• Title/Summary/Keyword: quenching

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A Study on Temperature Rising near Fatigue Crack Tip at Cryogenic Temperature (극저온 환경에서의 피로균열 선단의 온도상승에 관한 연구)

  • ;Maekawa, I.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.1
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    • pp.79-86
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    • 1995
  • The structural materials for cryogenic technology have been recently developed to support the many modern large-scale application from superconducting magnets for nuclear fusion reactor, magnetic levitation railway to LNG tankers. However it is pointed out that quenching phenomenon is one of the serious problems for the integrity of these applications, which is mainly attributed to the rapid temperature rising in the material due to some extrinsic factors of structures. From the viewpoint of fracture mechanics, it is therefore very important to clarify the mechanism of temperature rising of structural material due to cyclic loading at cryogenic temperature. From this purpose, fatigue test was carried out for high manganese steel at liquid helium temperature(4.2K) using triangular stress waveform to identify both the mechanism of temperature rising near crack tip and the effect of loading stress waveform on temperature rising near crack tip and the effect of loading stress waveforms on temperature rising. As the results, two types of temperature rising, that is, regular and burst types were observed. And a periodical temperature rising corresponding to the stress waveforms was also found. The peaks of the temperature rising were recorded near both the maximum and the minimum values of the applied stress. The sudden temperature rises, which indicated the higher values than those of periodical temperature rises under the repetition of stress, were observed at the final region of crack growth. It was shown that the peak values of the temperature rising increased with stress intensity factor range.

Photocatalytic Oxidation of 2-Mercaptoethanol to Disulfide using Sb(V)-, P(V)-, and Ge(IV)-porphyrin Complexes

  • Shiragami, Tsutomu;Onitsuka, Dai;Matsumoto, Jin;Yasuda, Masahide
    • Rapid Communication in Photoscience
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    • v.3 no.4
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    • pp.70-72
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    • 2014
  • Visible-light irradiation of MeCN solution containing di(hydroxo)metallo(tetraphenyl)porphyrin complex $(tppM(OH)_2$: 1a; $M=Sb(V)^+Br^-$, 1b; $M=P(V)^+Cl^-$, 1c; M=Ge(IV)) and 2-mercaptoethanol (2-ME) as a substrate under aerated condition gave bis(2-hydroxyethyl)disulfide (2-HEDS) as an oxidative product of 2-ME. It is indicated that the oxidation of 2-ME should proceed with a photocatalytic process by 1, because the turn over number (TON) for the formation of 2-HEDS was over unit. The TON was determined to be 642 as a maximum value when 1a was used as a sensitizer. The formation of 2-HDES was extremely slow under argon atmosphere. The fluorescence of 1 was not quenched by 2-ME at all, and the free energy change (${\Delta}G$) with electron transfer (ET) from 2-ME to excited triplet state of $1(^31^*)$ was estimated as a negative value. The quenching rate constant ($k_r$) of $^31^*$ by 2-ME, obtained by the kinetics for the formation of 2-HEDS, strongly depends on ${\Delta}G$. These findings indicate that 1-sensitized oxidation was initiated by photoinduced ET from 2-ME to $^31^*$ to generate both radical cation of 2-ME ($2-ME^{+\bulle}$) and porphyrin radical anion ($1^{-\bulle}$), resulting that the formation of 2-HEDS can be proceeded by the dimerization of $2-ME^{+\bulle}$, and through a catalytic cycle due to returning to 1 by the ET from $1^{-\bulle}$ to molecular oxygen.

Characterization of Acoustic Emission Signal for Welding Flaw and Stress Corrosion of SPPH Steels (SPPH강의 용접결함과 응력부식에 따른 음향 방출 신호의 특성)

  • Kim, Sung-Dai;Jung, Woo-Gwang;Lee, Jong-O;Jung, Yu-Jin
    • Journal of the Korean Society for Nondestructive Testing
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    • v.27 no.2
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    • pp.97-104
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    • 2007
  • An investigation has been made on the relationship between characteristics of Acoustic Emission (AE) signal in welding flaw and the stress corrosion defect in-service for the high pressure pipe steel. In order to tackle the problem of welding flaw in high pressure pipe, specimens were made by the aid of the application of both corrosion liquid usage and a quenching method after local heating. The amplitude of signal was $60{\sim}75\;dB$ in the territory which is suspected for defect, and the specimens which only have welding flaw showed gradients of 0.034, 0.034, 0.035. Moreover, there is a certain increase in gradient even though the differences are very slight. That is, corrosion specimens showed new gradients of 0.040, 0.039, 0.041 which put welding flaw and corrosion mechanism together. After pressurizing 3 minutes, AE signal has been detected from welding flaw easily in each part of the section. It is possible to predict the occurrence and also prevent the damage of stress corrosion crack which has characteristics of cleavage fracture.

