• Title/Summary/Keyword: property change

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Redox Property of Vanadium Oxide and Its Behavior in Cataltic Oxidation

  • 김영호;이호인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1457-1463
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    • 1999
  • Structure and their redox property of the vanadium oxides prepared by decomposing NH₄VO₃ at various temperatures were studied by XRD, SEM, XPS, and temperature programmed reduction/temperature programmed oxidation (TPR/TPO) experiment. All TPR profiles have two sharp peaks in the temperature range 650-750℃, and the area ratio of the two sharp peaks changed from sample to sample. There were three redox steps in TPR/TPO profiles. The oxidation proceeded in the reverse order of the reduction process, and both the reactions proceeded via quite a stable intermediates. The changes of the morphological factor $(I_{(101)}/I_{(010)})$, the ratio of $O_{1S}$ peak area (O$_{1S}$( α)/O$_{1S}$( β)) in the XPS results, and the ratio of hydrogen consumption in TPR profiles with various vanadium oxides showed the distinct relationship between the structural property and their redox property of vanadium oxides. The change of the specific yield of phthalic anhydride with various vanadium oxides showed a very similar trend to those of the peak area ratio in TPR profiles, which meant that the first reduction step related to the partial oxidation of o-xylene on the vanadium oxide catalyst.

Socio-cultural Interpretation of Fast Fashion Phenomenon (패스트패션(Fast Fashion) 현상에 대한 사회문화적 해석)

  • Ro, Ju-Hyun;Kim, Min-Ja
    • Journal of the Korean Society of Costume
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    • v.59 no.3
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    • pp.27-41
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    • 2009
  • Interpreting the phenomenon of Fast fashion that is prevalent these days, this research is meaningful in that it prepares the frame which suggests the vision to read the trend of 2000s and analyzes the property of phenomenon of Fast Fashion in the connection with society and culture. The so[io-cultural property can be largely characterized by consumption orientation, change orientation, efficiency, moment and multiculturism. Analyzing the phenomenon of fast fashion that emerged after 2000 on the basis of such sociocultural background, it is largely classified into imitation, fashionability, disposability, portability, transformation and convergence. Due to the hi-polarization of consumption, people tend to select imitated goods, and people accustomed to speed get interested in the fashionability of all Phenomena. Further, society that is transient and changing rapidly makes the habit of purchasing in disposability. The property of nomad society encourages to keep the habit of portability. Such change-oriented society and rapidly changing life pattern make them adapt in diverse transformation modes of Fast Fashion. Further, multi-cultural world integrates enterprises through combination of all cultures and the convergence of all factors.

A Study on the Change of Properties of Al-bronze Due to Alloy Elements and Cooling Rate. (알루미늄청동의 합금성분 및 냉각속도에 따른 특성변화에 관한 연구)

  • Jung, Woon-Jae;Kim, Heon-Joo;Kim, Dong-Ok;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.8 no.3
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    • pp.271-281
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    • 1988
  • Al-bronze has a good mechanical property, corrosion resistance and castability, so being highlighted for the new copper alloy. So, effects of alloy composition and cooling rate in the mechaincal properties and solidification behavior have been investigated. The results obtained are as follows; 1) Change in volume on solidification is larger in metal mold casting than in sand mold casting. And it decreases by the addition of Al. 2) The mechanical property in metal mold casting is superior to the one in sand mold casting, and the inclination is obvious up to 9% Al, after heat-treatment ($885^{\circ}C$, $1.5hrs\;{\rightarrow}\;W\;{\cdot}\;Q\;{\rightarrow}\;540^{\circ}C$, 3hrs) 3) By adding Al, the mechanical property is slightly increased up to 9% Al, Above 9% Al, it is increased rapidly, and is accelerated by adding Fe. 4) Cooling rate and hardness, and grain size and cooling rate are related as follows in the range of $1100^{\circ}C$ to $1200^{\circ}C$ pouring temperature. Grain size(${\mu}m$)=$929.6422{\times}cooling\;rate(^{\circ}C\;/\;sec)^{-0.51537}$ Hardness(BHN)=$765.45713{\times}grain\;size({\mu}m)^{-0.31058}$.

