• 제목/요약/키워드: produced water purification

검색결과 76건 처리시간 0.026초

마이크로 에멀젼 상태에서 전기분해법을 이용한 독성물질 분해 연구 (Decomposition of Toxic Chemicals in Microemulsion by Electrolytic Oxidation Method)

  • 심성현;전병철;정용찬
    • 청정기술
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    • 제14권3호
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    • pp.218-223
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    • 2008
  • 마이크로 에멀젼 수용액에 분산된 반응성 유기화합물을 전기분해를 통하여 얻을 수 있는 수산화이온 및 수소이온을 이용하여 가수분해시키고, 분해속도를 비교하는 실험을 수행하였다. 반응물질로 사용된 p-nitrophenylacetate (PNPA)의 가수분해로부터 발생하는 p-nitrophenoxide 농도 변화에 따른 흡광도 변화를 이용하여 분해속도를 얻을 수 있었다. 자체 조립한 전기분해 장치를 이용하여 전압, 반응온도, 반응물질 양에 따른 분해속도 변화를 관찰하였다. 마이크로 에멀젼 사용으로 인하여 반응물질 용해도를 증가시킬 수 있으며, 전기분해법 사용으로 인하여 반응속도 조절이 용이하며, 유지비용이 저렴하고, 기존 화학물질 투여방법에 비해 소모되는 시약 보충 및 반응 후 부산물 처리 등의 과정이 수월하다. 유기물질 분해에 대한 메커니즘 및 수처리 분야 응용에 대하여 토의하였다.

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고감도 비은염 화상재료 개발연구( I ) - CuPc안료의 승화정제 및 전해석출법에 의한 CuPc 박막의 제작과 전자사진감광체에의 응용 (A study of the High Sensitive Nonsilver Halide Imaging Material( I ) - Purification of CuPc pigment by a train sublimation technique and preparation of CuPc pigment thin films and it's application for electrophotoconductor -)

  • 이상남
    • 한국인쇄학회지
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    • 제8권1호
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    • pp.53-70
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    • 1990
  • It is well known that viologens such as 1.1 - disubstituted 4, 4` - bipyridinium salts and those used as redox indicator, herbicide and electrocheromic display device because those possess the lowest redox potential in any organic system. Viologen salts produced reversible high blue color under the influence of radical cation by photoreduction This study is related to the synthesis of viologen derivatives and the photoreduction property in water solution stats and the polar aprotic polyvinylpyrrolidone(PVP) matrix.

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A Studyd on Adsorptive Properties of Activated Carbons Produced from Rice-Straw

  • Kim, Kun;Lee, Dong-Sun
    • Archives of Pharmacal Research
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    • 제14권3호
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    • pp.249-254
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    • 1991
  • Activated carbons from rice-straw can be used as an adsorbents for the purification of water were prepared and evaluated. The adsorptive capacities of activated carbons were measured by iodine, potassium permangante, phenol and metals. It was observed by electron microscope (SEM) and IR spectrum that organic components in the rice-straw and its carbonization product were disappeared. Slit-shaped and porousstructures were formed by activation. There was no relationship between temperature and adsorption of iodine but adsorption of potassium permanganate increased as temperature rose. The adsorption of the phenol was greater than 99%. The adsorption data of phenol at $25^\circ{C}$ obeyed the Freundlich's isotherm. Various metals except sodium were not removed by activated carbon.

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Penicillium속(屬)이 생산(生産)하는 alkaline pretease에 관(關)하여 (Studies on the pretense produced by Penicillium species)

  • 김경순
    • 한국식품영양과학회지
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    • 제6권1호
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    • pp.27-33
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    • 1977
  • The alkaline protease was isolated from the culture of Penicillium species (P-46) grown in the wheat bran media. The crude purification of this enzyme was carried out by extraction with distilled water and precipitated with 0.7-saturated ammonium sulfate, then dialysis for 3days. The activity of this enzyme was determined by Folin's colorimetric method. The results were as follows; 1. The optimum pH and temperature of this enzyme were pH 8.4 and $45^{\circ}C$. 2. This enzyme was stable at pH $7.0{\sim}9.0$. 3. This enzyme was not inactivated by treatment in lower temperature than $30^{\circ}C$. 4. The activity of this enzyme was strongly inhibited by $Hg^{++}$ and $Cu^{++}$, but slightly by $Ag^+$ 5. This enzyme was not inhibited by cystein, thiourea, ${\varepsilon}-aminocaproic$ acid, 2, 4-DNP, EDTA but strongly inhibited by PCMB.

