• Title/Summary/Keyword: pure state

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Performance Comparison of Cubic Equations of State With Two Temperature Dependent Parameters (두 개의 온도 의존 매개변수가 있는 3차 상태방정식의 성능비교)

  • Kwon, Young-Wook;Park, Kyoung-Kuhn
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.205-210
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    • 2001
  • Cubic equations of state with two temperature dependent parameters are suggested and optimized using ASHRAE data for methane, propane, carbon dioxide, R-32 and R-134a. Appropriate simple functional forms are assumed for the temperature dependent parameters. The equations tested are Martin, Fuller, Harmens-Knapp, Schmidt-Wenzel. Among them modified Schmidt-Wenzel equation of state appears to be the choice for calculation of saturation properties such as vapor pressures, saturated liquid volumes, and saturated vapor volumes with an average absolute deviation of about one percent over the entire region excluding; the near cirtical.

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An Asymptotic Analysis on the Inviscid Plane Stagnation-flow Solidification Problem (비점성 평면 정체 유동 응고 문제에 대한 점근적 해석)

  • Yoo, Joo-Sik;Eom, Yong-Kyoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.6
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    • pp.792-801
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    • 2000
  • The problem of phase change from liquid to solid in the inviscid plane-stagnation flow is theoretically investigated. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The transient solution is dependent on the three dimensionless parameters, but the equilibrium state is determined by one parameter of (temperature ratio/conductivity ratio). The effect of the fluid flow on the growth rate of the solid in the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state. The characteristics of the transient heat transfer at the surface of the solid and the liquid side of the solid-liquid interface for all the dimensionless parameters are elucidated.

Photodynamics of an excited triplet state in the presence of molecular oxygen cluster

  • Nishimura, Yoshinobu
    • Rapid Communication in Photoscience
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    • v.2 no.3
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    • pp.72-75
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    • 2013
  • Bulk nanobubble is one of the nanoscopic gaseous state found in the solution. We measured transient absorption spectra of eosin Y in the excited triplet state ($^3EY^{2-*}$) to elucidate differences in the dissipation process of the bulk nanobubble of oxygen molecule at air pressure. The time dependence of the oxygen dissipation process was classified three time domains (P1, P2 and P3). The comparison of ordinary bubbling method gave different results at P3 in contrast to similar results at P1 and P2, indicating the existence of characteristic dissolving state in the case of nanobubble.

A Study on Electrical Properties of Organic Thin Film (유기박막의 전기적 특성에 관한 연구)

  • Choi, Yong-Sung;Song, Jin-Won;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1327-1329
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    • 2006
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 2, 10, 30[mN/m](gas state, liquid state, and solid state). The physicochemical properties of the LB films on the surface of pure water are studied by AFM. Also, we then examined of the Metal-Insulator-Metal(MIM) device by means of I-V.

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The Effect of Vibrationally Excited Levels on the Pressure Saturation of the Collisional Quenching of the $^3B_1\;State\;of\;SO_2

  • Bae, S. C.
    • Bulletin of the Korean Chemical Society
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    • v.17 no.1
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    • pp.56-60
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    • 1996
  • The pressure saturation effect on the phosphorescence decay rates of the $^3B_1$ State of $SO_2$ has been reinvestigated by the laser induced phosphorescence method in pure $SO_2$. We have attempted to fit the pressure dependence of the phosphorescence decay rates using the radiationless transition model by introducing different coupling constants for each vibrational level ofthe 3B1 state. The experimental decay rates can be fitted well, when the coupling constants for the (0,0,0), (0,1,0) and (0,2,0) levels of the $^3B_1$ state are $7.2\;{\times}\;10^{-4}$, $2.2\;{\times}\;10^{-3}$ and $5.9\;{\times}\;10^{-3}\;cm^{-1}$, respectively.

A theoretical analysis on the inviscid stagnation-flow solidification problem (비점성 정체 유동 응고 문제에 대한 이론적 해석)

  • 유주식
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.1-11
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    • 2000
  • This study investigates the problem of phase change from liquid to solid in the inviscid stagnation flow. The solution of dimensionless governing equations is determined by the three dimensionless parameters of (temperature ratio/conductivity ratio), Stefan number, and diffusi-vity ratio. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The equilibrium state is dependent on (temperature ratio/conductivity ratio), but is independent of Stefan number and diffusivity ratio. The effect of fluid flow on the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state, and the characteristics of the solidification process for all the dimensionless parameters are elucidated.

