• 펄프종이기술
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• 제46권6호
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• pp.71-77
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• 2014

Despite the ubiquity of electronic media, paper is still the most generally readable carrier of information. Because paper materials are deteriorated by chemical, biological and physical factors over time, there have been major concerns about the decay of large collections of books, publications, old maps, historical artifacts, and written records. Therefore, manufacture of permanent paper has been a highly debated issue in paper conservation research. Through the use of permanent paper, our new records, journals, library books, art works, and all culturally and historically important documents can be preserved. In this study, handsheets were made of mixture of hemp bast fiber produced by soda pulping and HwBKP varying the amount of hemp. Physical, mechanical and optical properties of each handsheet were examined. As the ratio of hemp bast fiber increased, mechanical properties were improved significantly, but opacity decreased. After aging, the optical properties of the handsheets mixed with the hemp bast fiber more decreased than those of the non-mixed handsheet. The more mixture ratio of hemp bast fiber increased, the more decreasing rate of optical properties increased. As a result, it was confirmed that hemp bast fiber is a very promising resource for the manufacturing of permanent paper.

• 한국산학기술학회논문지
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• 제17권6호
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• pp.729-736
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• 2016

지구 환경 보존이라는 관점에서 폐지류의 재활용 및 자원화 노력이 절대적으로 필요하다. 폐지 재활용은 잉크 제거의 효과에 따라 기술력이 좌우된다. 기존 고체 탈묵제의 잉크 제거 효울을 개선하기 위해 액상 탈묵제를 지방산 종류에 따라 검화 반응시키고 EO/PO를 추가 혼합하여 제조하였다. 제조된 탈묵제를 폐지 재활용 공정에 투입하고 각각 펄핑 공정 (시료 조성 ONP : OMG = 5 : 5, 농도 15%, 온도 $45^{\circ}C$, 펄핑 시간 20분) 과 flotation 공정 (농도 1%, 온도 $45^{\circ}C$, air flow 7 L/min, 반응시간 8분) 처리 전, 후의 ERIC과 brightness를 측정하여 잉크의 제거 효율을 평가하였다. 또한 hyperwashing 전, 후의 ERIC과 brightness도 측정하여 잉크의 재흡착 여부도 평가하였다. 포화 지방산 Lauric acid 보다 불포화 지방산 Oleic acid를 $80^{\circ}C$에서 KOH로 검화 반응시키고 EO/PO를 추가 혼합하여 액상 탈묵제를 대량 제조하였다. 대량 생산한 액상 탈묵제는 제지 회사의 탈묵 공정 현장에 직접 투입하였을 때, 거품의 사이즈가 커지고 reject의 색깔이 짙어지면서 잉크의 포집력이 좋아진 것을 확인할 수 있었다. flotation 전, 후 백색도는 4 point 정도 증가하던 것이 약 5 point로 1 point 정도가 더 증가였다. reject의 ERIC 값은 개발 제품을 사용했을 때 약 7%정도 낮아진 것을 확인할 수 있었다. 본 연구에서 개발한 액상 탈묵제의 탈묵 성능이 우수함을 알 수 있었다.

• 펄프종이기술
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• 제41권3호
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• pp.66-70
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• 2009

Paper cultural heritages usually experienced the chemical and the physical deterioration because of various factors including preservation environment and the property of their materials. General restoration technology for paper cultural heritages is the lining. The application of the lining paper and the lining technology has varied depending on researcher's experiences. Therefore, each lining material and technology must be evaluated to develop a standard guide for preservation and restoration of paper cultural heritages. To date, various analysis techniques using lining paper, in terms of their materials, have been applied to analyses of causes and condition of damages, but it is difficult to develop a standard restoration treatment method of paper cultural heritages because it varies by their material. The Hanf, is made frrr the mulberry, is generally used for the lining in Korea.edt is required that the cr, in terms properties and general properties of Hanf, is used for lining papers, are evaluated to develop a standard guide for their restoration.ed this study, the general properties of several lining papers(Hanf), especially dimensave bility, were evaluated as part of the standardization of lining papers. The result have varied depending on the pulping chemical and the manufacturers. the basis weight, thickness and tensale strength of lining papers is bigger the paper treated by natural ash than the paper treated by sodium carbonate.ed case of formation, folding endurance, and dimensave bility, the paper treated by sodium carbonate showed better properties than those of the paper treated by natural ash.

