• Title/Summary/Keyword: pulp properties

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Non-chlorine Bleaching of Oak Kraft Pulp by Ozone (오존을 이용한 신갈나무 크라프트펄프의 무염소표백)

  • 김동호;백기현
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.2
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    • pp.36-45
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    • 1997
  • Newly bleaching sequence using oxygen, ozone and hydrogen peroxide has introduced to avoid pollution hazards from chlorinated organic compounds, because chlorine dioxide substitution bleaching was produced a little chlorinated organic substance. Oxygen-type chemicals replaced for chlorine has attracted much research attention. Bleachability of ozone was improved at low temperature and high pulp consistency. In third bleaching followed OZ bleaching, addition of O2 and NaBH4 in alkali extraction was effective than only alkali extraction. Bleachability of pulps in ozone bleaching(Z) was improved at higher consistency and lower temperature The addition O2 and NaBH4 in alkali extraction after OZ bleaching sequence improved brightness, when compared to those obtained by only alkaline extraction. Pulps bleached by ECF bleaching sequences such as OZEoD and OZEopD was obtained by 90% ISO brightness. The brightness of pulp bleached by TCF sequences with the ozone dosage of 1.6% was approached to target brightness (88~90%ISO). Pulps bleached Z stage combined bleaching sequence was reduced the viscosity to a little greater extent. However, physical properties of pulps was not great different compared to those bleached by conventional bleaching sequences. A pollution index of bleaching effluente by ozone combined bleaching sequences was lower than by conventional bleaching sequence, but somewhat higher than multistage bleaching sequences combined C/D stage.

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Elemental Chlorine free Bleaching of Kraft Pulps with Enzymes( I )-Oakwood Kraft Pulp- (효소를 이용한 크라프트펄프의 무감소표백-신갈나무 크라프트펄프-)

  • 강진하;박성종;임현아
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.1
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    • pp.44-58
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    • 1998
  • This study was carried out to bleach the Oakwood kraft pulp without the elemental chlorine using the xylanase or wastewater(We : wastewater enzymes) effluented from the submerged biofilter reactor containing the fungi, Phanerorhaete sordida YK-624. So in this research, the proper treatment conditions (pH, temperature, dosage and time) were investigated respectively. And after the various kinds of multistage bleaching of pulps, the properties of pulps were tested. From the experimental results, we can conclude as follows. In the treatments of Oakwood kraft pulps with xylanase, the proper pH, temperature, enzyme dosage and time were 8.0, $35^{\circ}C$ , 400 EXU/kg and 1 hr. respectively. And in the case of treatment with a wastewater(We) effluented from the submerged biofilter reactor, the proper pH, temperature and time were 5.5, $37^{\circ}C$ and 2 hr. respectively. On the other hand, Oakwood kraft pulps were bleached by the method of a multistage bleaching using xylanase or We instead of elemental chlorine Consequently the strengthes and brightnesses of pulps bleached by the method mentioned above were lower than those of pulp bleached by the conventional method using the elemental chlorine. But it is possible to improve the brightnesses through the increase of chlorine dioxide dosage or use of hydrogen peroxide in the final bleaching stage.

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A Study on the Mechanical Properties of Hanji for Application of Automobile Fuel Filter (자동차 연료필터 적용을 위한 한지의 물리적 특성 연구)

  • Kim, Hyun-Chel;Jeon, Cheol
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.04a
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    • pp.191-197
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    • 2008
  • In this study, as a fuel filter for automobiles, base paper which can filtrate the polluted particles must satisfy with the standards of each vehicle. and a filter of impregnation paper made that combining the base paper with the resin. Therefore, They were wanted to found out the factors that affect base paper and impregnation paper according to content of HPZ, Mulberry pulp(MP), Laub holze bleached kraft pulp(LBKP). The most important things we wanted to find out in base paper and impregnation paper test were weight, thickness, air permeability, burst and tensile strength, maximum pore size and mean pore size, stiffness. we wanted to measure a rate of change of these condition by adjusting a rate of mixing for HPZ, MP and LBKP. Moreover, It suited for an impregnation paper mixed with a rate of mulberry pulp 20%, HPZ 40% and LBKP 40%. Used resins in this study was Phenol, Acryl, PVAc. And as every resins, sample was divided into existence and nothing of embossing. as a fuel filter for automobiles, It was appeared that the suitable condition of base paper was a rate of mixing for HPZ(40%), MP(20%) and LBKP(40%).

