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Preparation of Electrolyte Thin Film for Anode Support Type Solid Oxide Fuel Cells by Electrophoretic Deposition and Dip-Coating (전착법과 담금법에 의한 음극지지형 SOFC 지르코니아 전해질막 제조)

  • 김상우;이병호;손용배;송휴섭
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.791-798
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    • 1999
  • The preparation method of yttria-stabilized zirconia(YSZ) thin film for an anode support type solid oxide fuel cell(SOFC) by electrophoretic deposition(EPD) and dip-coating was studied. And the difference in both preparation method was investigated through basic understanding of processing parameters which may significantly affect weight microstruxcture and defect of film. In dip-coating the thickness of film increased with time until 30 s and then the weight of film decreased with time due to particle falling off from the coagulated film. In EPD although the weight of film increased with time and applied constant-current sagging of the film was observed when the applied current was less that 0.035 mA/$cm^2$ and more than 120 s. Since YSZ thin film by EPD on porous substrate was dense smooth and homogeneous it was expected to be suitable for the electrolyte of an anode support type SOFC.

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The Enhancement of Selectivity in Thick Film SnO2 Gas Sensors by Additives and Pattern Recognition (첨가제 및 패턴인식에 의한 후막 SnO2 가스센서의 선택성 향상)

  • 정해원;김종명;박희숙;윤기현
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1073-1077
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    • 2003
  • The Sn $O_2$-based gas sensors can detect inflammable and toxic gases of low concentration by the modulation of surface resistance, but they lack in selectivity on the whole. To give selectivity to the Sn $O_2$-based gas sensors, studies on the sensing mechanism, selective gas sensing materials and signal processing techniques are demanded. Ethanol (C$_2$ $H_{5}$OH) and acetonitrile ($CH_3$CN) were confirmed to undergo catalytic oxidation on Sn $O_2$ by gas chromatography. PdCl$_2$-doped Sn $O_2$ showed excellent sensitivity to ethanol and acetonitrile, while La$_2$ $O_3$-doped Sn $O_2$ showed excellent sensitivity to ethanol, but poor sensitivity to acetonitrile. Using these two sensors and pattern recognition, the selectivity to acetonitrile is greatly enhanced. The minimum detection level of acetonitrile was 15 ppm in air and 20 to 100 ppm when exposed to interfering gases together with acetonitrile.

Fabrication and Characterization of Biphasic Calcium Phosphate Scaffolds with an Unidirectional Macropore Structure Using Tertiary-Butyl Alcohol-Based Freeze-Gel Casting Method (동결-젤 주조 공정 기반 삼차부틸알코올을 이용한 단일방향 기공구조를 가지는 이상인산칼슘 세라믹 지지체의 제조 및 특성평가)

  • Kim, Kyeong-Lok;Ok, Kyung-Min;Kim, Dong-Hyun;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Ceramic Society
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    • v.50 no.4
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    • pp.263-268
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    • 2013
  • Porous biphasic calcium phosphate scaffolds were fabricated by a freeze-gel casting technique using a tertiary-butyl alcohol (TBA)-based slurry. After sintering, unidirectional macropore channels of scaffolds aligned regularly along the TBA ice growth direction were tailored simultaneously with micropores formed in the outer wall of the pore channels. The crystallinity, micro structure, pore configuration, bulk density, and compressive strength for the scaffolds were investigated with X-ray diffractometery, scanning electron microscopy analysis, a water immersion method, and a universal test machine. The results revealed that the sintered porosity and pore size generally resulted in a high solid loading which resulted in low porosity and small pore size, which relatively increased the higher compressive strength. After being sintered at $1100-1300^{\circ}C$, the scaffolds showed an average porosity and compressive strength in the range 35.1-74.9% and 65.1-3.0 MPa, respectively, according to the processing conditions.