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Pseudomonas fluorescens에 의한 Furfural의 분해대사 조절물질에 관하여 (Purification and Characterization of the Regulatory Substance of Furfural Biodegradation in Pseudomonas fluorescens)

  • 이병웅;유병설;이계준;하영칠
    • 미생물학회지
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    • 제23권4호
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    • pp.241-247
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    • 1985
  • Pseudomonas fluorescens에 의해 세포외에 생산된 furfural의 furoic acid로의 생물학적 전환을 촉진시키는 ninhydrin 반응에 양성인 대사물 (Ninhydrin positive Substance=NPS)을 ion exchange chromatography와 gel permeation chromatography 그리고 cellulose columm chromatography에 의하여 분리, 정제하였다. IR spectrophotometry와 $^H$-NMR spectrometry 그리고 $^{13}C-NMR$ spectrometry에 의해 이 NPS는 -$^H$ and $-NH_2$와 그리고 $-CH_2-OH$group을 갖는 유기물질로 추정된다.

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해양 방선균 유래 물질의 정제 및 항균 활성 (Purification and Antibacterial Activity of Compound Derived from Marine Actinomycetes)

  • 정성윤
    • 한국환경과학회지
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    • 제33권3호
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    • pp.205-215
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    • 2024
  • Antibiotics are substances produced by microorganisms that kill or inhibit and are essential for infectious diseases management. This study aimed to provide basic data for overcoming antibiotic resistance in the marine bacterium LJ-18. The API 20NE and API 50CH kits were used to identify this microorganism. Morphological, physiological, and biochemical properties were investigated using MacFaddin's manuals. Subsequently, isolated LJ-18 was found to belong to a genus of Streptomyces that forms mycelia. LJ-18 also grew well at 28-32℃ on modified Bennett's agar. To isolate and purify the antibacterial compound, LJ-18 culture was divided into ethyl acetate and distilled water fractions. Considerable antimicrobial activity against various pathogenic microorganisms, including methicillin-resistant Staphylococcus aureus (MRSA), was confirmed in the C18 ODS open column fractions. Peak 2 compound was obtained using reversed-phase HPLC. As a result, this compound had a significant antimicrobial activity against various pathogenic microorganisms. In particular, it showed strong activity against MRSA, Mycobacterium smegmatis, Bacillus subtilis, Bacillus cereus, and Staphylococcus aureus.

지하수 불소제거를 위한 고흡착 골탄의 현지 제조기술 이전과 정수장치의 지속 가능한 비즈니스 모델 개발 (Sustainable Business Model of Water Purification Equipment and Local Manufacturing Technology Transfer of High Adsorption Bone Char to Remove Fluoride from Groundwater)

  • 맹민수;이혜인;변정섭;박효진;신귀암
    • 적정기술학회지
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    • 제7권1호
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    • pp.41-50
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    • 2021
  • 탄자니아 아루샤에 위치한 Gongali model Co. Ltd는 지하수 불소제거를 위해서 현지에서 생산한 골탄을 이용하여 Nanofilter water station을 운영하고 있다. 현지에서 생산된 골탄은 탁도와 유기물 농도가 높아서 색도가 유발되는 문제가 있다. 또한, 불소 흡착 효율이 낮아서 골탄의 짧은 교체 주기로 인해 유지관리 비용이 증가하는 비용적 어려움도 있다. 이를 보완하기 위해서 고흡착 골탄을 보급하기 위한 목적으로 현지형 가마를 국내에서 제작하여 현지에 보급하는 사업을 추진하였다. 현지에서 고흡착 골탄을 생산함으로써 Nanofilter water station의 운영 효율이 증가하였으며 지역 주민들에게 안정적으로 지속해서 식수를 제공할 수 있었다. 또한, Gongali model Co. Ltd에게 지속 가능한 비즈니스 모델을 제시함으로써 고흡착 골탄의 지속성과 Nanofilter water station의 확산 계획을 제시하였다. 결과적으로 본 사업을 통해서 지속적으로 저소득층과 소외계층에게 저렴한 식수를 공급할 수 있는 방안을 마련할 수 있었다.

