• 제목/요약/키워드: primary pollutants

검색결과 122건 처리시간 0.022초

고로슬래그 기반 분말활성탄 혼입방법에 따른 미세먼지 흡착형 경화체의 특성 (Properties of Fine Dust Adsorption Matrix According to the Powdered Activated Carbon Mixing Method based on Blast Furnace Slag)

  • 김연호;조은석;이상수
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
    • /
    • pp.68-69
    • /
    • 2020
  • Recently, the problem of air pollution is drawing attention as a social problem worldwide. Particularly, fine dust is the biggest issue among air pollutants, and it is analyzed that fine dust is generated from air pollutants such as burning fossil fuels such as petroleum or coal, or exhaust gases from automobiles. In addition, yellow dust originating from China adjacent to Korea flows into the Korean Peninsula in a western wind, causing the concentration of fine dust to deteriorate. Fine dust is a harmful substance to the human body such as asthma or respiratory disease, and awareness of the risk is also increasing to a degree designated as a primary carcinogen. In this study, as a method for improving the indoor air quality, the Properties of the matrix according to the mixing ratio of powdered activated carbon based on blast furnace slag are reviewed. The flexural strength and compressive strength were measured, and a fine dust concentration measurement experiment will be conducted later.

  • PDF

Biochemical and Molecular Characterization of Laccases from Wild Mushrooms

  • Ro, Hyeon-Su
    • 한국균학회소식:학술대회논문집
    • /
    • 한국균학회 2014년도 춘계학술대회 및 임시총회
    • /
    • pp.43-43
    • /
    • 2014
  • White rot fungi have been useful source of enzymes for the degradation of environmental pollutants including polycyclic aromatic hydrocarbons (PAHs) and synthetic dyes. PAHs are widespread organic compounds present in fossil fuels and are routinely generated by incomplete fuel combustion. PAHs are some of the major toxic pollutants of water and soil environments. Synthetic dyes are major water-pollutants, which are toxic to organisms in water environments and interfere photosynthesis of water plants. Removal of PAHs and synthetic dyes has been of interests in the environmental science especially in the environmental microbiology. Mushrooms are fungal groups that function as primary degraders of wood polyphenolic lignin. The ligninolytic enzymes produced by mushroom, including manganese peroxidase, lignin peroxidase, and laccase, mediate the oxidative degradation of lignin. The catalytic power of these enzymes in the degradation of aromatic ring compounds has been sought for the degradation of various organic compounds. In this project, we have screened 60 wild mushroom strains for their degradation activity against two representative PAHs, naphthalene and anthracene, and five aromatic dyes, including alizarin red S, crystal violet, malachite green, methylene blue, rose bengal. The degradation of PAHs was measured by GC while the decolorization of dyes was measured by both UV spectrophotometer and HPLC. As results, 9 wild mushroom strains showed high activity in degradation of PAHs and textile dyes. We also describe the secretive enzyme activities, the transcription levels, and cloning of target genes. In conjunction with this, activities of degradative enzymes, including laccase, lignin peroxidase, and Mn peroxidase, were measured in the liquid medium in the presence of PAHs and dyes. Our results showed that the laccase activity was directed correlated with the degradation, indicating that the main enzyme acts on PAHs and dyes is the laccase. The laccase activity was further simulated by the addition of $Cu^{2+}$ ion. Detailed studies of the enzyme system should be sought for future applications.

  • PDF

서울 수도권 지역의 광화학오존에 관한 연구 (On Surface Ozone Observed in the Seoul Metropolitan Area during 1989 and 1990)

  • 정용승;정재섭
    • 한국대기환경학회지
    • /
    • 제7권3호
    • /
    • pp.169-179
    • /
    • 1991
  • Atmospheric $O_3$ in the biosphere is formed under the favourable meteorological condition, when the primary pollutants, such as $NO_2, HC, CO, CH_4$, etc., react with over constituents. Observed annual average concentrations for 1989 and 1990 were 11.8 and 10.4 ppb, respectively. THe number of days measured ozone over 80 ppb in Seoul were 36 in 1989 and 39 in 1990. In general, monthly maximum values occurred in May and August. In comparison with 1 $\sim$ 2 maxima of $O_3$ distribution in large cities in other countries, it was found that there were 3 $\sim$ 4 maxima in Seoul and its suburbs. Topographic effects, resulted by wind channelling in the Han River valley and by the blocking of air pollutants in the mountain, appeared to produce multiple centres of $O_3$ maxima in Seoul. Surface $O_3$ values were low with decreasing solar radiation, when the cloudiness increased and precipitation occurred. According to 12 cases examined, 2 cases shown here, $O_3$ values exceeding 80 ppb were occurred when the Korean peninsular was under the influence of the backside airflows with high intensity of solar radiation. Occasionally, sea breezes were observed to occur in warm seasons, and the chanelling effect of the Han River valley appeared to increase the general wind (speed) to the east side of Seoul. In this meso-scale situation $O_3$ in downwind is highly correlated with precursors. The sea breeze of 2 $\sim$ 4 m $s^{-1}$ will take 3 $\sim$ 5 hours to transport photochemical precursors for 20 $\sim$ 50 km. In turn the areas of maximum $O_3$ occurrence in Seoul are in the range of meso-scale transport of air pollutants.