A brief review of the bilayer electrolyte strategy to achieve high performance solid oxide fuel cells (고성능 고체산화물 연료전지를 위한 이중층 전해질 전략)

  • Park, Jeong Hwa;Kim, Doyeub;Kim, Kyeong Joon;Bae, Kyung Taek;Lee, Kang Taek
    • Ceramist
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    • v.23 no.2
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    • pp.184-199
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    • 2020
  • The solid oxide fuel cells (SOFCs) are the one of the most promising energy conversion devices which can directly convert chemical energy into electric power with high efficiency and low emission. The lowering operating temperature below 800 ℃ has been considered as the mostly considerable research and development for commercialization. The major issue is to maintain reasonably high performance of SOFCs at reduced temperatures due to increment of polarization resistance of electrodes and electrolyte. Thus, the alternative materials with high catalytic activities and fast oxygen ion conductivity are required. For recent advances in electrolyte materials and technology, newly designed, highly conductive electrolyte materials and structural engineering of them provide a new path for further reduction in ohmic polarization resistance from electrolytes. Here, a powerful strategy of the bilayer concept with various oxide electrolytes of SOFCs are briefly reviewed. These recent developments also highlight the need for electrolytes with greater conductivity to achieve a high performance, thus providing a useful guidance for the rational design of cell structures for SOFCs. Moreover, cell design, materials compatibility, processing methods, are discussed, along with their role in determining cell performance. Results from state-of-the-art SOFCs are presented, and future prospects are discussed.

Comparison analysis of big data integration models (빅데이터 통합모형 비교분석)

  • Jung, Byung Ho;Lim, Dong Hoon
    • Journal of the Korean Data and Information Science Society
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    • v.28 no.4
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    • pp.755-768
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    • 2017
  • As Big Data becomes the core of the fourth industrial revolution, big data-based processing and analysis capabilities are expected to influence the company's future competitiveness. Comparative studies of RHadoop and RHIPE that integrate R and Hadoop environment, have not been discussed by many researchers although RHadoop and RHIPE have been discussed separately. In this paper, we constructed big data platforms such as RHadoop and RHIPE applicable to large scale data and implemented the machine learning algorithms such as multiple regression and logistic regression based on MapReduce framework. We conducted a study on performance and scalability with those implementations for various sample sizes of actual data and simulated data. The experiments demonstrated that our RHadoop and RHIPE can scale well and efficiently process large data sets on commodity hardware. We showed RHIPE is faster than RHadoop in almost all the data generally.

Analysis of Two Dimensional and Three Dimensional Supersonic Turbulence Flow around Tandem Cavities

  • Woo Chel-Hun;Kim Jae-Soo;Lee Kyung-Hwan
    • Journal of Mechanical Science and Technology
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    • v.20 no.8
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    • pp.1256-1265
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    • 2006
  • The supersonic flows around tandem cavities were investigated by two-dimensional and three-dimensional numerical simulations using the Reynolds-Averaged Navier-Stokes (RANS) equation with the k- ω turbulence model. The flow around a cavity is characterized as unsteady flow because of the formation and dissipation of vortices due to the interaction between the freestream shear layer and cavity internal flow, the generation of shock and expansion waves, and the acoustic effect transmitted from wake flow to upstream. The upwind TVD scheme based on the flux vector split with van Leer's limiter was used as the numerical method. Numerical calculations were performed by the parallel processing with time discretizations carried out by the 4th-order Runge- Kutta method. The aspect ratios of cavities are 3 for the first cavity and 1 for the second cavity. The ratio of cavity interval to depth is 1. The ratio of cavity width to depth is 1 in the case of three dimensional flow. The Mach number and the Reynolds number were 1.5 and $4.5{\times}10^5$, respectively. The characteristics of the dominant frequency between two- dimensional and three-dimensional flows were compared, and the characteristics of the second cavity flow due to the first cavity flow was analyzed. Both two dimensional and three dimensional flow oscillations were in the 'shear layer mode', which is based on the feedback mechanism of Rossiter's formula. However, three dimensional flow was much less turbulent than two dimensional flow, depending on whether it could inflow and outflow laterally. The dominant frequencies of the two dimensional flow and three dimensional flows coincided with Rossiter's 2nd mode frequency. The another dominant frequency of the three dimensional flow corresponded to Rossiter's 1st mode frequency.

Image Discriminal Analysis for Detecting a Esophagitis (식도염 진단을 위한 영상 판별분석)

  • Seo K. W.;Lee C. W.;Kim W.;Lee S. Y.;Lee D. W.
    • Journal of Biomedical Engineering Research
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    • v.25 no.6
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    • pp.545-550
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    • 2004
  • An Image processing algorithm was developed and tested to detect abnormal parts, such as esophagitis, with the information on the color and the texture in a digital clinic endoscopic image by using discriminal analysis. In order to develope the algorithm, the critical parameters from many parameters were found to distinguish between normal and abnormal part in the various images. The Inflammation and ulceration which are very important diagnostic indexes were detected by the algorithm. The algorithm proved to a reliable program for detecting abnormal parts with 20 images. A success rate was 92.8% and 92.4% in the calibration stage and the validation stage by using the algorithm with discriminal analysis.

