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Recent Insights from the International Common-Cause Failure Data Exchange Project

  • Kreuser, Albert;Johanson, Gunnar
    • Nuclear Engineering and Technology
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    • v.49 no.2
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    • pp.327-334
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    • 2017
  • Common-cause failure (CCF) events can significantly impact the availability of safety systems of nuclear power plants. For this reason, the International Common Cause Data Exchange (ICDE) project was initiated by several countries in 1994. Since 1997 it has been operated within the Organisation for Economic Co-operation and Development (OECD)/Nuclear Energy Agency (NEA) framework and has successfully been operated over six consecutive terms (the current term being 2015-2017). The ICDE project allows multiple countries to collaborate and exchange CCF data to enhance the quality of risk analyses, which include CCF modeling. As CCF events are typically rare, most countries do not experience enough CCF events to perform meaningful analyses. Data combined from several countries, however, have yielded sufficient data for more rigorous analyses. The ICDE project has meanwhile published 11 reports on the collection and analysis of CCF events of specific component types (centrifugal pumps, emergency diesel generators, motor operated valves, safety and relief valves, check valves, circuit breakers, level measurement, control rod drive assemblies, and heat exchangers) and two topical reports. This paper presents recent activities and lessons learnt from the data collection and the results of topical analysis on emergency diesel generator CCF impacting entire exposed population.

Preparation of particle-size-controlled SiC powder for single-crystal growth

  • Jung, Eunjin;Lee, Myung Hyun;Kwon, Yong Jin;Choi, Doo Jin;Kang, Seung Min;Kim, Younghee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.57-63
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    • 2017
  • High-purity ${\beta}-SiC$ powders for SiC single-crystal growth were synthesized by direct carbonization. The use of high-purity raw materials to improve the quality of a SiC single crystal is important. To grow SiC single crystals by the PVT method, both the particle size and the packing density of the SiC powder are crucial factors that determine the sublimation rate. In this study, we tried to produce high-purity ${\beta}-SiC$ powder with large particle sizes and containing low silicon by introducing a milling step during the direct carbonization process. Controlled heating improved the purity of the ${\beta}-SiC$ powders to more than 99 % and increased the particle size to as much as ${\sim}100{\mu}m$. The ${\beta}-SiC$ powders were characterized by SEM, XRD, PSA, and chemical analysis to assess their purity. Then, we conducted single-crystal growth experiments, and the grown 4H-SiC crystals showed high structural perfection with a FWHM of about 25-48 arcsec.

Characteristics of Ni/YSZ Cermet Prepared by Mechanical Alloying Method for the High Temperature Electrolysis of Steam

  • Choo, Soo-Tae;Kang, Kyoung-Hoon;Chae, Ui-Seok;Hong, Hyun-Seon;Hwang, Kab-Jin;Bae, Ki-Kwang;Shin, Seock-Jae
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.764-767
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    • 2006
  • Ni/YSZ $(Y_2O_3-stabilized\;ZrO_2)$ composite as an electrode component for High Temperature Electrolysis (HTE) was fabricated by mechanical alloying method using Ni and YSZ powders. Characterization of the synthesized composite was investigated with various analysis tools, including XRD, SEM and PSA, and a self-supporting planar unit cell prepared with the Ni/YSZ composite was prepared to study the electrochemical reactions for the production of hydrogen. The Ni/YSZ cermet is composed of crystalline Ni and YSZ, in a sub-micro scale, and has an even distribution without aggregated particles. In addition, under an electrochemical reaction, the unit cell showed an $H_2$ evolution rate from steam of 14 Nml/min and $600mA/cm^2$ of current density at the electrode.

Characterization of Microcapsules for Self-Healing in Polymeric Composites

  • Lee Jong Keun;Hong Soon Ji;Liu Xing;Park Hee Won;Yoon Sung Ho
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.190-193
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    • 2004
  • Two different diene monomers [dicyclopentadiene (DCPD) and 5-ethylidene-2-norbomene (ENB)] as self­healing agent for polymeric composites were microencapsuled by in-situ polymerization of urea and formaldehyde. The healing agents were investigated by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). Exothermic reaction and glass transition temperature from DSC and storage modulus (G') and tan $\delta$ from DMA curves were analyzed for the samples cured for 5 min and 24 h in the presence of different amounts of catalyst. Micorcapsules were successfully formed for both diene monomers. Microcapsules containing the healing agent were manufactured and its thermal properties were characterized by thermo gravimetric analysis (TGA). Optical microscope (OM) and particle size analyzer (PSA) were employed to observe morphology and size distribution of microcapsules, respectively. Comparison of the two self-healing agents and their microcapsules with the two was made in this study.

