• Title/Summary/Keyword: radioactive metal

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A Study on the Application of Standards for Clearance of Metal Waste Generated During the Decommissioning of NPP by Using the RESRAD-RECYCLE (RESRAD-RECYCLE을 활용한 원전 해체 시 발생하는 금속폐기물의 자체처분 기준 적용 연구)

  • Song, Jong Soon;Kim, Dong Min;Lee, Sang Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.4
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    • pp.305-320
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    • 2016
  • The metal waste generated during nuclear power plant decommissioning constitutes a large proportion of the total radioactive waste. This study investigates the current status of domestic and international regulatory requirements for clearance and the clearance experience of domestic institutions. The RESRAD-RECYCLE code was used for analyzing the clearance of the metal wastes generated during actual nuclear power plant decommissioning, and assessment of the exposure dose of twenty-six scenarios was carried out. The evaluation results will be useful in preliminary analysis of clearance and recycling during nuclear power plant decommissioning. As a next step, the effects of reducing disposal costs by clearance can be studied.

Leaching Characteristic Analysis of Cement Solidified Radioactive Waste Attached by Yellow Sand Rain (황사빗물의 영향에 의한 방사성 폐기물 시멘트 고화체의 침출특성 분석)

  • 김혜진;이수홍;황주호;이재민
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.244-250
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    • 2003
  • With a recent public concern rising on the radioactive waste, it is disclosed that the problem is more serious than expected. This research has been conducted to find effects of yellow sandy rainwaters on the solidified cement of mid-and-low level radioactive waste. The ANS 16.1 standard test method was chosen for this leaching experiment. Make a cement solidified radioactive waste that contains Co nuclide, and fabricate it for over 28 days. Then, decide on the volume of leaching water and the concentration of ion and metal in leachate from the mass concentration of yellow sands in atmosphere. In this paper, we have taken a short look at characteristics of yellow sand. Before going into the leaching experiment, we decided experimental conditions first. Then, it was evaluated and analyzed how sandy rainfalls have impact on the cement solidified radioactive waste based on data from 90 days of leaching experiment.

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Recovery of Silver from the Spent Solution Generated from Electrochemical Oxidation of Radioactive Wastes (放射性 폐기물의 전기화학적 분해 폐액으로부터 銀의 回收)

  • 문제권;정종훈;오원진;이일희
    • Resources Recycling
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    • v.10 no.5
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    • pp.22-28
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    • 2001
  • Recovery of silver in the spent solution generated from MEO(Mediated Electrochemical Oxidation) process, which is a process to decompose radioactive organic mixed wastes at low temperature, was performed using chemical method. Silver nitrate in 5M nitric acid solution could be completely recovered as AgCl by using 1% excess of the stoichiometric HCl equivalents. Then, AgCl was transformed to Ag metal by reduction reaction with hydrogen peroxide under alkaline media. The optimum pH for the reduction to silver metal was found to be in the range of 12.8∼13.0.

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Chemical Effects of Nuclear Transformations in Metal Permanganates (금속 과망간산염의 핵변환에 의한 화학적 효과)

  • Lee, Byung-Hun;Kim, Bong-Whan
    • Journal of Radiation Protection and Research
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    • v.11 no.1
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    • pp.15-21
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    • 1986
  • The chemical effects resulting from the capture of the thermal neutrons by manganese in different crystalline permanganates, that is, potassium permanganate, sodium permanganate, silver permanganate, barium permanganate and ammonium permanganate, have been investigated. The distribution of radioactive manganese formed has been determined by using different absorbents and ion-exchangers, that is, manganese dioxide, alumina, Zeolite A-3, Kaolinite and Dowex-50. The distribution of radioactive manganese in various adsorbents and ion-exchangers has almost similar result for each permanganate. The affinity for radioactive manganous ion is greatest for Dewex-50. A significant increase of retention is shown through the thermal annealing and the retention depends on the first ionization potential of metal ion in permanganates.

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Development Status for Commercialization of Spent Nuclear Fuel Transportation and Dry Storage System Technology (사용후핵연료 수송/저장시스템 상용화 기술개발 경과)

  • Baeg, Chang-Yeal;Cho, Chun-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.271-279
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    • 2018
  • During the seven years from 2009 to 2016, PWR SNF (spent nuclear fuel) transportation and storage systems suitable for domestic conditions were developed by the government to cope with the saturation of wet storage capacity in NPPs. One of the developed systems is a multipurpose metal cask applicable for transportation/storage; the other is a concrete cask dedicated to storage. Efficient cask technologies were secured utilizing the characteristics and experience of relevant industrial, academic and research institutes. Technological independence was also achieved through several patent registrations of research outcomes. To prepare for a rapid increase of demand in the near future, technology transfer of secured patents and technologies to the domestic industry was carried out twice in the years of 2016 and 2017.