East Reconstruction of 3D Human Model from Contour Lines (외곽선을 이용한 고속 3차원 인체모델 재구성)

  • Shin Byeong-Seok;Roh Sung;Jung Hoe-Sang;Chung Min Suk;Lee Yong Sook
    • Journal of Biomedical Engineering Research
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    • v.25 no.6
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    • pp.537-543
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    • 2004
  • In order to create three-dimensional model for human body, a method that reconstructs geometric models from contour lines on cross-section images is commonly used. We can get a set of contour lines by acquiring CT or MR images and segmenting anatomical structures. Previously proposed method divides entire contour line into simply matched regions and clefts. Since long processing time is required for reconstructing cleft regions, its performance might be degraded when manipulating complex data such as cross-sections for human body. In this paper, we propose a fast reconstruction method. It generates a triangle strip with single tiling operation for simple region that does not contain branch structures. If there exist branches in contour lines, it partitions the contour line into several sub-contours by considering the number of vertices and their spatial distribution. We implemented an automatic surface reconstruction system by using our method which reconstructs three-dimensional models for anatomical structures.

The Implementation of Hierarchical Artificial Neural Network Classifier for Chromosome Karyotype Classification (염색체 핵형 분류를 위한 계층적 인공 신경회로망 분류기 구현)

  • Jeon, Gye-Rok;Choe, Uk-Hwan;Nam, Gi-Gon;Eom, Sang-Hui;Lee, Gwon-Sun;Jang, Yong-Hun
    • Journal of Biomedical Engineering Research
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    • v.18 no.3
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    • pp.233-241
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    • 1997
  • The research on chromosomes is very significant in cytogenetics since genes of the chromosomes control revelation of the inheritance plasma. The human chromosome analysis is widely used to study leukemia, malignancy, radiation hazard, and mutagen dosimetry as well as various congenital anomalies such as Down's, Klinefelter's, Edward's, and Patau's syndrome. The framing and analysis of the chromosome karyogram, which requires specific cytogenetic knowledge is most important in this field. Many researches on automated chromosome karyotype analysis methods have been carried out, some of which produced commercial systems. However, there still remains much room to improve the accuracy of chromosome classification and to reduce the processing time in real clinic environments. In this paper, we proposed a hierarchical artificial neural network(HANN) to classify the chromosome karyotype. We extracted three or four chromosome morphological feature parameters such as centromeric index, relative length ratio, relative area ratio, and chromosome length by preprocessing from ten human chromosome images. The feature parameters of five human chromosome images were used to learn HANN and the rest of them were used to classify the chromosome images. The experiment results show that the chromosome classification error is reduced much more than that of the other researchers using less feature parameters.

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Isolation and Growth Characteristics of Alkalophilic Bacillus sp. for Removal of Anthraquinone Dye. (Anthraquinone계 염료의 제거를 위한 호알칼리성 Bacillus sp.의 분리와 성장 특성)

  • 김정목
    • Microbiology and Biotechnology Letters
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    • v.29 no.2
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    • pp.67-71
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    • 2001
  • Isolation and Growth Characteristics of AIkalophilic Bacillus sp. for Removal of Anthraquinone Dye. Kim, Jeong-Mog. School of Environmental Information, Taekyeung College, Kyungsan, 712-850, Korea -Alkalophilic strain degrading and decolorizing anthraquinone dye, Remazol brilliant blue R was isolated from natural system and named as Bacillus sp. ARB!. The optimal temperature and pH of Bacillus sp. ARBI were 35°C and 9.0, respectively. The pH of culture media during the fermentation were changed from 10 and 10.5 of initial values to 9.3 and 9.4 after 40 hrs, respectively. Decolorization efficiency in aerobic shaking culture of Bacillus sp. ARBI was markedly higher than that in standing culture. At the optimal culture condition, decolorization efficiency by the Bacillus sp. ARBl was 93% after 32 hrs batch culture. In the case of batch culture using real dye processing wastewater, dye decolorization efficiency of Bacillus sp. ARBl was 78% after 40 hrs.

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