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Correlation between Structures and Magnetism in Iron: Ferromagnetism and Antiferromagnetism

  • Lee, Dong-Kook;Hong, Soon-Cheol
    • Journal of Magnetics
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    • v.12 no.2
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    • pp.68-71
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    • 2007
  • Even a pure bulk Fe has a complicated magnetic phase and its magnetism is still needed to be clarified. In this study we investigated the magnetism of bcc and fcc bulk Fe with total energy calculations as functions of atomic volume. The full-potential linearized augmented plane wave method was adopted within a generalized gradient approximation. The ground state of bulk Fe is confirmed to be of ferromagnetic (FM) bcc. For fcc structured Fe an antiferromagnetic (AFM) state is more stable compared to FM states which exist as low spin and high spin states. The stable AFM states were found to accompany a tetragonal distortion, while the FM states remained in a cubic symmetry. At an expanded lattice constant a high spin FM state was calculated to be able to be stabilized with significant enhanced magnetic moment compared to the value of the ground state, bcc FM.

State-of-charge Estimation for Lithium-ion Batteries Using a Multi-state Closed-loop Observer

  • Zhao, Yulan;Yun, Haitao;Liu, Shude;Jiao, Huirong;Wang, Chengzhen
    • Journal of Power Electronics
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    • v.14 no.5
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    • pp.1038-1046
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    • 2014
  • Lithium-ion batteries are widely used in hybrid and pure electric vehicles. State-of-charge (SOC) estimation is a fundamental issue in vehicle power train control and battery management systems. This study proposes a novel model-based SOC estimation method that applies closed-loop state observer theory and a comprehensive battery model. The state-space model of lithium-ion battery is developed based on a three-order resistor-capacitor equivalent circuit model. The least square algorithm is used to identify model parameters. A multi-state closed-loop state observer is designed to predict the open-circuit voltage (OCV) of a battery based on the battery state-space model. Battery SOC can then be estimated based on the corresponding relationship between battery OCV and SOC. Finally, practical driving tests that use two types of typical driving cycle are performed to verify the proposed SOC estimation method. Test results prove that the proposed estimation method is reasonably accurate and exhibits accuracy in estimating SOC within 2% under different driving cycles.

Improved Rate Capability of Li/Li3V2(PO4)3 Cell for Advanced Lithium Secondary Battery

  • Lim, Hyun-He;Cho, A-Ra;Sivakumar, Nagarajan;Kim, Woo-Seong;Yoon, Won-Sub;Lee, Yun-Sung
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1491-1494
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    • 2011
  • Lithium vanadium phosphate, $Li_3V_2(PO_4)_3$ was prepared by a simple solid state route. It was found that making a fine powder of $Li_3V_2(PO_4)_3$ by the mechanical milling is very effective for increasing the insertion/extraction of lithium from $Li_3V_2(PO_4)_3$ structure. In charge/discharge test, the ball-milled $Li_3V_2(PO_4)_3$ sample exhibited a higher initial discharge capacity of 174 mAh/g in the voltage range of 3.0-4.8 V, compared with pure $Li_3V_2(PO_4)_3$ sample (152 mAh/g). Furthermore, the ball-milled $Li_3V_2(PO_4)_3$ presented not only higher cycle retention rate after 50 cycles, but also better rate capability compared with pure sample in the whole region (0.1-7 C).

The Oxidation of Magnetic Particles in Medicinal Ointment

  • Kim, Eng-Chan
    • Journal of Magnetics
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    • v.17 no.2
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    • pp.83-85
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    • 2012
  • Magnetic particles in a novel, wound-healing ointment were studied using M$\ddot{o}$ssbauer spectroscopy and VSM to estimate the stability of the properties of the magnetic particles. The isomer shifts of $Fe_3O_4(A)$ were found to be 0.49-0.56 mm/s relative to iron metal, this indicates that the iron ions in $Fe_3O_4(A)$ are $Fe^{3+}$. On the other hand, the isomer shifts of $Fe_3O_4(B)$ were found to be 0.91-1.13 mm/s relative to iron metal, this shows that the ion state of $Fe_3O_4(B)$ is a mixed state of $Fe^{2+}$ and $Fe^{3+}$. It is noted that this composition, as well as that of the initial pure component in the form of a highly dispersed fraction (${\sim}10\;{\AA}$), differs from the stoichiometric one. It was found that the area ratio of the M$\ddot{o}$ssbauer subspectra of $Fe_3O_4(A)$ / $Fe_3O_4(B)$ taken at 87 and 181 K linearly increased in comparison to the initial pure magnetic particles, but the rate of increase of the area ratio at 181 K was about two times that at 87 K. From the magnetic hyperfine field, despite their small size, the particles exhibit no superparamagnetism.