• 예술인문사회 융합 멀티미디어 논문지
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• 제8권4호
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• pp.151-160
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• 2018

디지털 기술과 인터넷의 발전은 콘텐츠 산업에 큰 변화를 가져왔다. 이러한 변화에 발맞추기 위하여 저작권법 또한 여러 개정 작업을 거쳤고, 2006년 개정에서 "디지털음성송신" 개념이 도입되었다. 그러나 현행법상 디지털음성송신의 개념은 방송 및 전송과의 구분 기준이 추상적이고 명확하지 못한 문제점이 있다. 이러한 모호성으로 인해 새롭게 등장한 "프리리슨"과 같은 음악 웹캐스팅 서비스들의 법적 지위에 대해 판단하기 어려운 상황이다. 이들 서비스는 디지털음성송신을 표방하고 있으나, 그 편의성과 효용에 있어 전송과의 유사성으로 인해 "유사전송"이라는 새로운 개념을 탄생시켰다. 이러한 문제는 기술의 발전과 법체계의 불균형에서 비롯된 것으로 해결을 위해 규율 체계의 변화가 불가피 하다. 따라서 본 연구에서는 관련 사례와 미국의 저작권법 규정을 검토하여 유사전송 문제에 대한 해결방안을 논의한다. 유사전송 문제를 어떠한 법적 기준으로 판단할 것인지와 음반시장에 가져올 수 있는 실질적인 피해를 줄일 수 있는 입법 방안을 제시한다.

• 대한전자공학회논문지SP
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• 제47권4호
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• pp.20-27
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• 2010

본 논문에서는 웨이블릿 패킷 변환(WPT) 기반의 컬러화 알고리즘에서 슈도랜덤코드(pseudo-random code) 정보의 삽입을 통해 복원된 컬러 영상에서 채도를 보상하는 방법을 제안한다. 우선 컬러 영상을 흑백 영상으로 변환하는 과정(컬러-그레이변환)에서 RGB 영상을 YCbCr 영상으로 변환한 후, Y 영상에 2레벨 웨이블릿 패킷 변환을 적용하여 정보량이 최소인 부영역(수평의 수직, 수직의 수평 부영역)에 CbCr 영상을 삽입한다. 이때 프린팅 및 스캐닝 과정에서 발생하는 채도 열화를 보상하기 위해 원본 영상 CbCr의 최대값 및 최소값을 슈도랜덤코드 형태로 변환하여 대각의 대각 부영역에 역시 삽입한다. 슈도랜덤코드는 CbCr의 최대값 및 최소값을 흰색 점의 개수로 표현한 영상으로, 컬러 복원 과정(그레이-컬러변환)에서 이를 추출하여 원본의 CbCr 최대값 및 최소값과 복원 영상의 CbCr 최대값 및 최소값과의 비를 가중치로 이용함으로써 채도 보상 알고리즘을 수행한다. 실험을 통해 제안된 방법이 복원된 컬러 영상에서 채도를 향상시킴을 색차와 PSNR 수치로 확인할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제34권9호
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• pp.2753-2759
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• 2013

The aim of the present study is to explore the possibility of utilizing fly ash and loess, as alternative to activated carbon, for the adsorption of diazinon in water. Batch adsorption experiment was performed to evaluate the influences of various factors like initial concentration, contact time and temperature on the adsorption of diazinon. The adsorption data shows that fly ash is not effective for the adsorption of diazinon. The equilibrium data for both activated carbon and loess were fitted well to the Freundlich isotherm model. The pseudo-second-order kinetic model appeared to be the better-fitting model because it has higher $R^2$ compared to the pseudo-first-order kinetic model. The thermodynamic parameters such as free energy (${\Delta}G$), the enthalpy (${\Delta}H$) and the entropy (${\Delta}S$) were calculated. Contrary to loess, the ${\Delta}G$ values of activated carbon were negative at the studied temperatures. It indicates that the adsorption of diazinon by activated carbon is a favorable and spontaneous process. The positive ${\Delta}H$ values of activated carbon and loess suggest that the diazinon adsorption process is endothermic in nature. In addition, the positive ${\Delta}S$ values show that increased randomness occurs at the solid/solution surface during the adsorption of diazinon.

• 한국환경과학회지
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• 제24권1호
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• pp.47-53
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• 2015

Removal characteristics of Cu(II) ions by solid-phase extractant immobilized D2EHPA and TBP in PVC were investigated. Cu(II) ion concentrations in the solution and removal capacity of Cu(II) ion according to operation time were compared. The lower the initial concentration of Cu(II) ion in aqueous solution was, the removal capacity of Cu(II) ion by solid-phase extractant was increased relatively. The bigger the initial concentration of Cu(II) ion was, the removal capacity of Cu(II) ion was increased relatively. The pseudo-second-order kinetics according to operation time was showed more satisfying results than the pseudo-first-order kinetics for the removal velocity of Cu(II) ion. The removal capacity of Cu(II) ion was 0.025 mg/g in aqueous solution of pH 2, but the removal capacity of Cu(II) ion was increased to 0.33 mg/g mg/g in aqueous solution of pH 4 according to increasing pH.