THE PERFORMANCE OF CLAY BARRIERS IN REPOSITORIES FOR HIGH-LEVEL RADIOACTIVE WASTE

  • Pusch, Roland
    • Nuclear Engineering and Technology
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    • v.38 no.6
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    • pp.483-488
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    • 2006
  • Highly radioactive waste is placed in metal canisters embedded in dense clay termed buffer. The radioactive decay is associated with heat production, which causes degradation of the buffer and thereby time-dependent loss of its waste-isolating potential. The buffer is prepared by compacting air-dry smectite clay powder and is initially not fully water saturated. The evolution of the buffer starts with slow wetting by uptake of water from the surrounding rock followed by a long period of exposure to heat, pressure from the rock and chemical reactants. It can be described by conceptual and theoretical models describing processes related to temperature (T), hydraulic (H), mechanical (M) and chemical performance (C). For temperatures below 90 C more than 75 % of the smectite will be preserved for 100 000 years but cementation may reduce the excellent performance of the buffer to a yet not known extention.

The structural and non-linear dynamic analysis for radioactive waste container

  • Yu-Yu Shen;Kuei-Jen Cheng;Hsoung-Wei Chou
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.3010-3016
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    • 2023
  • In recent years, the development of radioactive waste containers for nuclear facility decommissioning and dismantling is a critical issue because the Taiwan domestic boiling water reactor nuclear power plant is going to be decommissioned. The main purpose of this research is to design a metal container that meets the structural requirements of related regulations. At first, the shielding analysis was performed by varying dimensions of radioactive waste to determine the storage efficiency of the container. Then, a series of structural analyses for operational and accidental conditions of the container with full load were conducted, such as lifting, stacking, and drop impact conditions. On the other hand, the field drop impact tests were carried out to ensure structural integrity. The present research demonstrates the structural safety of the developed container for decommissioned nuclear facilities in Taiwan.

Theoretical Considerations on an Electrolytic Reduction Process for Reducing Spent Oxide Fuel

  • Park B. H.;Seo C. S.;Jung K.-J.;Park S. W.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.86-91
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    • 2005
  • A metal product obtained from an electrolytic reduction process, possesses less volume and radioactivity than those of the unprocessed spent oxide fuels. The chemical composition of the metal product varies according to the process condition. In this work, a basic study was performed to evaluate the chemical forms of the spent oxide fuel components in an electrolytic reduction process with the operation conditions. One of the most important operation conditions is the cell potential applied for the reduction cell. It is expected that $PU_{2}O_3$ is difficult to reduce even though the cell potential is negative enough to reduce the lithium oxide when the activity of $Li_{2}O$ exceeds 0.003. The reduction of actinide oxides via the reduction of $Li_{2}O$ is assumed to have a greater reduction yield than a direct reduction of the actinide oxides.

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Thermal-Hydraulic, Structural Analysis and Design of Liquid Metal Target System (액체금속 표적 시스템의 열적, 구조적 건전성 평가 및 설계)

  • 이용석;정창현
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.294-298
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    • 2001
  • A research for transmutation reactor is in progress to transmute high radioactive isotopes into low radioactive ones. In this study, thermal-hydraulic and structural analysis was performed to design liquid metal target system that would be used in subcritical transmutation reactor. Diffuse plate installation was considered to enhance cooling of window. And thermal-structural analysis of window was performed varying window thickness, beam power, and coolant flow rate to determine target system design valuers. It is ensured that maximum window temperature and stress would be acceptable in the design condition.

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Recovery of RE-less U From U/RE Ingot by Electrochemical Oxidation Process

  • Kim, Si Hyung;Yoon, Dalsung;Jang, Junhyuk;Kim, Taek-Jin;Paek, Seunwoo;Lee, Sung-Jai
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.05a
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    • pp.51-52
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    • 2018
  • Selective oxidation of RE elements from the U/RE metal ingot was studied in this paper using electrochemical process. Constant potential of -1.7V was applied between anode and cathode, where the potential value corresponds to standard potentials between actinide and rare earth materials. When the current values approached to nearly 0 mA, the reaction was finished. It is confirmed from the EPMA analysis that only U part of the U/RE ingot was remained. The metal recovered to the zinc cathode was obtained through the distillation process and it is being chemically analyzed in the KAERI analytical laboratory.

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