• Title/Summary/Keyword: quinoline

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Photophysical Model of 10-Hydroxybenzo[h]quinoline: Internal Conversion and Excited State Intramolecular Proton Transfer

  • Lee, Junghwa;Joo, Taiha
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.881-885
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    • 2014
  • Photophysics of 10-hydroxybenzo[h]quinoline (HBQ) has been in controversy, in particular, on the nature of the electronic states before and after the excited state intramolecular proton transfer (ESIPT), even though the dynamics and mechanism of the ESIPT have been well established. We report highly time resolved fluorescence spectra over the full emission frequency regions of the enol and keto isomers and the anisotropy in time domain to determine the accurate rates of the population decay, spectral relaxation and anisotropy decay of the keto isomer. We have shown that the ~300 fs component observed frequently in ESIPT dynamics arises from the $S_2{\rightarrow}S_1$ internal conversion in the reaction product keto isomer and that the ESIPT occurs from the enol isomer in $S_1$ state to the keto isomer in $S_2$ state.

A Study on the Surfactant-Enhanced Desorption of Organic Contaminants from Soil Particles (계면활성제를 이용한 지반 오염물질의 탈착 연구)

  • 박준범;박상권
    • Geotechnical Engineering
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    • v.13 no.2
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    • pp.55-64
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    • 1997
  • Laboratory tests were performed to desorb organic contaminants spiked onto soil particles by using surfactants. Nonionic and anionic surfactants were tested as potential desorbing solvents for extracting quinoline and 2-napthol adsorbed on soil particles. Ahionisc stirfactant remediated approximately 80% and 90% of quinoline and 2-napthol respectively and appeared to be more effective than nonionic surfactant in remediating those compounds, Comparison between simple deionized water washing of the organic contaminated soil and a given surfactant technique evaluated the improvement by the application of a Burfactant to the promotion of desorption.

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Synthesis of 3-Aryl-3-hydroxypyrrolidin-2-ones and 2-Benzyl-9b-hydroxy-3,3a,5,9b-tetrahydro-2H-pyrrolo[3,4-c]quinoline-1,4-dione Derivatives from the Baylis-Hillman Adducts of Isatins

  • Kim, Seung Chan;Lee, Ka Young;Gowrisankar, Saravanan;Kim, Jae Nyoung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.8
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    • pp.1133-1139
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    • 2006
  • We prepared 3-aryl-3-hydroxypyrrolidin-2-one and tricyclic 2-benzyl-9b-hydroxy-3,3a,5,9b-tetrahydro-2H-pyrrolo[3,4-c]quinoline-1,4-dione derivatives starting from the Baylis-Hillman adducts of isatin derivatives.

Synthesis and Antimicrobial Activities of Piperazinyl Quinolone Derivatives (Piperazinyl Quinolone계 유도체의 합성 및 항균작용)

  • Yim, Chul-Bu;Lee, Young-Woon;Choi, Su-Hang;Youm, Jeong-Rok;Huh, In-Hoi
    • YAKHAK HOEJI
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    • v.35 no.6
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    • pp.515-521
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    • 1991
  • A number of 1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(4-substitutedcarbamyl-1-piperazinyl) quinoline [or 1,8-naphthyridine]-3-carboxylic acid and their pivaloyloxymethyl esters were prepared. The compounds synthesized were evaluated for antibacterial activity in vitro against Escherichia coli, Bacillus subtilis, Proteus vulgaris, Klebsiella pneumoniae, Staphylococcus aureus and Pseudomonas aeruginosa. Among those 1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(4-methylcarbamyl-1-piperazinyl) quinoline-3-carboxylic acid [1] and 1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(4-methylcarbamyl-1-piperazinyl)1,8-naphthyridine-3-carboxylic acid [6] showed the most potent in vitro antibacterial activity.

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A New Quinoline-Based Acylhydrazone for Highly Selective Fluorescence Recognition of Cu(II) and Sulfide in Aqueous Solution

  • Tang, Lijun;Zhou, Pei;Qi, Zhikai;Huang, Zhenlong;Zhao, Jia;Cai, Mingjun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2256-2260
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    • 2013
  • A new quinoline-based acylhydrazone (1) has been synthesized and applied as a fluorescent probe. Probe 1 exhibits high selectivity and sensitivity to $Cu^{2+}$ with fluorescence "ON-OFF" behavior in HEPES buffered (1‰ DMSO, HEPES 20 mM, pH = 7.4) solution. The on-site generated 1-$Cu^{2+}$ complex displays excellent selectivity to sulfide ions with fluorescence "OFF-ON" performance through copper displacement approach.