High Strength SA508 Gr.4N Ni-Cr-Mo Low Alloy Steels for Larger Pressure Vessels of the Advanced Nuclear Power Plant (차세대 원전 대형 압력용기용 고강도 SA508 Gr.4N Ni-Cr-Mo계 저합금강 개발)

  • Kim, Min-Chul;Park, Sang-Gyu;Lee, Ki-Hyoung;Lee, Bong-Sang
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.100-106
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    • 2014
  • There is a growing need to introduce advanced pressure vessel steels with higher strength and toughness for the optimizatiooCn of the design and construction of longer life and larger capacity nuclear power plants. SA508 Gr.4N Ni-Cr-Mo low alloy steels have superior strength and fracture toughness, compared to SA508 Gr.3 Mn-Mo-Ni low alloy steel. Therefore, the application of SA508 Gr.4N low alloy steel could be considered to satisfy the strength and toughness required in advanced nuclear power plants. The purpose of this study is to characterize the microstructure and mechanical properties of SA508 Gr.4N low alloy steels. 1 ton ingot of SA508 Gr.4N model alloy was fabricated by vacuum induction melting followed by forging, quenching, and tempering. The predominant microstructure of the SA508 Gr.4N model alloy is tempered martensite having small packet and fine Cr-rich carbides. The yield strength at room temperature was 540MPa, and it was decreased with an increase of test temperature while DSA phenomenon occurred at around $288^{\circ}C$. Overall transition property of SA508 Gr.4N model alloy was much better than SA508 Gr.3 low alloy steel. The index temperature, $T_{41J}$, of SA508 Gr.4N model alloy was $-132^{\circ}C$ in Charpy impact tests, and reference nil-ductility transition temperature, $RT_{NDT}$ of $-105^{\circ}C$ was obtained from drop weight tests. From the fracture toughness tests performed in accordance with the ASTM standard E1921 Master curve method, the reference temperature, $T_0$ was $-147^{\circ}C$, which was improved more than $60^{\circ}C$ compared to SA508 Gr.3 low alloy steels.

A Numerical Analysis on Combustion Characteristics of the Gasoline Engine using Methanol Reformulated Fuels under WOT Condition (전부하 운전조건에서 메탄올 개질연료를 사용한 가솔린 엔진의 연소특성에 대한 수치해석)

  • Lee, Suk-Young;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.20 no.2
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    • pp.163-169
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    • 2011
  • This research is to decide the possibility of using RM50(reformulated methanol fuel) without any modification of engine by the method of numerical analysis. Comparing the heat release rate, the difference among each fuel was decreased according to the increase of the engine speed, and the maximum heat release rate was higher in the order of RM50 and gasoline fuel. Also, this order corresponds to the order of burning speed. RM50 had the higher turbulent burning speed, and the curve of turbulent intensity was showed similar tendency to the curve of turbulent burning speed. RM50 had relatively high burning speed, short quenching length, high temperature in cylinder, so that it might increase NO emission, but owing to chemical reaction dynamics, it was decreased NO emission. Therefore, in order to predict the possibility of using RM50, it is needed to consider not only the temperature in cylinder by low heating value, but also combustion characteristics including burning speed.

Analysis of the Recovery Behavior of SFCL According to Reclosing Operation (재폐로 동작에 따른 초전도 한류기의 회복성능 분석)

  • Ha, Kyoung-Hun;Cho, Yong-Sun;Kim, Deog-Goo;Choi, Hyo-Sang
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.5
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    • pp.1073-1077
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    • 2011
  • The breaking capacity of circuit breakers could be no more increased in the electric power system. This is because the fault current increases due to continuous increases in electric power demand and facilities. To solve the problem, it is necessary to come up with an alternative. The superconducting fault current limiter (SFCL) has received an attention among various alternatives. The SFCL effectively reduce a fault current in cooperation with a power circuit breaker. A various types of the SFCL are suggested and a study on them have been progressed. As a result of it, the SFCL can be applyed to the electric power system in the near future. But, a study on recovery behaviors of the SFCL is not enough for applying to the electric power system. If the superconducting elements do not completely recover to the superconducting state after fault operation, it might be a breakdown of the superconducting elements due to heavy power burden and it gives an bad influence on the working of other electric devices. Additionally, the distribution power system has reclosing operation such as open-0.3sec-closed/open-3min-closed/open procedure. So we need to study more about improvement of the recovery behaviors of the SFCL. In this paper, we analyzed the recovery behaviors of a flux-coupling type SFCL according to reclosing operation when a single line-to-ground fault occurred and we compared recovery behaviors of the SFCL with and without a neutral line between secondary reactors and superconducting elements. Also, the flux-coupling type SFCL has advantageous for increases of capacity by controlling the variation in turn ratios between two reactors. Consequently, when the number of turns of the secondary reactors increased, the power burden of the superconducting elements was bigger due to the increase of impedances of the secondary reactors. To distribute the power burden, two superconducting elements connected in series and the balanced quenching of the superconducting elements was induced by connecting a neutral line.

