과 Sulfamethazine의 약물상호작용 (Drug Interaction of Sulfamethazine and Ethanol)

  • 최준식;전종철;이진환;유영종
    • Journal of Pharmaceutical Investigation
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    • 제16권1호
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    • pp.31-35
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    • 1986
  • Effect of ethanol on the absorption rate, blood level and bioavailability of sulfamethazine (SM) in rats was determined. Absorption rate of SM was determined both by the in vitro and in situ experiment. In vitro, absorption rate of SM in rat small intestine was increased by 0.3, 1.0 and 3.0% ethanol. In situ, absorption rate of SM was increased by 0.3 and 1.0% ethanol but not by 3.0% ethanol. After oral administration, blood level of SM was elevated and relative bioavailability was significantly increased to 114.8% at the dose of 0.6g/kg ethanol but not significantly at the dose of 3.0g/kg ethanol. The time for attainment of peak blood level was changed from 2.5 to 1.5hr. Ethanol enhanced absorption rate constant of SM significantly and reduced elimination rate constant of SM administered orally at the dose of 0.6g/kg ethanol.

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균열닫힘현상을 고려한 피로균열전파식 (Fatigue Crack Growth Rate Equation by Crack Closure)

  • 김용수;강동명;신근하
    • 한국안전학회지
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    • 제6권4호
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    • pp.81-87
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    • 1991
  • We propose the crack growth rate equation which will model fatigue crack growth rate behavior such that constant stress amplitude fatigue crack growth behavior can be predicted. Constant stress amplitude fatigue tests are conducted for four materials under three stress ratios of R=0.2, R=0.4 and R=0.6. Materials which have different mechanical properties i.e. stainless steel, low carbon steel, medium carbon steel and aluminum alloy are used. Through constant stress amplitude fatigue test by using unloading elastic compliance method, it is confirmed that crack closure is a close relationship with fatigue crack propagation. We describe simply fatigue crack propagation behavior as a function of the effective stress intensity factor range ($\Delta$ $K_{eff}$=U .$\Delta$K) for all three regions (threshold region, stable region). The fatigue crack growth rate equation is given by da / dN=A($\Delta$ $K_{eff}$­$\Delta$ $K_{o}$ )$^{m}$ / ($\Delta$ $K_{eff}$­$\Delta$K) Where, A and m are material constants, and $\Delta$ $K_{o}$ is stress intensity factor range at low $\Delta$K region. $K_{cf}$ is critical fatigue stress intensity factor.actor.

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The Decomposition of Leaf Litters of Some Tree Species in Temperate Deciduous Forest in Korea I. Losses in Dry Weight of Leaf Litter

  • Yang, Keum-Chul;Shim, Jae-Kuk
    • The Korean Journal of Ecology
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    • 제26권4호
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    • pp.203-208
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    • 2003
  • Losses in the dry weight of leaf litter from six tree species were studied during 16 months on the forest floor in temperate deciduous forest of Mt. Cheonma in the vicinity of Seoul in Korea by using litter bag method. The decomposition rate of each leaf litter varies with each species. After 16 months elapsed, the leaf litter of Acer pseudo-sieboidianum showed the highest decomposition constant (0.82) as Olson´s decomposition constant, while that of Pinus densiflora showed the lowest decomposition constant (0.33). The decomposition constant of Quercus mongolica, Q. serrata, Betula ermani and Carpinus laxiflora showed 0.43, 0.37, 0.66 and 0.75, respectively. The decomposition constant of leaf litter was considered with temperature and precipitation which accumulated daily during each term of litter bag collection. The decomposition constant of leaf litter showed closely positive correlation with daily accumulative temperature and precipitation. The relationships between decomposition constant and the daily accumulative temperature and precipitation at each period of litter bag collection were analyzed through multi-regression analysis. The correlation coefficients as a result of multi-regression analysis in Q. mongolica, Q. serrata, P densiflora, B. ermani, C. laxiflorais and A. pseudo-sieboldianum were 0.83, 0.81, 0.69, 0.77, 0.77 and 0.62, respectively. The precipitation showed higher effect, about 10 times, on the leaf litter decomposition than the daily accumulative temperature.

