• 펄프종이기술
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• 제30권4호
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• pp.28-34
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• 1998

Polyvinyl acetate emulsion has been widely used as adhesives for wood and paper, paint additives and binders for fiber, leather, and other materials because it is an excellent adhesive with many advantages including low in toxicity risks and manufacturing cost. It is expected the consumption of polyvinyl acetate emulsion as adhesives will increase in cigarette industry as well as in paperboard coating industry. Recently the operation speed of the cigarette tip wrapper increased so substantially that improvement of the emulsion properties is required including good wet tack development, narrow and controlled particle size distribution, low viscosity, etc. In this study the effects of such polymerization conditions as the type and amount of emulsifier, internal or external plasticizing, and emulsification methods on the viscosity and particle size of polyvinyl acetate emulsions were examined. Results showed that polyvinyl alcohol with a high degree of hydrolysis and low molecular weight and nonionic surfactants are superior to anionic surfactant in improving adhesion and emulsion stability. They also tend to produce emulsions with smaller particle size. External plasticization with dipropylene glycol dibenzoate was more effective in improving flexibility than internal plasticization with butyl acrylate. Monomer emulsification under high shear was more effective in decreasing the particle size.

• 펄프종이기술
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• 제38권2호
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• pp.22-34
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• 2006

To improve the mechanical properties of Hanji, starches such as maize, konyaku, and wheat powders were added at various concentrations in the manufacturing processes of Hanji. The effect of starches on the physical properties of Hanji was as follows. Filling rates of surface of hanji were increased with the increase of the concentration of starch. Hanji surface were completely filled at the 3.0% konyaku treatment. Konyaku powder showed higher filling rates than maize and wheat powder. The breaking length was increased with the increase of filling rates. Konyaku powder showed the highest breaking length: Tear index of hanji treated with maize and wheat powder were a little improved but that of hanji treated with konyaku powder were a little decreased compared to non-treated hanji. In conclusion, starch treatment showed the increase of the breaking length, but no effect on tear index.

• 펄프종이기술
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• 제38권4호
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• pp.1-9
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• 2006

Increasing the filler content of sheet provides an opportunity for saving production cost through fiber replacement with relatively low-priced filler. But increasing the filler content tends to decrease the strength of paper and filler retention. To overcome these problems, preflocculation technology of fillers has been suggested. To evaluate the effect cationic polymers on the size and size distribution of preflocculated GCC and their shear stability, cationic PAM and cationic starch were used. Results showed that cationic PAM formed large prefloc at low dosage. It was required to add 15 times as high as cationic starch to cationic PAM to obtain the same size prefloc. But preflocs formed with cationic starch was superior in shear stability to those formed with cationic PAM. With the increase of shear rate the size of preflocs decreased. Greater amount of small preflocs or un-flocculated fillers was observed when the dosage of polymers was low and this ended up low ash retention in handsheets.

• 펄프종이기술
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• 제30권1호
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• pp.29-43
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• 1998

This study was to investigate the effect of .compressive load and cyclic humidity(2$0^{\circ}C$, 65% and 90% RH) on the physical and mechanical properties of corrugated board. Corrugated boards in the study were under compressive load and under cyclic humidity, and their properties were compared to those without load. Results were summarized as follows ; 1 Statistically significant correlation was shown between the ring crush of the boards and the compressive strength of cylinder specimen made from the boards. So we could study the compressive behavior of board with cylinder specimen. 2. The boards under the compressive load increased their moisture content and thickness much more than those without load both in constant and in cyclic RH. 3. The compressive and tensile strength of board samples were inversely and closely proportional to the sheet moisture content regardless of their load and humidity history. 4. The moisture content did not show any significant proportionality to the change of burst strength of boards within this experiment. 5. Board reconditioning in standard condition led to the recovery of the strength loss that had occurred under various load and humidity condition. 6. The handsheets prepared from the boards that had experienced compressive load and cyclic humidity, and those with no-load and 65% RH did not show any significant difference in strength properties. No physical damage or load-carrying properties of the wood fiber were observed by the compressive load and cyclic humidity history.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2011년도 춘계학술발표회 논문집
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• pp.271-277
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• 2011

Hanji(Korean traditional paper) is made from bark of paper mulberry(Broussonetia kazinoki). For a long time, Hanji has been used in various fields, such as paintings, printing paper, as specialty paper. The utilization of Hanji will become more and more diverse. One of the characteristic properties of Hanji is a long life time comparing to western paper. The mucilage which must be used in Hanji manufacturing should effect the conservation properties of Hanji. The effectiveness of the mucilage in aging of Hanji was evaluated in this paper. Strength properties of thermal aged Hanji made with synthetic mucilage decreased more slowly than those of Hanji made with natural mucilage. As prolonged aging time, all Hanji made mucilage increased oxidation index. But, Hanji made with PAM was most stable in oxidation of cellulose.

