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Mass transfer characteristics of continuous electrocoagulation for dyestuff solution using aluminum flat plate electrode (Al 전극에 의한 염료의 전기응집에서 물질전달 특성)

  • Kim, Tak-Hyun;Park, Chulhwan;Shin, Eung-Bai;Kim, Sangyong
    • Proceedings of the KAIS Fall Conference
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    • 2001.05a
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    • pp.290-291
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    • 2001
  • The relationship between velocity, viscosity, diffusion coefficient, mass transfer coefficient and characteristic length and mass transfer data can be correlated by dimensionless relationship in electrolytic process. The performance of dyestuff removal was decreased as the flow rate of electrolyte was increased. It was due to the effect of retention time decreasing was superior to that of turbulent inlet mixing. Sh/Sc$\^$1/3/ vs Re plot for Al flat electrode did not showed the general tendency of the relationship between Sh/Sc$\^$1/3/ and Re. It can be thought that flow rate was not sufficiently high to increase the effect of mixing.

Condensation Heat Transfer of R32 and R454B Inside a Microfin Tube as an Alternative Refrigerant to R410A (R410A 대체냉매 R32와 R454B의 미세핀 관내 응축 열전달)

  • KARAGEORGIS, ANDREAS;HINOPOULOS, GEORGE;KIM, MAN-HOE
    • Journal of Hydrogen and New Energy
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    • v.33 no.4
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    • pp.413-418
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    • 2022
  • This paper presents two-phase condensation heat transfer and pressure drop characteristics of R32 and R454B as an alternative refrigerant to R410A in a 9.52 mm OD microfin tube. The test facility has a straight, horizontal test section with an active length of 2.0 m and is cooled by cold water circulated in a surrounding annular space. The heat transfer coefficients of the annular space were obtained using the modified Wilson plot method. Average condensation heat transfer coefficient and pressure drop data are presented at the condensation temperature of 35℃ for the range of mass flux 100-400 kg/m2s. The average condensation heat transfer coefficients of R32 refrigerant are 35-47% higher than R410A at the mass flux considered in the study, while R454B data are similar to R410A. The average pressure drop of R32 and R454B are much higher than R410A and they are 134-224% and 151-215% of R410A, respectively. R32 and R454B have relatively low GWP and high heat transfer characteristics, so they are suitable as alternatives for R410A.

Effect of Red Pepper Canopy Coverages on Soil Loss and Runoff from Sloped Land with Different Transplanting Dates (경사지에서 고추 정식시기에 따른 토양유실과 유출수에 대한 식생피복 효과)

  • Cho, H.R.;Ha, S.K.;Hyun, S.H.;Hur, S.O.;Han, K.H.;Hong, S.Y.;Jeon, S.H.;Kim, E.J.;Lee, D.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.3
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    • pp.260-267
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    • 2010
  • As sloped farmland is subject to runoff and soil erosion and consequently require appropriate vegetative coverage to conserve soil and water, a field study was carried out to evaluate the impact of crop canopy coverage on soil loss and runoff from the experimental plot with three different textural types (clay loam, loam, and sandy loam). The runoff and soil loss were examined at lysimeters with 15% slope, 5 m in length, and 2 m in width for five months from May to September 2009 in Suwon ($37^{\circ}$ 16' 42.67" N, $126^{\circ}$ 59' 0.11" E). Red pepper (Capsicum annum L. cv. Daechon) seedlings were transplanted on three different dates, May 4 (RP1), 15 (RP2), and 25 (RP3) to check vegetation coverage. During the experimental period, the vegetation coverage and plant height were measured at 7 day-intervals and then the 'canopy cover subfactor' (an inverse of vegetation cover) was subsequently calculated. After each rainfall ceased, the amounts of soil loss and runoff were measured from each plot. Under rainfall events >100 mm, both soil loss and runoff ratio increased with increasing canopy cover subfactor ($R^2$=0.35, p<0.01, $R^2$=0.09, p<0.1), indicating that as vegetation cover increases, the amount of soil loss and runoff reduces. However, the soil loss and runoff were depending on the soil texture and rainfall intensity (i. e., $EI_{30}$). The red pepper canopy cover subfactor was more highly correlated with soil loss in clay loam ($R^2$=0.83, p<0.001) than in sandy loam ($R^2$=0.48, p<0.05) and loam ($R^2$=0.43, p<0.1) plots. However, the runoff ratio was effectively mitigated by the canopy coverage under the rainfall only with $EI_{30}$<1000 MJ mm $ha^{-1}hr^{-1}$ ($R^2$=0.34, p<0.05). Therefore, this result suggested that soil loss from the red pepper field could be reduced by adjusting seedling transplanting dates, but it was also affected by the various soil textures and $EI_{30}$.

Wetting of Galvanised Steel by An Epoxy Adhesive: Effects of Surface Oil

  • Shanahan, M.E.R.;Greiveldinger, M.
    • Journal of Adhesion and Interface
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    • v.3 no.1
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    • pp.20-23
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    • 2002
  • The wetting properties of an uncured epoxy resin on both clean and oiled, galvanised steel have been studied. Since the polymer is very viscous at ambient temperature, and also with an aim to simulate industrial conditions, the spreading of drops of resin during a heating cycle (temperature increase at $10^{\circ}C/min$) was recorded and analysed. On clean steel, a contact angle, ${\theta}$, vs time, t, plot shows sigmoidal behaviour, whereas on the oiled substrate, spreading almost ceases in an intermediate stage. This strange behaviour is attributed to significant oil absorption by the polymer.

