• 제목/요약/키워드: pure state

검색결과 552건 처리시간 0.026초

펜실바니아 유역 수질의 공간적 변이에 관한 연구 (Spatial Variations of Nutrient Concentrations in Pennsylvania Watersheds)

  • Chang, Heejun
    • 대한지리학회지
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    • 제37권5호
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    • pp.536-550
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    • 2002
  • 이 연구는 7년 동안의 수문, 기후, 수질자료를 이용하여 펜실바니아 38개 유역 수질의 공간적 변이 패턴을 고찰하였다. 연구기간동안 도시적, 농업적 토지이용이 많은 유역에서 농도의 변이가 심하게 나타났다. 질소의 농도는 농업적 토지이용과. 인의 농도는 도시적 토지이용과 상관관계가 높게 나타났다. 주성분분석을 통해 이들의 농도 변이를 설명하는 주요 성분 셋이 - 토지 지형관련, 기후관련, 규모 - 도출되었다. 부분 여분 분석을 통해 기후, 토지, 지형의 복합적인 영향이 질소 농도 변이의 28.1%를 설명하고 있으며, 순수한 토지 변수의 영향이 인 농도의 41.8 o/o를 설명하고 있음을 알 수 있었다. 주 전체적인 차원에서 농도변이의 뚜렷한 지리적 패턴-북서부지역의 낮은 농도와 남동부지역의 높은 농도-이 나타나고 있으며, 이는 지역적 규모에서 수문, 기후, 토지이용, 지형 등 여러 가지 환경변수의 복합적인 상호관련성을 반영하고 있다.

레늄카보닐에 의한 고활성 메타세시스 촉매제조 및 그의 촉매작용 (Preparation of Highly Active Metathesis Catalyst from Rhenium Carbonyl and its Catalysis)

  • 안호근
    • 공업화학
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    • 제9권1호
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    • pp.115-120
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    • 1998
  • 메타세시스에 높은 활성을 나타내는 고분산 레늄촉매을 제조하기 위한 레늄카보닐 침착의 표면화학 및 활성점 생성에 관하여 연구하였다. 알루미나는 773K(PDA)와 1223K(DA)에서 각각 처리하여 담체로 사용하였고, 메타세시스 활성은 순수한 프로펜을 사용하여 상압하의 298K에서 조사하였다. PDA상의 레늄 산화가는 상당히 높았으나, DA에서는 저산화가의 레늄으로 담지되어 있었다. 제조한 Re/DA촉매를 고온에서 열분해시킨 다음 저온에서 산소로 처리하면 메타세시스 활성이 나타났고, 그 활성은 극히 낮은 담지율에서도 Re/PDA이나 통상의 $Re_2O_7/Al_2O_3$촉매에 비해 높은 활성을 보여, 레늄 카보닐을 출발물질로 하고 DA를 사용하는 것이 효과적이었다. 열분해하여 얻은 Re/DA촉매상의 레늄이온은 알루미나의 산소원자 2개와 결합하여 2가를 가지고, 산소처리에 의하여 4가만큼 증가한 6가의 레늄이온이 되며, 메타세시스는 그 6가이온에 의해 생성된 카르벤착체를 통하여 진행됨을 알았다.

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수동급기 직접 메탄올 연료전지의 동적 모델 (Dynamic Model of a Passive Air-Breathing Direct Methanol Fuel Cell)

  • 하승범;장익황;차석원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.33-36
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    • 2008
  • The transient behavior of a passive air breathing direct methanol fuel cell (DMFC) operated on vapor-feeding mode is studied in this paper. It generally takes 30 minutes after starting for the cell response to come to its steady-state and the response is sometimes unstable. A mathematical dynamic one-dimensional model for simulating transient response of the DMFC is presented. In this model a DMFC is decomposed into its subsystems using lumped model and divided into five layers, namely the anodic diffusion layer, the anodic catalyst layer, the proton exchange membrane (PEM), the cathodic catalyst layer and the cathodic diffusion layer. All layers are considered to have finite thickness, and within every one of them a set of differential-algebraic governing equations are given to represent multi-components mass balance, such as methanol, water, oxygen and carbon dioxide, charge balance, the electrochemical reaction and mass transport phenomena. A one-dimensional, isothermal and mass transport model is developed that captures the coupling between water generation and transport, oxygen consumption and natural convection. The single cell is supplied by pure methanol vapor from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The water is not supplied from external source because the cell uses the water created at the cathode using water back diffusion through nafion membrane. As a result of simulation strong effects of water transport were found out. The model analysis provides several conclusions. The performance drop after peak point is caused by insufficiency of water at the anode. The excess water at the cathode makes performance recovery impossible. The undesired crossover of the reactant methanol through the PEM causes overpotential at the cathode and limits the feeding methanol concentration.

