• Title/Summary/Keyword: quaternary ammonium silyl polydimethplsiloxane

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Preparation and Properties of Siloxane Modified EPDM/HDPE/Carbon black Composite (실록산 변성 에틸렌프로필렌 고무/고밀도 폴리에틸렌/카본블랙 복합체의 제조와 물성)

  • Lee, Byoung-Chul;Kang, Doo-Whan
    • Polymer(Korea)
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    • v.31 no.1
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    • pp.80-85
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    • 2007
  • Maleic anhydride (MA) modified ethylene-propylene-diene terpolymer (MEPDM) was pre-pared from solution polymerization. MEPDM-g-PST copolymer was prepared by melt polymerization of male ate d EPDM and quaternary ammonium silyl polydimethylsiloxane -7,7,8,8- tetracyanoquinodimethane (TCNQ) adduct (PST) in internal mixer and MEPDM-g-PST/HDPE/CB (MPEC) was prepared by com-pounding HDPE, MEPDM-g-PST copolymer and carbon black (CB, 5, 10, 15, and 20 phr), and HDPE/ CB (PEC) by compounding HDPE and CB (5, 10, 15, and 20 phr), respectively. The structure of MEPDM-g-PST copolymer was confirmed by measuring the FTIR. The maximum grafting ratio of MA onto EPDM was 2.35%. The thermal and mechanical properties of the composites were measured and dispersion characteristics of CB in matrix show that CB in MPEC was better dispersed than that in PEC composite.