• 펄프종이기술
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• 제42권2호
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• pp.95-101
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• 2010

For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

• 펄프종이기술
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• 제31권2호
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• pp.15-24
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• 1999

A new technique for recycling of white water was developed in order to reduce the calcium hardness in a closed OCC recycling system. Calcium ions present in the white water were precipitated as calcium carbonate by reacting with sodium carbonate, and the precipitated $CaCO_3$ was removed from the system using a flotation fractionation method, which has been commonly used in deinking process. In the flotation stage, a mixed gas of $CO_2$-air was purged into the flotation cell because the pH of $Na_2CO_3$-treated white water was reduced to neutral by $CO_2$ gas. Since $CaCO_3$ precipitate tends to stick onto fine fiber surface and then selectively removed from the white water, a proper amount of suspended solid in white water acts as an important factor for deciding the removal efficiency. By the application of $Na_2CO_3$ addition-$CO_2$ flotation to the short circulated white water, the calcium hardness was significantly reduced by 87% and more. Removal of calcium ions with fine fibers led to a drainage improvement, reduction of fresh water consumption, and enhanced efficiency of wet-end chemicals.

• 펄프종이기술
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• 제39권5호
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• pp.52-57
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• 2007

Corrugated fiberboard is a representative packaging material because of high compressive strength and stiffness in spite of light weight. The flutes of corrugated fiberboard are various depending on the height and the number per unit length of flute. The corrugated fiberboard with microflute like E, F or G with low height less than 1.5 mm has developed. Because it has some advantages including higher stiffness and lower requirement of fiber than carton board, it has a possibility to replace folding box board. Its consumption has been increased with the various applications like graphic packaging. As microflute has the different geometry from other conventional flutes, it can show the different behavior in testing and it may require a new testing method. In this study, we evaluated the edgewise compressive strength of the corrugated fiberboard with microflute according to ISO and other standard test methods. And the effect of specimen shape and platen compression rate was examined. From this study, we found that ISO methods was suitable and reasonable methods for corrugated fiberboard with microflute.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 1999년도 Proceedings of Pre-symposium of the 10th ISWPC
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• pp.50-55
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• 1999

Sizing development of AKD-sized paper by beta-ketoester formation has been debated until recent years because of absence of its obvious and direct spectroscopic evidence. In this study, reaction between AKD and cellulose was investigated to disclose the possibility of beta-ketoester formation between two components under no catalyzed neutral condition. In absence of water, AKD reacted with cellulose to form beta-ketoester linkage under no catalyzed neutral condition, while, in presence of water, most of AKD was hydrolyzed to a dialkyl ketone or beta-ketoacid. Therefore, the main mechanism of AKD sizing would not be the formation of beta-ketoester between AKD and cellulose in the papermaking process. It could be suggested that the sizing development of AKD-sized paper is obtained by next two mechanisms: 1) formation of a thin-layer of AKD on the fiber surface through melting and spreading of AKD emulsion particles by heat, and 2) the formation of ketone by the hydrolysis of AKD during drying and storage of AKD-sized papers.

• 펄프종이기술
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• 제47권2호
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• pp.34-41
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• 2015

Recovered paper has been widely used as a main raw material of papermaking in Korea. Recycling of recovered paper helps to reduce production cost and preserve an environment. To recycle recovered paper efficiently, de-inking is a key process in recycling mills. De-inking process would be affected by various influencing factors such as the type of de-inking agent, mixed ratio of recovered paper, season, and process conditions. In this study, fatty acid and nonionic surfactant were used as the de-inking agent in froth-flotation process of mixed recovered paper. De-inking properties of mixed recovered paper were investigated according to the addition level of each chemical. Nonionic surfactant had a small effect on de-inking efficiency of mixed recovered paper due to decreased reject. As the additional level of fatty acid increases, fragmented ink particles increased and then optical properties of recycled paper decreased because fragmented ink particles adsorbed onto the fiber surface.