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Expression Analysis of ESTs Derived from the Leaf of Chunpoong (Panax ginseng C,A. Meyer)

  • In, Jun-Gyo;Lee, Bum-Soo;Yang, Deok-Chun
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2003.04a
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    • pp.122-122
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    • 2003
  • Expressed sequence tags (EST) are help to quickly identify functions of expressed genes and to understand the complexity of gene expression. In order to analyze gene expression of the leaf development in Panax ginseng, which is one of the most important medicinal plant, expressed sequence tags (EST) analysis was carried out. We constructed a cDNA library using the immature leaf of Chunpoong. Partial sequences were obtained from 3,170 clones. The ESTs could be clustered into 1,624 (56.1%) non-redundant groups. Similarity search of the non-redundant ESTs against public non-redundant databases of both protein and DNA indicated that 1,137 groups show similarity to genes of known function. These ESTs clones were divided into sixteen categories depending upon gene function. Most abundant transcripts in immature ginseng leaf were photosynthesis related protein, such as chlorophyll a/b binding protein LHCII type I (128), chlorophyll a/b binding protein (53), ribulose-1,5-bisphosphate carboxylase (41), and photosystem I psaH (26). The EST data from immature leaf generated in this study is useful in dissecting gene expression in leaf organ of ginseng.

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Pressure Swing Adsorption Based Hydrogen Purification Vessel 3D Modeling and Feasibility Study (Pressure Swing Adsorption 기반 수소정제용기 3차원 모델링 및 타당성 검증 연구)

  • CHA, YOHAN;CHOI, JAEYOO;JU, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.4
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    • pp.197-204
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    • 2021
  • Pressure swing adsorption is a purification process which can get pure hydrogen. The purification process is composed of four process: compression, adsorption, desorption and discharge. In this study the adsorption process was simulated by using the Fluent and validated with experimental results. A gas used in experiment is composed of H2, CO2, CH4, and CO. Adsorption process conducted under 313 kelvin and 3 bar and bituminous-coal-based (BPL) activated carbon was used as the adsorbent. Langmuir model was applied to explain the gas adsorption. And diffusion of all the gases was controlled by micro-pore resistances. The result shows that, the most adsorbed gas was carbon dioxide, followed by methane and carbon monoxide. And carbon monoxide took the least amount of time to reach the maximum adsorption amount. The molar fraction of the off-gas became the same as the molar fraction of the gas supplied from the inlet after adsorption reached the equilibrium.

A study of activity ratios of uranium isotope in the groundwater using liquid scintillation counter (액체섬광계수기를 이용한 지하수 내 우라늄 동위원소 측정법에 관한 연구)

  • Cho, Soo-Young;Song, Kyung-Sun;Lee, Kil-Yong;Yoon, Yoon-Yeol;Kim, Won-Baek;Ko, Kyung-Sok
    • Analytical Science and Technology
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    • v.25 no.2
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    • pp.146-151
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    • 2012
  • An analytical method was developed for the measurement of uranium isotope in ground water using the liquid scintillation counting technique. A LKB Wallac Quantulus 1220 liquid scintillation counter (LSC) equipped with pulse shape analyzer (PSA) and a solvent extraction method were used for the measurement of uranium isotope in ground water samples. The effect of solution volume on the extraction efficiency was evaluated for 100 to 1000 mL solutions using a NIST standard reference material (NIST SRM 4321C). The effect of groundwater pH on the extraction efficiency was also investigated for pH ranging from 0.5 to 10. It was found that the extraction efficiency had a strong dependence on pH showing a maximum at pH 2. In contrast, the effect of groundwater volume on the extraction efficiency was negligible in the range investigated. According to the method, the extraction efficiency of uranium isotopes was near 96% and the lower detection limit for uranium was 0.018 Bq/L with the counting time of 300 min. The result of this study was also verified by the conventional ICP-MS measurement. It is demonstrated that the suggested method is valuable to the determination of the optimum extraction and measurement conditions for uranium in ground water. The method was successfully applied to the ground water at four locations near the Daejeon province. It was found that the uranium content and the isotopic ratio of $^{234}U/^{238}U$ at the locations ranged 0.59~6.69 Bq/L and 0.72~1.40, respectively.