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Sketch-based Image Retrieval System using Optimized Specific Region (최적화된 특정 영역을 이용한 스케치 기반 영상 검색 시스템)

  • Ko Kwang-Hoon;Kim Nac-Woo;Kim Tae-Eun;Choi Jong-Soo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.8C
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    • pp.783-792
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    • 2005
  • This paper proposes a feature extraction method for sketch-based image retrieval of animation character. We extract the specific regions using the detection of scene change and correlation points between two frames, and the property of animation production. We detect the area of focused similar colors in extracted specific region. And it is used as feature descriptor for image retrieval that focused color(FC) of regions, size, relation between FCs. Finally, an user can retrieve the similar character using property of animation production and user's sketch as a query Image.

Electrical Conduction Property of the Carbon Black-Filled Polyethylene Matrix Composites Below the Percolation Threshold (문턱스며들기 이하 카본블랙 충진 폴리에칠렌기지 복합재료의 전기전도 특성)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.20 no.5
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    • pp.271-277
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    • 2010
  • In this paper two aspects of the percolation and conductivity of carbon black-filled polyethylene matrix composites will be discussed. Firstly, the percolation behavior, the critical exponent of conductivity of these composites, are discussed based on studying the whole change of resistivity, the relationship between frequency and relative permittivity or ac conductivity. There are two transitions of resistivity for carbon black filling. Below the first transition, resistivity shows an ohmic behavior and its value is almost the same as that of the matrix. Between the first and second transition, the change in resistivity is very sharp, and a non-ohmic electric field dependence of current has been observed. Secondly, the electrical conduction property of the carbon black-filled polyethylene matrix composites below the percolation threshold is discussed with the hopping conduction model. This study investigates the electrical conduction property of the composites below the percolation threshold based on the frequency dependence of conductivity in the range of 20 Hz to 1 MHz. There are two components for the observed ac loss current. One is independent of frequency that becomes prevalent in low frequencies just below the percolation threshold and under a high electrical field. The other is proportional to the frequency of the applied ac voltage in high frequencies and its origin is not clear. These results support the conclusion that the electrical conduction mechanism below the percolation threshold is tunneling.

Effect of Dietary Vitamin A on Plasma Membrane Property and Ultrastructure in Ethanol -administered Rat Liver

  • Yang, Kyung-Mi;Seo, Jung-Sook;Cho, Hyun-Gug
    • Preventive Nutrition and Food Science
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    • v.3 no.1
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    • pp.56-61
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    • 1998
  • This study was conducted to investigate the effect of dietary supplementation of vitamin A on the membrane property and ultrastructure in ethanol-administered rat livers. Male Sprague-Dawley rats weighing of 130 ~150g were fed with experimental diets for 7 weeks. The diets contained different types of vitamin A which were $\beta$-carotene, retinyl acetate and retinoic acid. After feeding theexperimental diets for 7 weeks, a dose of 3.0g ethanol (30%, W/V)/kg B.W was injected to rats intraperitoneally. Control rats received 0.9% saline containing isocaloric sucrose instead of ethanol. Plasma membrane fluidity of liver decreased in rats fed with vitamin a -Deficient diet with ethanol as compared to that of control rats. Fluidity change of liver plasma membrane that ethanol had induced was influenced by dietary supplementation of vitamin A, but not influenced by the type of supplemented vitamin. A . The ultrastructural changed of hepatic mitrochondria were observed in some rats such as vitamin A-deficient rats with ethanol. Inadequate consumptionof vitamin A contributed to ultrastructural changes such as swelled mitochondria occurred by ethanol-induced hepatotoxicity. Although accurate mechanism involved in the plasma membrane-stabilizing effect of vitamin A is still unclear, dietary supplementation of vitamin A such as retinyl acetate is neede to modulate this change. The direct involvement of membrane property on the cell damage caused by ethanol treatment remains to be established.