정수슬러지를 사용한 조합토의 개발 (Development of Grogged Clay Used Water-purified-sludge)

  • 정재진;이용석;이병하
    • 한국세라믹학회지
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    • 제51권4호
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    • pp.317-323
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    • 2014
  • People could not imagine living without tab water. However, the water filtering process at a purification plant used to produce tab water creates tons of sludge, which is generally wasted. This sludge waste consists of (1) mineral elements, such as sand, (2) organic materials, and (3) a coagulant, which agglomerates the two. As an enormous amount of sludge waste is generated every year, numerous studies have been carried out to identify how to deal with this problem. Currently, however, most of the sludge waste is directly discarded in landfills. In the present study, water-purified sludge waste received a heat treatment at $1300^{\circ}C$ and was then ground into particles to be used as a ceramic material. Next, the resultant particles were compounded with chamotte substitutes to produce grogged clay that is suitable for wheel-throwing ceramics. Consequently, the plasticity of the sludge waste decreased as the content of calcination increased. Thus, it is considered that wheel throwing is available only up to PBF-3. Thus, it is available for wheel throwing and has a high strength of 864 $kgf/cm^2$ with less than 0.2 percent of porosity and absorption ratio were displayed in PBF-2 at $1280^{\circ}C$ with 20 percent of calcination from the purified sludge. Therefore, the PBF-2 body produced in this study was considered to be capable of replacing grogged clay in the market.

Antifungal Mechanism and Properties of Antibiotic Substances produced by Bacillus subtilis YB-70 as a Biological Control Agent

  • Kim, Yong-Su;Kim, Sang-Dal
    • Journal of Microbiology and Biotechnology
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    • 제4권4호
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    • pp.296-304
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    • 1994
  • Antibiotic substances were produced by Bacillus subtilis YB-70, a potential biocontrol agent found to suppress root-rot of eggplant (Solanum melonggena L) caused by Fusarium solani, in a dextrose glutamate medium and isolated by isoelectric precipitation. Partial purification was performed by column chromatography on silica gel with two solvent systems: chloroform-methanol and methanol-chloroform-water as eluting solvents, This active fraction YBS-1 s contained antifungal activity were soluble in ethanol, methanol, and water, but were not soluble in other solvents including acetone, butanol, ethyl ether, dimethylformamide, propanol, and etc. High performance liquid chromatography and thin layer chromatographic separation of YBS-1s showed that they have been composed of three biological active bands that were named YBS-1A, -1B, and -1C. The substances were stable to heat and resistant to protease. YBS-1s were active against a wide range of plant pathogenic fungi but did not inhibit the growth of bacteria and yeasts. They were not only fungicidal but also fungistatic against chlamydospores of F. solani. The $ED_{50}$ values for the chlamydospore germination and the germ-tube growth of F. solani were $O.725\mu\textrm{m}/ml\;and\;O.562\mu\textrm{m}/ml$, respectively. Microscopic observations proved the substances restricted the growth of phytopathogenic fungus F. solani by spore burst followed by dissolving of its germ-tube, and caused abnormal hyphal swelling after application to chlamydospores or growing hyphae. Cultural filtrate of B; subtilis YB-70 also suppressed the development of root-rot of eggplant in pot tests.

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수단그라스 Biochar를 적용한 수중 암모니아성 질소(NH4-N) 흡착 특성 (The characteristics of aqueous ammonium-adsorption of biochar produced from Sudangrass)

  • 류도윤;김도용;김대기
    • 유기물자원화
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    • 제31권2호
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    • pp.63-71
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    • 2023
  • 수계 내 질소의 증가는 부영양화나 녹조 및 적조현상을 유발하여 수계의 파괴 및 물의 자정능력을 저하시켜 전세계적으로 중요한 환경문제가 되었다. 수계 내 질소의 가장 일반적인 형태는 암모늄(NH4+)이온의 형태로 폐수로부터 유입되는 가장 많은 부분을 차지하고 있으며 부영양화의 주요 원인이 되고 있어 암모늄 제거에 있어 적절한 처리 및 방안이 필요하다. 본 연구에서는 생장력이 좋은 바이오매스 중 하나인 수단그라스를 적용하여 바이오차를 생산하였으며, 200℃-400℃ 탄화 온도 조건 변화에 따른 과정에서 생성된 수단그라스 바이오차를 활용하여 암모늄 이온, 10~100ppm 농도 변화에 따른 흡착능력 분석하였으며, 이 결과를 통해 흡착제로써 활용 가능성을 평가하고자 하였다. 탄화반응으로 인해 수단그라스의 화학구조가 분해되면서 바이오차의 탄소 및 고정 탄소함량이 증가하였다. 바이오차의 pH는 탄화 온도가 높을수록 pH와 전기전도도가 높아지면서 전기전도도로 인해 양이온에 대해 높은 흡착 가능성을 보였다. 흡착실험 결과를 바탕으로 NH4-N의 농도가 높아지면서 최대 54.5%, 최저 17.4%의 제거효율을 보였으며, 탄화 온도가 높을수록 바이오차의 기공 및 비표면적 증가로 인해 오염물질의 흡착이 용이해져 NH4-N의 제거효율이 높아졌다. FT-IR 분석 결과, 탄화반응의 고온으로 인해 전체적인 표면 작용기의 감소가 나타났다.