Evaluations of Microstructure and Hydrogenation Properties on $Mg_2NiH_x$ ($Mg_2NiH_x$ 수소저장합금의 미세결정구조 및 수소화 특성평가)

  • Seok, Song;Shin, Kyung;Kweon, Soon-Yong;Ur, Soon-Chul;Lee, Young-Geun;Hong, Tae-Whan
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.3
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    • pp.238-243
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    • 2005
  • Mg and Mg-based alloys are most important hydrogen storage materials. It is a lightweight and low-cost materials with high hydrogen storage capacity. However, the formation of hydride at high temperature, the deterioration effect, the hydriding and dehydriding kinetics are bad factor for application. In this study, Mg and Ni have been produced by hydrogen induced mechanical alloying(HIMA) process. The raw materials, Mg(purity 99.9%) chip and Ni(purity 99.95%) chip was prepared by using a planetary ball mill apparatus(FRITSCH pulverisette 5). The balls to chips mass ratio(BCR) are 30:1. The hydrogen pressure induced 2.0MPa and milling times were 12, 24, 48, 72, 96 hours with a rotating speed of 200rpm. X-ray diffraction(XRD) analysis was made to characterize the crystallite size and misfit strain. The crystallite size measured by laser particle size analysis(PSA). Microstructure changes were investigated by scanning electron microscopy(SEM) and the transmission electron microscopy(TEM). The hydrogen storage properties were evaluated by using an Sivert's type automatic pressure-composition-therm(PCT) apparatus.

Effect of Carbon dioxide in Fuel on the Performance of PEM Fuel Cell (연료중의 이산화탄소 불순물에 의한 연료전지 성능변화 연구)

  • Seo, Jung-Geun;Kwon, Jung-Taek;Kim, Jun-Bom
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.184-187
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    • 2007
  • Hydrogen could be produced from any substance containing hydrogen atoms, such as water, hydrocarbon (HC) fuels, acids or bases. Hydrocarbon fuels couold be converted to hydrogen-rich gas through reforming process for hydrogen production. Even though fuel cell have high efficiency with pure hydrogen from gas tank, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. Most impurities are removed using pressure swing adsorption (PSA) process to get high purity hydrogen. However, high purity hydrogen production requires high operation cost of reforming process. The effect of carbon dioxide on fuel cell performance was investigated in this experiment. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run (10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography (GC).

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Enhanced Production of Human Serum Albumin by Fed-Batch Culture of Hansenula polymorpha with High-Purity Oxygen

  • Youn, Jong-Kyu;Shang, Longan;Kim, Moon-Il;Jeong, Chang-Moon;Chang, Ho-Nam;Hahm, Moon-Sun;Rhee, Sang-Ki;Kang, Hyun-Ah
    • Journal of Microbiology and Biotechnology
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    • v.20 no.11
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    • pp.1534-1538
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    • 2010
  • Fed-batch cultures of Hansenula polymorpha were studied to develop an efficient biosystem to produce recombinant human serum albumin (HSA). To comply with this purpose, we used a high-purity oxygen-supplying strategy to increase the viable cell density in a bioreactor and enhance the production of target protein. A mutant strain, H. polymorpha GOT7, was utilized in this study as a host strain in both 5-l and 30-l scale fermentors. To supply high-purity oxygen into a bioreactor, nearly 100% high-purity oxygen from a commercial bomb or higher than 93% oxygen available in situ from a pressure swing adsorption (PSA) oxygen generator was employed. Under the optimal fermentation of H. polymorpha with highpurity oxygen, the final cell densities and produced HSA concentrations were 24.6 g/l and 5.1 g/l in the 5-l fermentor, and 24.8 g/l and 4.5 g/l in the 30-l fermentor, respectively. These were about 2-10 times higher than those obtained in air-based fed-batch fermentations. The discrepancies between the 5-l and 30-l fermentors with air supply were presumably due to the higher contribution of surface aeration over submerged aeration in the 5-l fermentor. This study, therefore, proved the positive effect of high-purity oxygen in enhancing viable cell density as well as target recombinant protein production in microbial fermentations.