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이상적인 음료수 공급을 위한 수질관리에 관한 연구 (Study on the Water Management to get High Quality of Drinking Water)

  • 김형석;신현덕;박경석
    • 환경위생공학
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    • 제6권1호
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    • pp.7-25
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    • 1991
  • Until now, pure drinking water grnerally menas the water without taste, odor, general bacteria, coliform, and other exotic substance. Such a definition has been changing recently due to the finding of numerous other inorganic and organic substances unknown to us. 10 years ago, major causes of death were infectious agents and parasites contained in water, but recently, it has become apparent that some substances contained in drinking water cause cancer and heart diseases. We must drink about 2L of water everyday in order to maintain healthy condition. Waters used for drinking include tap water, well water, spring water, filtered water, etc., but the quality of drinking water has more polluted due to the industrial development and population increase. For example, industrial waste waters from industrial plants pollute the water supply sources ; toxic substances contained in the waste waters pollute the ground water sources by penetrating the geological strata, and municipal, livestock, public building waste waters also pollute the water supply sources. Sometimes, the polluted surface waters were announced to be polluted by various kinds of orgainc substance, and it is reported that the pollution of ground water by orga nic substances has few in number but high in its concectration comparing with those of surface water. As the water quality pollution level increases, so the amount of disinfectant also increase. For example, chlorine solution, one of widely used disinfectants, creates trihalomethane(THM), a carcinogen, and halogen compounds. According to Oliver, through chlorine disinfection process, humine substance and chlorine create bolatile organic halide and nonvolatile organic halide by chemical reaction. There are tens or hundreds filtering devices, but filtering principles and maintenance metjhods are different, so their efficiency tests are needed. According to Smith, the effeciency tests aginst over 30 Ameican filtering devices show that 10 devices can remove 85% of volatile organics and further studies on filtered waters are underway. In consideration of important impacts of polluted drinking water on national health, authors studied the state of water quality pollution against tap water used as drinking water, filtration device passed water, ground water, and conserved drinking water ; tested the efficiency of filtration devices for tap water ; tried to sep up the detection method by using ion chromatography based on negative ion and positive ion by using single column, and attemped the simple filtration method for general households.

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SPECTROSCOPIC AND CHEMOMETRIC ANALYSIS OF SW-NIR SPECTRA OF SUGARS AND FRUITS

  • Golic, Mirta;Walsh, Kerry;Lawson, Peter
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1133-1133
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    • 2001
  • Fruit sweetness, as indexed by total soluble solids (TSS), and fruit acidity are key factors in the description of the fruit eating quality. Our group has been using short wave NIR spectroscopy (SW-NIR; 700-1100 nm) in combination with chemometric methods (PLS and MLR) for the non-invasive determination of the fruit eating quality (1,2). In order to further improve calibration performance, we have investigated SW-NIR spectra of sucrose and D-glucose. In previous reports on the band assignment for these sugars in the 1100-2500 nm spectral region (3-7), it has been established that change in concentration, temperature and physical state of sugars reflects on the shape and position of the spectral bands in the whole NIR region(5-7). The effect of change in concentration and temperature of individual sugar solutions and sugar spiked Juice samples was analysed using combined spectroscopic (derivative, difference, 2D spectroscopy) and linear regression chemometric (PLS, MLR) techniques. The results have been compared with the spectral data of a range of fruit types, varying in TSS content and temperature. In the 800-950 nm spectral region, the B-coefficients for apples, peaches and nectarines resemble those generated in a calibration of pure sucrose in water (Fig. 1). As expected, these fruits exhibit better calibration and prediction results than those in which the B-coefficients were poorly related to those for sugar.(Figure omitted).

