• Bulletin of the Korean Chemical Society
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• v.31 no.1
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• pp.220-223
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• 2010

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.81-85
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• 2007

A fluidized bed reactor is made with quartz. The size of FBR is 0.055 m I.D. and 1.0 m in height. The FBR was employed for the thermocatalytic decomposition of propane to produce hydrogen without $CO_{2}$. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. Carbon black DCC-N330 is used to decompose the propane gas. The propane decomposition reaction over carbon black catalyst in a fluidized bed reactor was carried out the temperature range of 600 ${\sim}$ 800 $^{\circ}C$, propane gas velocity of 1.0 ${\sim}$ 4.0$U_{mf}$($1U_{mf}$ = 0.61cm/s) and the catalyst loading of 100 ${\sim}$ 200g. Production of $H_{2}$ such as other reaction temperature, gas velocity, catalytic loading on the reaction rates was investigated. The carbon depositied on the catalyst surface was observed by FE-SEM. The particle size of the carbon black was observed by Particle size analyzer. Resulting production in the experiment was not only hydrogen but also several by-products such as methane, ethylene, ethane, and propylene.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.388-391
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• 2006

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

• Journal of the Korean Institute of Gas
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• v.9 no.4 s.29
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• pp.50-56
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• 2005

Liquefied Petroleum 6aso-PG) is combustible gas which used for fuel for domestic and automobiles. A research for adjust a component of LPG to improve the fuel characteristics and control the manufacturing process of that is carrying in petrochemical industry. Some kinds of LPG blending is considered as a adjusting method to control component of LPG. LPG is mainly propane for domestic use and butane for automobile use but propylene and butylene also a kind of LPG Change of explosion characteristic and combustion gas component by mixing of propylene in propane and butane was measured and analysed in this research. Based on the result of experiment, it was found that explosion pressure and pressure rise rate was slightly increased with mixing rate of propylene and it was considered the possibility of increasing the CO concentration in combustion gas with increase the mixing rate of propylene.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.85-88
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• 2006

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

• Bulletin of the Korean Chemical Society
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• v.23 no.5
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• pp.674-678
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• 2002

The dehydrogenation of propane to propylene has been studied in an isothermal high-temperature shell-and-tube membrane reactor containing a Pd-coated ${\psi}$-Al2O3 membrane and a Pt/K/Sn/Al2O3 packed catalyst . A tubular Pd-coated ${\psi}$-Al2O3 membrane was prepared by an electroless plating method. This membrane showed high hydrogen to nitrogen permselectivities (PH2N2 = 10-50) at 400 $^{\circ}C$ and 500 $^{\circ}C$ with various transmembrane pressure drops. The employment of a membrane reactor in the dehydrogenation reaction, which selectively separates hydrogen from the reaction mixture along the reaction path, can greatly increase the conversion and enable operation of the reactor at lower temperatures. High hydrogen permselectivity has been confirmed as a key factor in determining the reactor performance of conversion enhancement.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.12
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• pp.1656-1667
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• 1997

Condensing heat transfer characteristics of hydrocarbon refrigerants are experimentally investigated. Single component hydrocarbon refrigerants (propane, isobutane, butane and propylene) and binary mixtures of propane/isobutane and propane/butane are considered as test fluids. Local condensing heat transfer coefficients of selected refrigerants are obtained from overall conductance measurement. Average heat transfer coefficients at different mass fluxes and heat transfer rates are shown and compared with those of R22. Pure hydrocarbon refrigerants have higher values of heat transfer coefficient than R22. It is also found that there is a heat transfer degradation for hydrocarbon mixtures due to composition variation during condensation. Measured condensing heat transfer coefficients are compared with predicted values by available correlations. An empirical correlation for pure and mixed hydrocarbon is developed, and it shows good agreement with experimental data.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.7
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• pp.639-644
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• 2004

This paper deals with the heat transfer characteristics of R-1270 (Propylene), R-600a (Iso-butane) and R-290 (Propane) as an environment friendly refrigerant and R-22 for condensing. The experimental apparatus has been set-up as a conventional vapor compression type heat pump system. The test section is a horizontal double pipe heat exchanger. A tube diameter of 12.70 mm with 1.32 mm wall thickness is used for this investigation. The test results showed that the local condensing heat transfer coefficients of hydrocarbon refrigerants were higher than that of R-22. The average condensing heat transfer coefficient was obtained with the maximum value in R-1270 and the minimum one in R-22. Comparing the heat transfer coefficient of experimental results with that of other correlations, the presented results had a good agreement with the Cavallini-Zecchin's correlation. It reveals that the natural refrigerants can be used as substitute for R-22.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.6
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• pp.522-529
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• 2004

In this study, external condensation heat transfer coefficients (HTCs) of flammable refrigerants of propylene, propane, isobutane, butane, DME, and HFC32 were measured on a horizontal plain tube, 26 fpi low fin tube, and Turbo-C tube. All data were taken at the temperature of 39$^{\circ}C$ with a wall subcooling of 3∼8$^{\circ}C$. Test results showed a typical trend that condensation HTCs of flammable refrigerants decrease with increasing wall subcooling. HFC32 had the highest HTCs among the tested refrigerants showing 44% higher HTCs than those of HCFC22 while DME showed 28% higher HTCs than those of HCFC22. HTCs of propylene and butane were similar to those of HCFC22 while those of propane and isobutane were similar to those of HFC134a. Based upon the tested data, Nusselt's equation is modified to predict the plain tube data within a deviation of 3%. For 26 fpi low fin tube, Beatty and Katz equation predicted the data within a deviation of 7.3% for all flammable refrigerants tested. The heat transfer enhancement factors for the 26 fpi low fin and Turbo-C tubes were 4.6∼5.7 and 4.7∼6.9 respectively for the refrigerants tested indicating that the performance of Turbo-C tube is the best among the tubes tested.

• Membrane Journal
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• v.26 no.1
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• pp.38-42
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• 2016

Polyvinylpyrrolidone (PVP), which is glassy polymer to have amide functional group, was induced to fabricate the facilitated olefin transport membranes for olefin/paraffin separation. Separation performance for the mixed gas consisting of propylene and propane (50 : 50 vol%) was measured by gas chromatography and bubble flow meter. The properties of membranes were confirmed by scanning electron microscope and FT-IR. The results of long-term separation tests showed the selectivity of 15 and permeance of 1.3 GPU. The membranes was compared with poly(2-ethyl-2-oxazoline) $(POZ)/AgBF_4/Al(NO_3)_3$ membranes and the characteristics were confirmed as polymer matrix for facilitated transport membranes.