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Observation of Shear Bonding Strength by Compositional Change and Firing Steps of the Ni-Cr Alloy for Porcelain Fused Metal Crown (금속-도재관용 Ni-Cr합금의 조성변화와 소성단계에 따른 전단결합강도)

  • Cho, Yong-Wan;Hong, Min-Ho;Kim, Won-Young;Choi, Sung-Min;Chung, In-Sung
    • Journal of Technologic Dentistry
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    • v.35 no.4
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    • pp.353-358
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    • 2013
  • Purpose: This study was observation shear bonding strength by compositional change and firing step of a Ni-Cr alloy for porcelain fused metal crown. The aim of study was to suggest the material for firing step of Ni71-Cr14 alloy to development of alloy for porcelain fused to metal crown. Methods: The test was on the two kinds of Ni-Cr alloy specimens. The surfaces of two alloys were analyzed by EDX in order to observe oxide characteristic. And the shear test was performed by MTS. Results: The surface property and oxide characteristic analysis of oxide layer, weight percentage of Element O within $Ni_{71}Cr_{14}$ alloy measured 23.32wt%, and $Ni_{59}Cr_{24}$ alloy was measured 23.03wt%. And the maximum shear bonding strength was measured 58.02MPa between $Ni_{59}Cr_{24}$ alloy and vintage halo(H4 group). Conclusion: The surface property and oxide characteristic three kind of Ni-Cr alloy was similar. and shear bonding strength showed the highest bonding strength in H4 specimens.

A Study on the Property Analysis of Software Reliability Model with Shape Parameter Change of Finite Fault NHPP Erlang Distribution (유한고장 NHPP 어랑분포의 형상모수 변화에 따른 소프트웨어 신뢰성 모형의 속성 분석에 관한 연구)

  • Min, Kyung Il
    • Journal of Information Technology Applications and Management
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    • v.25 no.4
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    • pp.115-122
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    • 2018
  • Software reliability has the greatest impact on computer system reliability and software quality. For this software reliability analysis, In this study, we compare and analyze the trends of the properties affecting the reliability according to the shape parameters of Erlang distribution based on the finite fault NHPP. Software failure time data were used to analyze software failure phenomena, the maximum likelihood estimation method was used for parameter estimation. As a result, it can be seen that the intensity function is effective because it shows a tendency to decrease with time when the shape parameters a = 1 and a = 3. However, the pattern of the mean value function showed an underestimation pattern for the true values when the shape parameters a = 1 and a = 2, but it was found to be more efficient when a = 3 because the error width from the true value was small. Also, in the reliability evaluation of the future mission time, the stable and high trend was shown when the shape parameters a = 1 and a = 3, but on the contrary, when a = 2, the reliability decreased with the failure time. Through this study, the property of finite fault NHPP Erlang model according to the change of shape parameter without existing research case was newly analyzed, and new research information that software developers can use as basic guideline was presented.

Fault Diagnosis for Parameter Change Fault

  • Suzuki, Keita;Fujii, Takao
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2183-2187
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    • 2005
  • In this paper we propose a new fault detection and isolation (FDI) method for those faults of parameter change type. First, we design a residual generator based on the ${\delta}$-operator model of the plant by using the stable pseudo inverse system. Second, the parameter change is estimated by using the property of the block Hankel operator. Third, reliability with respect to stability is quantified. Fourth, the limitations for the meaningful diagnosis in our method are given. The numerical examples demonstrate the effectiveness of the proposed method.

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A Study on the Relationship between Mechanical Property and Impedance Characteristics with respect to Tempering Temperature in Alloy Steels by Electromagnetic Method (자기유도법에 의한 합금강의 템퍼링 온도에 따른 기계적성질과 임피던스 특성과의 관계에 관한 연구)

  • Cho, K.S.;Chang, H.K.;Lee, J.S.;Bae, J.S.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.8 no.1
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    • pp.38-43
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    • 1988
  • Microstructure and mechanical properties of most steels change by heat treat treatment. Such variation of stucture and properties of steel cause an impedance change on electromagnetic induction coil. The objective of this study is, by searching the relationship between the mechanical property or microstructural changes and impedance value of induction coil, to examine the applicablity of a monitoring the heat treated condition of products nondestructively.

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