• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.5 s.248
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• pp.405-412
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• 2006

In order to realize a stably propagating flame in a narrow channel, flame instabilities resulting from flame-wall interaction should be avoided. In particular flame quenching is a significant issue in micro combustion devices; quenching is caused either by excessive heat loss or by active radical adsorptions at the wall. In this paper, the relative significance of thermal and chemical effects on flame quenching is examined by means of quenching distance measurement. Emphasis is placed on the effects of surface defect density on flame quenching. To investigate chemical quenching phenomenon, thermally grown silicon oxide plates with well-defined defect distribution were prepared. ion implantation technique was used to control defect density, i.e. the number of oxygen vacancies. It has been found that when the surface temperature is under $300^{\circ}C$, the quenching distance is decreased on account of reduced heat loss; as the surface temperature is increased over $300^{\circ}C$, however, quenching distance is increased despite reduced heat loss effect. Such abberant behavior is caused by heterogeneous surface reactions between active radicals and surface defects. The higher defect density, the larger quenching distance. This result means that chemical quenching is governed by radical adsorption that can be parameterized by oxygen vacancy density on the surface.

• Journal of Korea Foundry Society
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• v.35 no.4
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• pp.88-98
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• 2015

The effects of quenching and tempering temperatures on the tensile, impact and corrosion properties of A487 alloy cast with different C contents of 0.16, 0.19 to 0.23 wt.% were examined. The impact tests were conducted at $25^{\circ}C$ and $-60^{\circ}C$ and the immersion test was performed using 3.5% NaCl solution for 14 days. The quenching temperature affected the mechanical properties of A487 alloy cast, while the magnitude of change varied depending on the C content. The increase in tempering temperature showed the typical trend of decreasing tensile strength and increasing impact properties. The change in quenching and tempering temperature in this study did not affect the corrosion properties of A487 alloy significantly. The change in mechanical and corrosion properties of A487 with different C contents was discussed based on the microstructural and fractographic observation.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.4
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• pp.216-222
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• 2004

Study was focused on the quenching embrittlement property of Zircaloy-4 cladding simulated Loss Of Coolant Accident (LOCA) environment in terms of high temperature oxidation and phase transformation. Property in LOCA condition of advanced cladding that contained Nb element was also investigated. Claddings were oxidized at given temperature and given time followed by water quenching. The results showed that ${\beta}$ phase which formed at quenching stage has an influence on cladding property. In case of advanced cladding, Nb retards cladding oxidation, thus enhances quenching resistance.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.06a
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• pp.48-53
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• 2000

The effects of added elements, such as Co or Nb, on wear properties of high speed steel by powder metallurgy(PM-HSS) had been evaluated in previous paper. The wear properties of materials, in fact, have been a]so influenced by heat-treating conditions. In this paper, the effects of heat-treating conditions on wear properties of PM-HSS have been evaluated. The wear tests have been performed as same conditions as previous paper using PM-HSS(5%Co-1%Nb) heat-treated under different quenching and tempering temperature. The result of this paper shows that wear resistance of PM-HSS is improved with relatively high quenching temperature. However tempering temperature is not sensitve to the wear resistance in range of high quenching temperature. It may be deduced by the fact that the shear strength of matrix by strengthening mechanisms of quenching aging in addition to dispersion-hardening is improved.

• Journal of the Korean Society for Heat Treatment
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• v.23 no.6
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• pp.323-330
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• 2010

The present study was motivated by increasing demands on quantitative measurements of the heat flux through the water cooling and quenching process of hot steel. The local heat flux measurements are employed by a novel experimental technique that has a function of high-temperature heat flux gauge in which test block assemblies are directly used to measure the heat flux variation during water cooling and quenching of hot steel. The heat flux can be directly achieved by Fourier's law and is also compared with numerical estimation which is solved by inverse heat conduction problem (IHCP). The high-temperature heat flux gauge developed in this study can be applicable to measure cooling rate and history during the actual cooling applications of steelmaking process. In addition, the measurement uncertainty of heat flux is calculated by a quantitative uncertainty analysis which is based on the ANSI/ASME PTC 19.1-2005 standard.

• Journal of Photoscience
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• v.12 no.1
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• pp.51-54
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• 2005

The electronic excitationenergy quenching of 2, 5-diphenyl-1, 3, 4-oxadiazole (PPD) by Carbon tetrachloride ($CCl_4$) in different solvents viz, n-hexane, n-heptane, toluene, benzene, cyclohexane, 1, 4- dioxane has been carried out at room temperature to understand the role of quenching mechanism. The Stern-Volmer plots have been found to be linear. As probability of quenching per encounter 'p' is less than unity, and the activation energy for quenching '$E_a$' is greater than the activation energy of diffusion '$E_d$', it is inferred that the fluorescence quenching mechanism is not due to material diffusion alone.