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Elemental Chlorine Free Bleaching of Kraft Pulps with Enzymes(II) -Pinewood Kraft Pulp- (효소를 이용한 크라프트펄프의 무감소표백(제2보) -소나무 크라프트펄프-)

  • 강진하;박성종;정인수
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.84-96
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    • 1998
  • This study was carried out to bleach the Pinewood kraft pulp without the elemental chlorine using the xylanase or wastewater(We:wastewater enzymes) effluented from the submerged biofilter reactor containing the fungi, Phanerochaete sordida YK-624. So in this research, the proper treatment conditions(pH, temperature, dosage and time) were investigated respectively. And after the various kinds of multistage bleaching of pulps, the properties of pulps were tested. From the experimental results, we can conclude as follows. In the treatments of Pinewood kraft pulps with xylanase, the proper pH, temperature, enzyme dosage and time were 8.0, $35^{\circ}C, 400EXU/kg and 3 hr. respectively. And in the case of treatment with a wastewater(We) effluented from the submerged biofilter reactor, the proper pH, temperature and time were 5.0, $37^{\circ}C and 3 hr. respectively. On the other hand, Pinewood kraft pulps were bleached by the method of a multistage bleaching using xylanase or We instead of elemental chlorine. Consequently, the strengthes and brightnesses of pulps bleached by the method mentioned above were lower than those of pulp bleached by the conventional method using the elemental chlorine. But it is possible to improve the brightnesses through the increase of chlorine dioxide dosage or use of hydrogen peroxide in the final bleaching stage.

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Use of Waste Woods for Developing Environment-friendly Shock-absorbing Materials

  • Kim, Chul-Hwan;Song, Dae-Bin;Lee, Young-Min;Kim, Jae-Ok;Kim, Gyeong-Yun;Shin, Tae-Gi;Park, Chong-Yawl
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.475-478
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    • 2006
  • Environment-friendly shock-absorbing materials were made using a vacuum forming method from waste wood collected from local mountains in Korea. The waste wood was pulped by thermomechanical pulping. The TMP cushions showed superior shock-absorbing properties with lower elastic moduli compared to EPS and pulp mold. Even though the TMP cushions made using different suction times had many free voids in their inner fiber structure, their apparent densities were a little higher than EPS and much lower than pulp mold. The addition of cationic starch improved the elastic modulus of the TMP cushions without increasing the apparent density, which was different from surface sizing with starch. The porosity of the TMP cushions was a little greater than EPS and much less than pulp mold. Finally, the TMP cushions have great potential to endure external impacts occurring during goods distribution.

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Effects of Fiber Wall Thickness on Paper Properties Using CLSM (CLSM을 이용한 고해과정 중 섬유벽 두께 변화의 종이 특성 영향 분석)

  • 김서환;박종문;김철환
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.39-45
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    • 1999
  • Refining in papermaking plays an important role in changing fiber properties as well as paper properties. The major effects of refining on pulp fibers are internal and external fibrillation, fiber shortening, and fines formation. Many workers showed that internal fibrillation of the primary refining effects was most influential in improving paper properties. In particular, refining produces separation of fiber walls into several lamellae, thus causing fiber wall swelling with water penetration. This leads to the increase of fiber flexibility and of fiber-to-fiber contact during drying. If the fibers are very flexible, they will be drawn into close contact with each other by the force of surface tension as the water is removed during the drainage process and drying stages. In order to study the effect of fiber wall delamination on paper properties, cross-sectional image of fibers in a natural condition had to be generated without distortion. Finally, it was well recognized that confocal laser scanning microscope (CLSM) could be one of the most efficient tool for creating and quantifying fiber wall delamination in combination with image analysis technique. In this study, the CLSM could be used not only to observe morphological features of transverse views of swollen fibers refined under low and high intensity, but also to investigate the sequence of fiber wall delamination and fiber wall breakage. From the CLSM images, increasing the specific energy or refining decreased the degree of fiber collapse, fiber cross-sectional area, fiber wall thickness and lumen area. High intensity refining produced more external fibrillation.