A Study on the Residual Stress of AISI 4140 Formed during Surface Hardening Treatment by using the CO2 Laser Beam (CO2레이저 비임을 이용한 표면경화 처리중 형성된 AISI 4140의 잔류응력에 관한 연구)

  • Park, K.W.;Lee, J.B.;Han, Y.H.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.4
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    • pp.289-299
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    • 1996
  • This study has been performed to investigate into some effects of power density and traverse speed of laser beam on the microstructure, hardness and residual stress of AISI 4140 treated by laser surface hardening technique. Optical micrograph has shown that large martensite and a small amount of retained austenite in outermost surface layer and fine lath martensite in inner surface hardened layer are formed under the condition of a given power density and traverse speed. Hardness measurements have revealed that as the power density increases at a given 2.0m/min of the traverse speed, the maximum hardness values of outermost surface hardened layer is increased from Hv=635 to Hv=670. X-ray analysis for residual stress has exhibited that low compressive residual stress values are obtained in center point of the cress section of surface hardened layer with in mid point between the edge and the center point, about 1.5mm from the center point, due simply to a difference in self-quenching rate. It has been shown that the higher the power density at a given traverse speed and the olwer the traverse speed at a given power density, the more the compressive residual stress values are increased due to an increase in the input heat of laser beam.

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Biophysical Studies Reveal Key Interactions between Papiliocin-Derived PapN and Lipopolysaccharide in Gram-Negative Bacteria

  • Durai, Prasannavenkatesh;Lee, Yeongjoon;Kim, Jieun;Jeon, Dasom;Kim, Yangmee
    • Journal of Microbiology and Biotechnology
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    • v.28 no.5
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    • pp.671-678
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    • 2018
  • Papiliocin, isolated from the swallowtail butterfly (Papilio xuthus), is an antimicrobial peptide with high selectivity against gram-negative bacteria. We previously showed that the N-terminal helix of papiliocin (PapN) plays a key role in the antibacterial and anti-inflammatory activity of papiliocin. In this study, we measured the selectivity of PapN against multidrug-resistant gram-negative bacteria, as well as its anti-inflammatory activity. Interactions between Trp2 of PapN and lipopolysaccharide (LPS), which is a major component of the outer membrane of gram-negative bacteria, were studied using the Trp fluorescence blue shift and quenching in LPS micelles. Furthermore, using circular dichroism, we investigated the interactions between PapN and LPS, showing that LPS plays critical roles in peptide folding. Our results demonstrated that Trp2 in PapN was buried deep in the negatively charged LPS, and Trp2 induced the ${\alpha}$-helical structure of PapN. Importantly, docking studies determined that predominant electrostatic interactions of positively charged arginine residues in PapN with phosphate head groups of LPS were key factors for binding. Similarly, hydrophobic interactions by aromatic residues of PapN with fatty acid chains in LPS were also significant for binding. These results may facilitate the development of peptide antibiotics with anti-inflammatory activity.

Development of Pressure Sensitive Paint(PSP) technique for low-speed flows and its application (아음속 저속 유동용 Pressure Sensitive Paint의 개발과 응용)

  • Kang, Jong-Hoon;Lee, Sang-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.4
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    • pp.12-17
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    • 2004
  • The PSP technique has been used to measure pressure distribution on model surfaces ins high-speed flows. The objective of this study is to develop a PSP technique which can be applied to low-speed aerodynamic flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was evaluated. In a static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The developed PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

Preparation and Behavior of High Performance Alkaline Cleaning Agents for Steel (철강용 고성능 알칼리세정제의 제조 및 세정거동)

  • Park, Hong-Soo;Jo, Hye-Jin;Shim, Il-Woo;You, Hyuk-Jae;Kim, Myung-Soo;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.1
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    • pp.15-20
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    • 2005
  • $Na_2CO_3$. Sodium orthosilicate (Na-OSi), Tetronix T-701 (T-701), Na-dioctyl sulfosuccinate (303C), Newpol PE-68 (PE-68), MJU-100A, and tetrasodium pyrophosphate were blended to prepare high performance alkaline cleaning agents (ACASs). The results of cleaning test with steel specimen showed that ACAS-6 ($Na_2CO_3$ 50g/Na-OSi 35g/T-701 20g/303C 18g/PE-68 17g/MJU-100A 10g/TSPP 20g/ water 180g mixture) had a good cleaning power. The cleaning power for press-rust preventing oil was 98% and 99% degreasing at 4wt%, $70^{\circ}C$ and $90^{\circ}C$, respectively ; for quenching oil, the cleaning power of ACAS-6 was 91% degreasing at 4wt% and $70^{\circ}C$. The foam heights measured immediately after foaming by Ross & Miles method and Ross & Clark method at 6wt%, $60^{\circ}C$ were 18mm and 65mm, respectively. It was concluded that ACAS-6 had a good low foaming cleaning agent.