• International Journal of Automotive Technology
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• v.7 no.1
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• pp.69-74
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• 2006

Residual stresses are introduced in aluminum cylinder head during quenching at the end of the T6 heat treatment process. Tensile residual stress resulted from quenching is detrimental to fatigue behavior of a cylinder head when it is overlapped with stresses of engine operation load. Quenching simulation has been performed to assess the distribution of residual stress in the cylinder head. Analysis revealed that in-homogeneous temperature distribution led to high tensile residual stress at the foot of the long intake port, where high stresses of engine operation load are expected. Measurements of residual stress have been followed and compared with the calculated results. Results successfully proved that high tensile residual stress, which was large enough to accelerate fatigue failure of the cylinder head, are formed during quenching process at the end of heat treatment at the same critical position. Effect of quenching parameters on the distribution of residual stress in cylinder head has been investigated by choosing different combination of heat treatment parameters. It was demonstrated that changes of quenching parameters led to more homogeneous temperature distribution during cooling and could reduce tensile residual stress at the critical region of the cylinder head used in this study.

• Journal of the Korean Society for Precision Engineering
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• v.27 no.11
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• pp.84-91
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• 2010

Heat treatment with carburized quenching process is widely used for automotive helical gear to improve its surface properties of hardness and strength. However, the gear can be deformed with the process over the allowable tolerance, which possibly makes noise, vibration and heat problems in operation. In this study, deformation of helical gear during heat treatment of carburized quenching was analyzed with a numerical method, incorporating coupled calculations of thermal conduction, carbon diffusion, phase transformation and thermal stresses. With the analysis, the effect of coolant temperature in quenching on the deformation was investigated. The result of the analysis revealed that the higher the coolant temperature became, the more change of helix angle and the more compressive stresses in the surface generated, because of delayed generation of martensite in the part.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.6 no.5
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• pp.27-37
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• 1992

We studied the dielectric and dynamic mechanical losses according to the quenching condition in low density polyethylene being used to power cables. According to severe quenching condition, characteristics of the temperature in internal friction los peak have decreased the magnitude of loss peak as amorphous region lengthen. From now on, the frequency dependent characteristics of dielectric loss have investigated at room temperature, and the dielectric loss peak due to interface polarization, between crystal and amorphous region, occurs about 30[Hz], and that, the peak due to orientation polarization in correspondence to the loss peak in internal friction has observed at about 3 [MHz]. As quenching velocity increased, the effect on quenching condition about the dielectric loss has decreased the magnitude of the loss peak. Thus, estimation has been carried out on the activation energies nd the degree of crystallinity by means of X-ray diffraction are obtained as follows: room quenching : 26.4 [kal/mole] and 54.73 [%], ice quenching : 25.6 [kcal/mole] and 48.47 [%], liquid nitrogen quenching specimens : 22.56 [kcal/mole] and 40.95 [%].

• Journal of Photoscience
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• v.4 no.3
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• pp.97-103
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• 1997

The effect of temperature on the fluorescence quenching of 2-(4-Methoxyphenyl)-5-(1-naphthyl)-1,3,4-oxadiazole (MPNO1), 2-(4-Methoxyphenyl)-5-(2-naphthyl)-1,3,4-oxadiazote(MPNO2), by aniline, and 2-Phenylindole (2-PI) by CCk, in toluene by steady state method and in benzene by time-resolved method have been carried out in the temperature range 30 - 70$\circ$C. The Stem-Volmer (S-V) plots, I$_0$/I against quencher concentration [Q] at different temperanares show positive deviations. The fluorescence lifetimes determined at different temperatures show no systematic variations and the variations being within the experimental error, the average values of lifetimes $ $\tau$ (t) are taken for further calculations. Rate constants such as Stem-Volmer quenching constants K$_sv}$, quenching rate parameters k$_q$ and k'$_q$, static quenching constant V and kinetic distance r are determined using the modified Stem-Volmer equation and sphere of action static quenching model. In order to see whether the reactions are diffusion limited, equations k$_q$ = e$^{-Eq/RT}$ and k'$_q$ = e$^{-Eq/RT}$ are used to determine the values of E$_q$ and E'$_q$, the activation energies for collisional quenching and the values of E$_q$ are 14.53. 17.28 and 16.20 kJ mole$^{-1}$ for MPNO1, MPNO2 and 2-PI respectively and the values of E'$_q$ are 14.62 and 17.73 for MPNO1 and MPNO2 respectively. From the magnitudes of various quantities it has been concluded that the reactions are diffusion limited and the observed positive deviations in the S-V plot are due to static and dynamic quenching.