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Studies on the Multi-layered Coated Paper(II) -Effects of Binder in Pre-coated Layer on Properties of Top-coated Layer- (다층 도공지에 관한 연구(II) - 프리코팅층의 바인더가 탑층에 미치는 영향 -)

  • Choi, Ki-Soon;Shin, Woo-Seul;Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.443-453
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    • 2011
  • This study was carried out in order to elucidate effects of types of binder used in pre-coated layer on optical properties and printability of top-coated layer. Coated papers with four different types of SB latex were prepared. Tg, particle size and gel contents of latices were of different. Optical properties and printability of coated paper including print mottle were evaluated. It was confirmed that properties of pre-coated layer distinctively affected final properties of top-coated layer. Tg was found to be the most influencing factor on the print mottle of coated paper: the SB latex with lower Tg and higher particle size resulted in a superior print mottle. These results indicate that final printability and properties of top-coated layer can be controlled by adjusting pre-coated layer.

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Physical and Strength Properties of Frankincense Resin Treatment Paper (유향수지 처리지의 물리 및 강도적 특성)

  • Kim, Jong-Min;Yoon, Seung-Lak;Jo, Jong-Soo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.6
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    • pp.26-33
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    • 2014
  • Frankincense resin was applied to Hanji to improve its physical properties. The resin-treated paper showed the increasement of physical properties such as weight, thickness, and density. The highest increasement in weight and density of resin-treated paper were found at 30% treatment concentrations and the largest values of density were $41g/m^2$ Hanji. With the increasement of concentration, the brightness was decreased and transparency was improved. Of the mechanical properties of the paper, the tensile index and burst index showed the improved values. The tear index, however, was decreased. The frankincense resin showed the highest result in the tensile index of resin-treated paper and the basis weight of $41g/m^2$ Hanji. The air resistance of the resin-treated paper got improved with the increase of the concentration and $105g/m^2$ Hanji showed the highest values. The highest improvement in air resistance may make the resin-treated Hanji possible to use for semipermeable materials.

Effects of Optical Brightening Agents on Aging Characteristics of Paper (형광증백제가 종이의 열화 특성에 미치는 영향)

  • Choi, Kyoung-Hwa;Lee, Jae-Hun;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.6
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    • pp.87-93
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    • 2014
  • Optical brightening agents (OBA) is generally used to improve the optical property of printing paper in the paper industry. However, effects of OBA addition on paper preservability has been not fully understood yet. Therefore, this study was aimed to investigate effects of a OBA on the aging characteristics of paper. The OBA treatment of three different types was performed by dipping a filter paper into each a OBA solutions of different concentrations. The filter papers applied with a OBA were artificially aged at 80oC and 65% RH, and their optical and mechanical properties were evaluated. It was found that application of OBAs influenced the aging characteristics of paper. Especially, after aging, the optical and mechanical properties of the filter paper treated with the tetra-type OBA were more significantly decreased than those of the non-treated filter paper. The more the concentration of the tetra-type OBA increased, the more decreasing rate of optical and mechanical properties of the filter paper. While, in case of di-type OBA and hexa-type OBA, paper optical and mechanical properties were slightly decreased or not changed with a OBA treatment.

Effects of PCC Loading at Thick Stock on the Paper Properties (고농도 지료에서의 PCC 충전이 종이 물성에 미치는 영향)

  • Won, Jong-Myoung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.4
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    • pp.62-68
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    • 2012
  • This study was carried out to evaluate the effect of PCC loading at thick stock on the physical properties of paper. The effect of starch addition(2, 4 and 6%) and mixing time(5, 10 and 20 min.) on the filler retention and paper properties were investigated. Optimum dosage of cationic starch as a fixing agent was 4%, and mixing time did not showed any significant effect on the filler retention. PCC loading at thick stock was more effective to improve bulk and opacity than PCC loading at thin stock, although their improvement was not so significant. It was also found that the strength properties could be improved by the loading at thick stock. PCC loading method at thick stock could be considered as one of potential approaches for further improving of paper properties, although further research works are required in order to apply the PCC loading at thick stock in the paper mill.