• 한국의류학회지
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• 제32권9호
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• pp.1366-1375
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• 2008

This studies were carried out in order to develope environmentally-friendly fiber materials and substitute resources of Paper mulberry. Various plant fibers such as New Zealand flax, Indian mallow, Kuzu vine and Yucca were used as raw materials of hand-made papers. We rotted these 4 kinds of plant fibers and removed non-cellulose. After rotting, the pulping rate(%) and the length of fibers in pulps were measured. The physical characteristics of papers made of various plants fiber were investigated and the probabilities of practical use were considered. The results were as follow: The non-cellulose contents of plant fibers were $30{\sim}40%$ and those contents must be lower down to 8% to be able to manufacture the hand made papers. The lignin in pulps were removed almost and the hemicellulose were partially removed to reach up to appropriate level of the pulp rates and fiber lengths. The more hemicellulose removed, the finer fiber thickness were and rapidly the lower Hanji tensile strength were. But the tear strength of these plants of hand-made papers do not decreased so much as tensile strength. So the property of 4 types of plant fibers might be of great advantages to make hand-made papers. Both tensile and tear strengths of Hanji of New Zealand flax, Indian mallow, Kuzu vine and Yucca were higher than Paper mulberry hand-made paper. When 30% of mulberry paper were mixed, the mixing effect showed maximum. Because of the functions of all plant fiber hand-made papers showed better than those of Paper mulberry hand-made paper, 4 types of plant fibers could be substitute Paper mulberry.

• 한국산림과학회지
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• 제53권1호
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• pp.44-55
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• 1981

중성(中性)아황산소오다 전처리(前處理)한 젓나무로부터 가압(加壓)리화이닝법(法)에 의해 고수율(高收率)펄프를 제조(製造)함에 있어서 리화이닝온도(温度)가 섬유(纖維)의 표면구조(表面構造) 및 펄프시트의 강도(強度)에 미치는 영향(影響)을 검토(檢討)하여 다음과 같은 결과(結果)를 얻었다. 전처리수율(前處理收率)(84%, 92% 및 100%) 및 리화이닝온도(温度)($20^{\circ}C$, $120^{\circ}C$ 및 $180^{\circ}C$)는 펄프의 수율(收率), 고해성(叩解性), 펄프 시트의 강도(強度) 및 섬유(纖維)의 표면구조(表面構造)에 미치는 영향(影響)이 현저(顯著)하였으며, 특히 펄프수율(收率)과 고해성(叩解性)은 리화이닝온도(温度)가 상승(上昇)함에 따라 감소(減少)하였다. 전처리수율(前處理收率) 84%의 미고해(未叩解)펄프의 섬유표면(纖維表面)이 거의 2차벽(次壁)으로 싸여있음이 확인(確認)되었으며, 반면(反面) 전처리수율(前處理收率) 92%의 펄프는 복합세포중간층(複合細胞中間層)으로 대부분(大部分) 덮여있었다. 미처리(未處理) 펄프의 경우는 섬유(纖維)의 손상(損傷)이 심하였으며 섬유표면(纖維表面)은 2차벽(次壁)과 복합세포중간층(複合細胞中間層)이 거의 같은 정도로 노출(露出)되어 있었다. 전처리수율(前處理收率)이 높은 펄프(92% 및 100%)의 경우는 리화이닝온도(温度) 및 여수도(濾水度)가 달라지더라도 밀도(密度)와 펄프시트의 강도(強度)와의 사이에는 직선적(直線的)인 비례관계(比例關係)가 성립(成立)하였으며 고온(高温)리화이닝한 것이 실온(室温)리화이닝한 펄프보다 강도(強度)가 우수(優秀)하였다. 수율(收率)이 84%정도로 강(強)하게 전처리(前處理)한 경우 동일(同一)한 밀도(密度)에서 비교(比較)하였을때 시트강도(強度)는 실온(室温)리화이닝한 펄프가 고온(高温)리화이닝한 것보다 우수(優秀)하였다. 이는 전자(前者)가 후자(後者)보다 보수도(保水度)가 높은 미세섬유(微細纖維)를 더많이 함유(含有)한 때문으로 결론(結論)지울수 있다. 또한 섬유장분포(纖維長分布)에 있어서는 리화이닝온도(温度)에 따른 근소한 차(差)가 인정(認定)되었으나 섬유(纖維)의 표면구조(表面構造)는 거의 유사(類似)하였다.