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Studies on the Ecological Changes in the Plant Community of the Erosion Controlled Area at Yoju-Gun, Kyonggi-Do (사방시공지(砂防施工地) 식물사회(植物社會)의 생태학적(生態學的) 변화(變化)에 관(關)한 연구(硏究)(II) - 경기(京畿), 여주지역(驪州地域)을 중심(中心)으로 -)

  • Lee, Hyun Kyu
    • Journal of Korean Society of Forest Science
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    • v.81 no.4
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    • pp.303-309
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    • 1992
  • This study eras carried out to investigate the ecological changes on the plant community at erosion controlled area in Yoju-gun, Kyonggi-do. The results of the study were as follows : 1. The depth of organic matters in the soil profile from 4 to 14 years was estimated to be $Y_{(cm)}=0.436X_{(yr)}-0.931$(r=0.978), and 02 layer was $Y_{(cm)}=0.339_{(yr)}-0.931$ (r=0.954). 2. On upper plant layer. Alnus spp. was decreased, on an average, 32% of relative coverage, 12.4% of relative density and 16.8% of relative frequency in each plot for 3 years, as this area was damaged by Agelastica coerulea Baly for 2-3 years. 3. On upper plant layer, relative coverage of Pinus spp. was increased after 6, 7 years in erosion controlled area and was taked the highest plant (more then 40%) from 10 to 14 years. 4. On lower plant layer, relative density of Quercus ssp. (these species has not been planted and sown on erosin controlling) was increased all the plot. 5. The increase of the whole crown projection area was estimated to be $Y_{(m^2)}=18.020X_{(yr)}+18.834$(r=0.954) 6. The biomass was estimated to be 14.88t/ha on elapsed 6 years, 22.84t/ha on 8 years, 35.08t/ha on 10 years, 47.80t/ha on 12 years, 58.13t/ha on 14 years.

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Repeatability of Monocular Spherical Endpoints Test (단안 구면 끝점검사의 반복성 검증)

  • Kim, Sang-Yeob;Moon, Byeong-Yeon;Cho, Hyun Gug
    • Journal of Korean Ophthalmic Optics Society
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    • v.17 no.2
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    • pp.209-213
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    • 2012
  • Purpose: To assess the repeatability of the monocular spherical endpoints, a test was performed with four methods which are the retinoscopy, the MPMVA (maximum plus maximum visual acuity) method, the R/G duochrome method, and the crossed cylinder method. Methods: The monocular spherical endpoints was measured by four kinds of method (Retinoscopy, MPMVA method, R/G duochrome method, Crossed cylinder method) on 20 subjects (40 eyes) of average age 23.0 year-old men and women. After a week, retest was performed by same procedure and the test-retest repeatability was assessed by using the Bland-Altman plot analysis. Results: The test-retest mean difference of retinoscopy was the smallest diopters of -0.03 and that of R/G duochrome method was the largest diopters of -0.19. The upper/lower 95% limits of agreement for repeatability was the narrowest in retinoscopy and was the widest in crossed cylinder method. When compared the spherical endpoints of each eye between by retinoscopy and by other three methods, the error rate of ${\pm}0.25D$ in total eyes was 85% in MPMVA method, 80% in R/G duochrome method, and 24% in crossed cylinder method. Conclusions: Test-retest repeatability is the highest in the retinoscopy, and the retinoscopy, the MPMVA method, and R/G duochrome method are suitable for monocular spherical endpoints test.

Behavior of NO3-N and Accompanying Cations Derived from Urea under Upland Condition -I. Leaching of NO3-N and Accompanying Cations (요소유래(尿素由來) NO3-N 및 동반(同伴) 양(陽)이온의 토양(土壤) 중 행동(行動) -I. NO3-N 동반(同伴) 양(陽)이온의 용탈(溶脫))

  • Yun, Sun-Gang;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.1
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    • pp.15-20
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    • 1994
  • Lysimeter experiments were conducted to elucidate the behavior of $NO_3-N$ derived from urea applied at different rates and accompanying cations in soils and to further provide fundamental information of rational nitrogen-fertilizer management. Urea was applied at rates of 0, 7, 14, 21, 28 and 35kg N/10a to sandy loam pakced into PVC cylindrical lysimeter(vol. : $0.187m^2$, area $0.43m^2$). Leachates from the lysimeter with or without grass grown were collected periodically and analyzed for $NO_3$ and cations. Grass growth and yield responses to N fertilization were also examined. Dry matter yield and nitrogen uptake increased with the urea application rate. The amount of leachate from the lysimeter was negatively correlated with urea application ratesl($r=-0.95^{**}$). The nitrate leaching loss with grass grown was 230 g N/10a at the maximum rate of 35kg N/10a, but the highest leaching loss was observed as 1,607 g N/10a from the bare plot. Increase in urea application rates decreased significantly leaching losses of Ca, Mg, K and Na(>0.01). The highest leaching loss from the bare plot was observed for Ca but only 6.5% of exchangeable form and 14.0% for K from the grass plot respectively. Equivalent ratio of cations to nitrate leached were 3.2 % for the bare plot and the ratio for the grass plot increased with the urea application rate, ranging from 18.6 to 32.7%.