Predicting the Methane Gas Generation Rate at Landfill Sites Using the Methane Gas Generation Rate Constant (k)

  • Chung, Jin-Do;Kim, Jung-Tae
    • Asian Journal of Atmospheric Environment
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    • 제2권2호
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    • pp.116-124
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    • 2008
  • In this study, the Tier 2 method recommended by the Intergovernmental Panel on Climate Change (IPCC) was used to predict the methane generation rate at two landfill sites, designated as Y and C for purposes of this study, in South Korea. Factors such as the average annual waste disposal, methane emissions ($L_0$) and methane gas generation rate constant (k) were estimated by analyses of waste and the historical data for the landfills. The value of k was estimated by field experiments and then the changes in the methane generation rate were predicted through the year 2050, based on the value of k. The Y landfill site, which was in operation until the year 2008, will generate a total of 17, 198.7 tons by the end of 2018, according to our estimations. At the C landfill site, which will not be closed until the end of 2011, the amount of methane gas generated in 2011 will be 3,316 tons and the total amount of gas generated by 2029 will be 61,200 tons. The total production rate of methane gas at the C landfill is higher than that of the Y landfill. This indicates that the capacity of a landfill site affects the production rate of methane gas. However, the interrelation between the generation rate of methane and the value of k is weak. In addition, the generation of methane gas does not cease even when the operations at a landfill site come to a close and the methane gas production rate is at its highest at end of the operating life of a landfill site.

Optimal Criterion for the Scale-Up Production of Schizophyllan in the Stirred Tank Reactor

  • KWAK, JUNG-KI;KOO, JAE-GUEN;PARK, SUNG-WOO;CHO, MAN-GI;KANG, BYEONG-CHUL;RAINER BUCHHOLZ;PETER GOETZ
    • Journal of Microbiology and Biotechnology
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    • 제15권1호
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    • pp.1-6
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    • 2005
  • Optimal criterion for the scale-up production of schizophyllan, a fungal polysaccharide secreted by Schizophyllum commune, was investigated. For the production of the polysaccharide in a 150-l bioreactor, the culture conditions optimized in a 15-l bioreactor were applied to a 150-l bioreactor with scale-up process, by changing impeller speed and airflow rate. The optimized impeller speed in the 15-l bioreactor was 50 rpm in a technical medium based on barley. For establishment of the scale-up process, 3 kinds of criteria were used while the gas throughput number was kept constant, as follows; constant volume-related power input, constant tip speed of stirrer, and constant Reynolds number. In the 150-l bioreactor, the highest values for the maximum specific growth rate (1.17/day) and productivity (0.63 g/L${\cdot}$day) were achieved in the culture condition from constant volumerelated power input criterion.

Changes in Pressure-Flow Control Characteristics of Shunt Valves by Intracranial Pressure Pulsation: an In Vitro Study

  • Lee, Chong-Sun;Kim, Joo-Young
    • 대한의용생체공학회:의공학회지
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    • 제26권4호
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    • pp.193-197
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    • 2005
  • Shunt valves used to treat patients with hydrocephalus were tested to investigate influence of intracranial pressure pulsation on their flow control characteristics. Five commercial shunt valves were tested in the flow loop that simulates pulsed flow under pressure pulsation. As 20cc/hr of flow rate was adjusted at a constant pressure, application of $40mmH_2O$ of pressure pulse increased the flow rate by $67.9\%.$ As a 90cm length catheter was connected to the valve outlet, increase in the flow rate was substantially reduced to $17.5\%.$ As the flow rate was adjusted to 40cc/hr at a constant pressure, increase in the flow rate was $51.1\%$ with the same pressure pulsation of $40mmH_2O$. The results indicated that pressure-flow control characteristics of shunt valves implanted above human brain ventricle is quite different from those obtained by syringe pump test at constant pressures right after manufacture. The influence of pressure pulsation was observed to be more significant at low flow rate and the flexibility of the outlet silicone catheter was estimated to significantly reduce flow increase due to pressure pulsation.