• 제목/요약/키워드: rapid solidification

검색결과 180건 처리시간 0.025초

레이저 빔을 이용한 철계 급랭 응고 재료의 표면 합금화 (Surface Alloying of Iron Base Rapid Solidification Materials Using Laser Beam)

  • 남기석;이구현
    • 열처리공학회지
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    • 제9권4호
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    • pp.229-233
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    • 1996
  • This work has been carried out to reduce the softening of heat affected zone on laser surface alloying. Iron based rapid solidification material with $Cr_{5-10}$, $V_{1-3}$, $Mo_{3-7}$, $W_{2-5}$, $B_{7-8}$, $C_{2-3}$, $Si_{0.5-1}at%$ was alloyed on the surface of SM45C steel. The excellent softening resistance in alloyed and heat affected zone showed, which could be attributed to the formation of stable high temperature precipitates.

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급속응고기술에 의한 n-type 90%$Bi_{2}Te_{3}+10% Bi_{2}Se_{3}$ 열간압축제의 열전특성 (Thermoelectric Properties of n-type 90%$Bi_{2}Te_{3}+10% Bi_{2}Se_{3}$ Materials Prepared by Rapid Solidification Process and Hot Pressing)

  • 김익수
    • 한국분말재료학회지
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    • 제3권4호
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    • pp.253-259
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    • 1996
  • The efficiency of thermoelectric devices for different applications is known to depend on the thermoelectric effectiveness of the material which tends to grow with the increase of its chemical homogeneity. Thus an important goal for thermal devices is to obtain chemically homogeneous solid solutions. In this work, the new process with rapid solidification (melt spinning method) followed by hot pressing was investigated to produce homogeneous material. Characteristics of the material were examined with HRD, SEM, EPMA-line scan and bending test. Property variations of the materials were investigated as a function of variables, such as dopant ${CdCl}_{2}$ quantity and hot pressing temperature. Quenched ribbons are very brittle and consist of homogeneous $Bi_2Te_3$, ${Bi}_{2}{Se}_{3}$ solid solutions. When the process parameters were optimized, the maximum figure of merit was 2.038$\times$$10^{-3}K^{-4}. The bending strength of the material hot pressed at 50$0^{\circ}C$ was 8.2 kgf/${mm}^2$.

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급속응고한 Ag-Sn-In 미세조직에 미치는 Sn 함량 변화의 영향 (The Effect of the Sn Amounts on the Microstructure of Rapidly Solidified Ag-Sn-In Alloys)

  • 조대형;권기봉;남태운
    • 한국주조공학회지
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    • 제26권2호
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    • pp.92-97
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    • 2006
  • Contact material is widely used as electrical parts. Ag-Cd alloy has a good wear resistance and stable contact resistance. But the disadvantages of Ag-Cd alloy are coarse Cd oxides and harmful metal, Cd. To solve the disadvantages of that, Ag-Sn alloy that has stable and fine Sn oxide at high temperature has been developed. In order to optimize Sn amount that affects the formation of the oxide layer on the surface, we worked for the microstructures and properties of Ag-Sn material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. We have shown that the optimized Sn amount for high hardness is 7.09 wt%Sn. Surface oxide layer forms when Sn amount is over 9.45 wt%. The size of Sn oxide is 20 nm.

강제교반법으로 제조된 Al-Pb계 베어링 합금의 마모특성 (Wear properties of Al-Pb alloys produced by a forced stirring method)

  • 임화영;허무영;임대순
    • Tribology and Lubricants
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    • 제8권1호
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    • pp.70-77
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    • 1992
  • Al-Pb-Si bearing alloys were produced by a forced stirring method and a rapid solidification process to study wear properties of bearing alloys. A homogeneous distribution of Pb particles in Al matrix could be obtained by means of the forced stirring and the rapid cooling during the casting. The wear properties of bearing alloys were tested by a pin-on-disc wear tester. The change in microstructure according to the alloy manufacturing variables was observed by the backscattered electron images. Al-Pb and Al-Si binary alloys showed a transition from mild to severe wear. The transition was not found in Al-Pb-Si ternary alloys. It could be concluded that the lubricatioin effect of Pb and the strengthening effect of Si in the ternary alloys enhanced the bearing properties. A Al-25%Pb-13%Si alloy showed the lowest coefficient of friction in this experiment. It indicated that the optimum concentration of alloy was 25% Pb and 13% Si when the forced stirring of melt and water-cooled-copper-mold solidification were adopted.

급속응고법으로 제조한 과공정 Al-Si합금분말 압출재의 마멸특성 (Wear Characteristics of the Extruded Bars of Hypereutectic Al-Si Alloy Powders produced by Rapid Solidification Process)

  • 안영남;조규섭;나형용
    • 한국주조공학회지
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    • 제14권5호
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    • pp.447-454
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    • 1994
  • Wear resistance and wear mechanism of hypereutectic Al-($15{\sim}40$)wt%Si alloys were investigated. Primary Si particles under $20{\mu}m$ size were formed in hypereutectic Al-Si alloy powders due to rapid solidification. But the Si particles of extruded bars were finely distributed in smaller size than that of atomized powders. The wear mechanism of hypereutectic Al-Si alloys was divided into three types of wear phenomena, which were abrasive wear, delamination wear and severe adhesive wear according to sliding speed and load. At low sliding speed and load, wear mechanism was abrasive wear, so Al-15wt%Si alloy showed the best wear resistance. At high sliding speed and load, wear mechanism was adhesive wear, and Al-40wt%Si alloy showed the best wear resistance.

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Facile synthesis of nanostructured n-type SiGe alloys with enhanced thermoelectric performance using rapid solidification employing melt spinning followed by spark plasma sintering

  • Vishwakarma, Avinash;Bathula, Sivaiah;Chauhan, Nagendra S.;Bhardwaj, Ruchi;Gahtori, Bhasker;Srivastava, Avanish K.;Dhar, Ajay
    • Current Applied Physics
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    • 제18권12호
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    • pp.1540-1545
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    • 2018
  • SiGe alloy is widely used thermoelectric materials for high temperature thermoelectric generator applications. However, its high thermoelectric performance has been thus far realized only in alloys synthesized employing mechanical alloying techniques, which are time-consuming and employ several materials processing steps. In the current study, for the first time, we report an enhanced thermoelectric figure-of-merit (ZT) ~ 1.1 at $900^{\circ}C$ in ntype $Si_{80}Ge_{20}$ nano-alloys, synthesized using a facile and up-scalable methodology consisting of rapid solidification at high optimized cooling rate ${\sim}3.4{\times}10^7K/s$, employing melt spinning followed by spark plasma sintering of the resulting nano-crystalline melt-spun ribbons. This enhancement in ZT > 20% over its bulk counterpart, owes its origin to the nano-crystalline microstructure formed at high cooling rates, which results in crystallite size ~7 nm leading to high density of grain boundaries, which scatter heat-carrying phonons. This abundant scattering resulted in a very low thermal conductivity ${\sim}2.1Wm^{-1}K^{-1}$, which corresponds to ~50% reduction over its bulk counterpart and is amongst the lowest reported thus far in n-type SiGe alloys. The synthesized samples were characterized using X-ray diffraction, scanning electron microscopy and transmission electron microscopy, based on which the enhancement in their thermoelectric performance has been discussed.