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Comparison of Glass CTAD Tube and Plastic Sodium Citrate Tube for Coagulation Test (혈액응고 검사용 유리 CTAD 채혈관와 플라스틱 Sodium Citrate 채혈관의 비교)

  • Kang, Su-Jin;Park, Jeong-Su;Song, Yoon-Kyung;Kong, Sun-Yong;Lee, Do-Hoon
    • Korean Journal of Clinical Laboratory Science
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    • v.39 no.3
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    • pp.156-160
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    • 2007
  • We evaluated the newly developed plastic sodium citrate tubes for routine coagulation test by direct comparison with glass citrate theophylline adenosine dipyridamole (CTAD) tubes. Blood was drawn from 100 patients into glass CTAD tubes and plastic sodium citrate tubes. After collection, samples were centrifuged at 1500 ${\times}$g for 15 min at $22^{\circ}C$. Prothrombin time (PT), activated partial thromboplastin time (aPTT), fibrinogen were measured by using the Coagrex-800 (IRC, Japan). We used comparison plot by linear regression model and difference plot graphs to compare the results of the independent measurements of PT, aPTT, fibrinogen between glass CTAD tubes and plastic sodium citrate tubes. On the comparison study between glass CTAD tubes and plastic sodium citrate tubes, the correlation coefficients (R) were 0.99 for PT, 0.97 for aPTT and 0.97 for fibrinogen. This results implicated good correlation of each parameter between two tubes. Although the difference plot graph analysis showed statistically significant differences between glass and plastic tubes for PT, aPTT and fibrinogen, the range of difference was acceptable according to the CLSI/NCCLS guideline. The plastic sodium citrate tubes showed good correlation with the glass CTAD tubes, so it can substitute glass citrate tube for routine coagulation tests.

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The α-Effect in Hydrazinolysis of 4-Chloro-2-Nitrophenyl X-Substituted-Benzoates: Effect of Substituent X on Reaction Mechanism and the α-Effect

  • Kim, Min-Young;Kim, Tae-Eun;Lee, Jieun;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2271-2276
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    • 2014
  • Second-order rate constants ($k_N$) have been measured spectrophotometrically for the reaction of 4-chloro-2-nitrophenyl X-substituted-benzoates (6a-6h) with a series of primary amines including hydrazine in 80 mol % $H_2O$/20 mol % DMSO at $25.0^{\circ}C$. The Br${\o}$nsted-type plot for the reaction of 4-chloro-2-nitrophenyl benzoate (6d) is linear with ${\beta}_{nuc}$ = 0.74 when hydrazine is excluded from the correlation. Such a linear Br${\o}$nsted-type plot is typical for reactions reported previously to proceed through a stepwise mechanism in which expulsion of the leaving group occurs in the rate-determining step (RDS). The Hammett plots for the reactions of 6a-6h with hydrazine and glycylglycine are nonlinear. In contrast, the Yukawa-Tsuno plots exhibit excellent linear correlations with ${\rho}_X$ = 1.29-1.45 and r = 0.53-0.56, indicating that the nonlinear Hammett plots are not due to a change in RDS but are caused by resonance stabilization of the substrates possessing an electron-donating group (EDG). Hydrazine is ca. 47-93 times more reactive than similarly basic glycylglycine toward 6a-6h (e.g., the ${\alpha}$-effect). The ${\alpha}$-effect increases as the substituent X in the benzoyl moiety becomes a stronger electron-withdrawing group (EWG), indicating that destabilization of the ground state (GS) of hydrazine through the repulsion between the nonbonding electron pairs on the two N atoms is not solely responsible for the substituent-dependent ${\alpha}$-effect. Stabilization of transition state (TS) through five-membered cyclic TSs, which would increase the electrophilicity of the reaction center or the nucleofugality of the leaving group, contributes to the ${\alpha}$-effect observed in this study.

Graphical Method for Multiple Regression Model (다중회귀모형의 그래픽적 방법)

  • Lee, W.R.;Lee, U.K.;Hong, C.S.
    • The Korean Journal of Applied Statistics
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    • v.20 no.1
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    • pp.195-204
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    • 2007
  • In order to represent multiple regression data, an alternative graphical method, called as SSR Plot, is proposed by using geometrical description methods. This plot uses the relation that the sum of sqaures for regression (SSR) of two explanatory variables is known as the sum of the SSR of one variable and the increase in the SSR due to the addition of other variable to the model that already contains a variable. This half circle shaped SSR plot contains vectors corresponding explanatory variables. We might conclude that some explanatory variables corresponding to vectors which locate near the horisontal axis do affect the response variable. Also, for the regression model with two explanatory variables, a magnitude of the angle between two vectors can be identified for suppression.