• Membrane and Water Treatment
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• 제7권5호
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• pp.403-416
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• 2016

The possibility of using carica papaya leaf powder for removal of copper from wastewater as a low cost adsorbent was explored. Different parameters that affect the adsorption process like initial concentration of metal ion, time of contact, adsorbent quantity and pH were evaluated and the outcome of the study was tested using adsorption isotherm models. A maximum of 90%-94.1% copper removal was possible from wastewater having low concentration of the metal using papaya leaf powder under optimum conditions by conducting experimental studies. The biosorption of copper ion was influenced by pH and outcome of experimental results indicate the optimum pH as 7.0 for maximum copper removal. Copper distribution between the solid and liquid phases in batch studies was described by isotherms like Langmuir adsorption and Freundlich models. The adsorption process was better represented by the Freundlich isotherm model. The maximum adsorption capacity of copper was measured to be 24.51 mg/g through the Langmuir model. Pseudo-second order rate equation was better suited for the adsorption process. A dynamic mode study was also conducted to analyse the ability of papaya leaf powder to remove copper (II) ions from aqueous solution and the breakthrough curve was described by an S profile. Present study revealed that papaya leaf powder can be used for the removal of copper from the wastewater and low cost water treatment techniques can be developed using this adsorbent.

• 한국콘텐츠학회논문지
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• 제9권10호
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• pp.444-450
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• 2009

본 연구는 폐 활성슬러지를 이용하여 $Pb^2+$와 $Cr^2+$의 생체흡착속도 및 평형을 도출하였으며, 가압부상법이 이용하여 A/S 비에 따른 폐슬러지의 분리효율을 비교하였다. 흡착량 및 접촉시간은 흡착평형과 동역학 모델식을 이용하여 모사하였다. 폐 활성슬러지상에서 $Pb^2+$와 $Cr^2+$의 흡착평형은 Langmuir와 Redlich-Peterson식에 의해 잘 예측될 수 있었다. 흡착속도는 유사 1차 반응식보다는 유사 2차 반응식에 의해 더 잘 예측되었다. 가압부상법을 이용한 폐 활성슬러지의 분리효율은 90%이상 유지하는 것이 가능하였다.

• 산업기술연구
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• 제31권B호
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• pp.119-125
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• 2011

N-doped Titanium oxides were prepared by using urea as a source of nitrogen. The photoactivities of the doped $TiO_2$ were evaluated on the basis of degradation of humic acid in aqueous solutions with different light sources, ultraviolet lamp, fluorescent lamp and solar light. XRD analysis was conducted to identify the crystal structure of the synthesized photocatalysts. N-doped $TiO_2$ and $pure-TiO_2$ was anatase type. SEM results showed that spherical particles were formed, which are the characteristics of the anatase form. N doped $TiO_2$ showed higher $UV_{254}$ decrease ratio and DOC removal ratio compared to $pure-TiO_2$. The humic acid degradation reaction using the UV-A lamp and UV-C lamp was assigned to pseudo-first order reaction. For solar light, only $pure-TiO_2$ and $N-TiO_2$ exhibited the pseudo-first order reaction.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2010년도 춘계 학술발표회
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• pp.1006-1011
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• 2010

This study was focused on the reactivity of furnace slag against cadmium to design the vertical drain method with reactive column for improving contaminated sea shore sediment. The removal capacity of furnace slag was analyzed using pseudo-second-order model. And the effective parameters of removal test were initial concentration and initial pH. According to equilibrium removal amount and reactive constant calculated by pseudo-second-order model, the removal capacity was analyzed. Equilibrium removal amount of furnace slag was linearly increased as increasing intial cadmium concentration. Because the pH was around 11, the removal mechanism of furnace slag could be both sorption and precipitation. Therefore the removal amount was increased due to initial concentration. pH was increased to around 11 in the case of "No treat", but the pH were 3.8 in the case of "HAc added" and 0.7 in the case of "HCl added". The removal amount was different 4.8, 1.19 and 0.27 mg/g. This results show the pH was major factor to remove cadmium using furnace slag.

• 한국환경과학회지
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• 제24권9호
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• pp.1145-1153
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• 2015

PVC-Zeolite composite was prepared by immobilizing zeolite with polyvinyl chloride (PVC). The prepared PVC-Zeolite beads were characterized by using X-ray diffractometer (XRD), fourier transform infrared spectrometer (FTIR), thermo gravimetric analyzer (TGA), and scanning electron microscopy (SEM). The removal properties of Sr and Cs ions from aqueous solution were investigated in batch experiment. The removal efficiencies of Sr and Cs ions by the PVC-Zeolite beads were dependent on the initial pH of solution. The removal efficiencies sharply increased at below pH 4 and was kept constant at pH 4 or more. The adsorption kinetics of Sr and Cs ions by the PVC-Zeolite beads were fitted well by the pseudo-second-order model ($r^2$>0.99) more than pseudo-first-order model. The maximum adsorption capacities of Sr and Cs ions calculated from Langmuir isotherm model were 39.37 mg/g and 55.87 mg/g, respectively.

• 한국환경과학회지
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• 제20권12호
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• pp.1607-1615
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• 2011

The adsorption performance of cupper and zinc ions($Cu^{2+}$ and $Zn^{2+}$) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of $Cu^{2+}$ and $Zn^{2+}$ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed $Cu^{2+}$ and $Zn^{2+}$ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity($q_{max}$) by the Langmuir model was determined as $Cu^{2+}$ 99.8 mg/g and $Zn^{2+}$ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.