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MnO2 첨가가 0.985[Li0.04(Na0.545K0.46)0.96(Nb0.81Ta0.15Sb0.04)]O3+0.015KNbO3 세라믹스의 유전 및 압전 특성에 미치는 영향 (Effect of MnO2 Addition on Dielectric and Piezoelectric Properties of 0.985[Li0.04(Na0.545K0.46)0.96(Nb0.81Ta0.15Sb0.04)]O3 Ceramics)

  • 김유석;류주현
    • 한국전기전자재료학회논문지
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    • 제27권6호
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    • pp.361-366
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    • 2014
  • $MnO_2$-doped $0.985[Li_{0.04}(Na_{0.545}K_{0.46})_{0.96}(Nb_{0.81}Ta_{0.15}Sb_{0.04})]O_3+0.015KNbO_3(0.985LNKNTS+0.015KNbO_3)$ lead-free ceramics were fabricated by conventional solid state method to develop excellent dielectric and piezoelectric properties. The result of X-ray diffraction patterns obviously indicated that all of the specimen has pure perovskite structure without secondary phase. In addition, orthorhombic phase and coexistance region of orthorhombic-tetragonal phase (MPB) were observed with amount of $MnO_2$. The optimal values of ${\rho}$=4.70 $g/cm^3$, $d_{33}=238$ pC/N, $k_P=0.46$, $Q_m=121$, ${\varepsilon}_r=849$, and $T_C=225^{\circ}C$ were obtained at 0.01 mol% $MnO_2$ doped $0.985LNKNTS+0.015KNbO_3$ ceramics sintered at $990^{\circ}C$ for 5 h, respectively. Hence, it was indicated that the suitable amount of $MnO_2$ could improve the electrical properties of $0.985[Li_{0.04}(Na_{0.545}K_{0.46})_{0.96}(Nb_{0.81}Ta_{0.15}Sb_{0.04})]O_3+0.015KNbO_3$ ceramics.

Fe2O3첨가에 따른 (Na,K,Li)(Nb,Sb,Ta)O3계 세라믹스의 압전 및 유전 특성 (Piezoelectric and Dielectric Properties of (Na,K,Li)(Nb,Sb,Ta)O3 Ceramics as a Function of Fe2O3 Addition)

  • 이광민;신상훈;류주현
    • 한국전기전자재료학회논문지
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    • 제27권9호
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    • pp.555-560
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    • 2014
  • In this paper, in order to develop outstanding Pb-free composition ceramics, the $Fe_2O_3$-doped ($Na_{0.525}K_{0.443}Li_{0.037}$)($Nb_{0.883}Sb_{0.08}Ta_{0.037}$)$O_3$ + 0.3 wt% $Bi_2O_3$ + x wt% $Fe_2O_3$ (x= 0~1.0 wt%)(abbreviated as NKL-NST) lead-free piezoelectric ceramics have been synthesized using the ordinary solid state reaction method. The effect of $Fe_2O_3$-doping on their microstructure and electrical properties were investigated. XRD diffraction pattern studies confirm that $Fe_2O_3$ completely diffused into the NKL-NST lattice to form a new stable soild solution with $Fe^{3+}$ entering the $Nb^{5+}$, $Sb^{5+}$ and $Ta^{5+}$ of B-site. And, phase structure of all the ceramics exhibited pure perovskite phase and no secondary phase was found in the ceramics. The ceramics doped with 0.6 wt% $Fe_2O_3$ have the optimum values of piezoelectric constant($d_{33}$), planar piezoelectric coupling coefficient($k_p$) and mechanical quality factor($Q_m$) : $d_{33}$ = 233 [pC/N], $k_p$= 0.44, $Q_m$= 95. These results indicate that the ($Na_{0.525}K_{0.443}Li_{0.037}$)($Nb_{0.883}Sb_{0.08}Ta_{0.037}$)$O_3$ +0.3 wt% $Bi_2O_3$ + 0.6 wt% $Fe_2O_3$ ceramic is a promising candidate for lead-free piezoelectric ceramics.

분산 웹 서버 시스템에서의 DNS 기반 동적 부하분산 기법 (DNS-based Dynamic Load Balancing Method on a Distributed Web-server System)

  • 문종배;김명호
    • 한국정보과학회논문지:시스템및이론
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    • 제33권3호
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    • pp.193-204
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    • 2006
  • 대부분의 분산 웹 시스템은 Domain Name System(DNS)을 이용하여 사용자 요청을 분산한다. DNS 기반 부하분산 시스템은 구성하기 쉬운 장점이 있지만, 주소 캐싱 매커니즘에 의해 서버들 사이의 부하 불균형이 발생한다. 또한, 서버의 상태를 파악하기 위해서 DNS의 수정이 필요하다. 본 논문에서는 DNS의 동적 갱신(dynamic update)과 라운드로빈 방법을 이용한 새로운 부하분산 기법을 제안한다. 본 논문에서 제안하는 방법은 DNS의 수정 없이 동적인 부하분산을 한다. 본 논문에서 제안하는 시스템은 서버의 부하량에 따라 서버를 DNS 리스트에 동적으로 추가, 삭제한다. 부하가 많은 서버를 DNS 리스트에서 제거함으로써 사용자 응답시간이 빠르다. 동적인 부하분산을 위하여 CPU와 메토리 네트워크 자원의 사용률에 따른 부하분산 알고리즘을 제안한다. GUI 기반의 관리도구를 이용하여 손쉽게 제안하는 시스템을 관리할 수 있다. 실험을 통하여 본 논문에서 구현한 모듈들이 제안된 시스템의 성능에 많은 영향을 주지 않는다는 것을 보여준다. 또한 기존 라운드로빈 DNS와의 비교실험을 통하여 사용자 응답시간과 파일전송률이 더 빠르다는 것을 보여준다.

무채색 무늬가 포함된 배경색의 파스텔색상에 따른 뇌파반응 (Brain Waves Evoked by the Changes of Background Pastel Colors with a Pattern of Achromatic Color)

  • 이희란;김소영;김기성;홍경희
    • 한국의류산업학회지
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    • 제19권5호
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    • pp.653-660
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    • 2017
  • Recently, consumers' evaluation and purchase of online design has been increasing due to the popularization of designing through personal computers, but there has not been enough studies on consumers' brain wave responses depending on the change of PC monitor's color. Therefore, this study investigated how brain waves changed when different background colors with gray patterns were presented through PC monitors. Six background colors with same tone of slightly low saturation were selected, including ivory, yellow, pink, green, blue and pure white as a base color. The brightness and characteristics of color used were analyzed using the luminance meter and color scales. Brain wave was measured by EEG measurement equipment. Brain wave measurement was carried out with 9 subjects at 6 points: F3, F4, T3, T4, O1, and O2. Stimuli were shown for 15 seconds each and black screens were displayed for 15 seconds between each stimulus. As results, the brain waves at O1 responded sensitively by different background colors, followed by F4 and T4. Brain index such as 'RT', 'RA', 'RG', 'RSA', and 'RAHB' showed significant differences depending on the background color at O1, whereas 'RST' differed at F4. Yellow and blue backgrounds pair was the only stimuli that showed significant differences in six brain indices mentioned. Yellow background had higher value of 'RG' at O1 and higher 'RST' at F4, indicating yellow background enhanced concentration. Blue background activated 'RT', 'RA', 'RSA', 'RAHB' at O1, meaning blue background induced calm and stable state.

LaFeO3 함량에 따른 (1-x)Bi0.5(Na0.78K0.22)0.5TiO3-xLaFeO3의 강유전, 압전 특성 (Effect of LaFeO3 Doping on the Ferroelectric and Piezoelectric Properties of Bi0.5(Na0.78K0.22)0.5TiO3 Lead-Free Piezoceramics)

  • 박춘길;임지호;박정수
    • 한국전기전자재료학회논문지
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    • 제30권3호
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    • pp.157-161
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    • 2017
  • $(1-x)Bi_{0.5}(Na_{0.78}K_{0.22})_{0.5}TiO_3-xLaFeO_3$ ceramics were fabricated using a solid state reaction method. The microstructural, ferroelectric and piezoelectric properties were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and polarization hysteresis loops (P-E). XRD results indicated that BNKT ceramic crystal structure modified by $LaFeO_3$ was transformed from a ferroelectric tetragonal to a non-polar pesudo-cubic phase with increased $LaFeO_3$ content. The improved piezoelectric properties resulted from the addition of $LaFeO_3$ up to 3 mol%. The $LaFeO_3$ 3mol% sample showed markedly improved piezoelectric and strain behaviors in comparison with pure BNKT ceramic.