  • PDF

동북아시아 대기오염물질의 이동 패턴에 따른 장거리 수송 특성 연구 (Characteristics of Long-Range Transport of Air Pollutants due to Different Transport Patterns over Northeast Asia)

  • 박신영;김연종;김철희
    • 한국대기환경학회지
    • /
    • 제28권2호
    • /
    • pp.142-158
    • /
    • 2012
  • This paper investigates the physical and chemical characteristics of long-range transport (LRT) process of air pollutants by employing the MM5-CMAQ and its comparison with local emission dominant (LED) case over northeast Asia. We first classified high air pollution days into LRT and LED cases based on the synoptic meteorological variables of vorticity and geostrophic wind speed/direction at a geopotential level of over 850hPa. LRT cases are further categorized into three types of transport patterns (LRT-I-III) according to the air mass pathways from source regions. LRT-I-III are originated from northern, central, and southern China, respectively, identified by back trajectory analysis. Three LRT-I-III groups have different and unique locations of high pressure and transport pathways. The chemical characteristics showed that the simulated spatial distributions varied in terms of locations of maximum concentrations and the temporal variation of surface concentrations. The primary air pollutants such as $NO_x$, $PM_{10}$ and $SO_2$ of all of three LRT cases are well transported into Korea peninsula with different concentration levels. Of LRT cases, LRT-II has the greatest effect on air quality of Korea peninsula, followed by LRT-I and LRT-III. In comparison with LRT, the LED case shows relatively higher air pollution concentrations in general, but showed a variety of different air quality levels following the emission strength pattern. These widely varying patterns are impling the case dependent multi-directional approach for the development of indicators of long-range transport process over northeast Asia.

Assessment of Photochemistry of OH and NO$_3$ at Jeju Island During Asian Dust-Storm Period of the Spring 2001

  • Shon, Zang-Ho;Keith N. Bower;Kim, Ki-Hyun;Lee, Gangwoong;Kim, Jiyoung
    • 한국대기환경학회:학술대회논문집
    • /
    • 한국대기환경학회 2002년도 추계학술대회 논문집
    • /
    • pp.429-429
    • /
    • 2002
  • This study examines the influence of long-range transport of dust particles and air pollutants on photochemistry of OH and NO$_3$ at Jeju Island (33.17$^{\circ}$ N, 126.10$^{\circ}$ E) during the Asian dust-storm (ADS) period in April 2001. The atmospheric concentrations of criteria pollutants (O$_3$, NO$_2$, CO) and sulfur species were measured at a ground station on Jeju Island, Korea as part of the ACE-Asia intensive operation. Three ADS events were observed during the periods of 10-12, 13-14, and 25-26 April, respectively. The concentrations of the criteria pollutants (i.e., $O_3$, NO$_2$, and SO$_2$) were not significantly different from those during the non-Asian-dust-storm (NADS) period. Average OH and NO$_3$ levels at Jeju Island during the study period (ADS and NADS) were estimated to be 4-10 $\times$ 10$^{5}$ moleculescm$^{-3}$ and 2-4 pptv, respectively. Two main sources of OH radical were the primary production from the reaction of water vapor ($H_2O$) and O(1D) radicals and the reaction of HO$_2$ with NO. CO was a dominant sink of OH during the ADS period: whereas NO$_2$ was the most important during the NADS period. for NO$_3$ radical, a reaction of NO$_2$ with $O_3$ was the most important atmospheric source; while $N_2$O$_{5}$ uptake on dust particles was the most dominant sink during the ADS period.

  • PDF

A Review on the Photochemical Oxidant Modeling as Applied to Air Quality Studies in Complex Terrain

  • Lee Hwa-Woon;Kim Yoo-Keun;Won Gyeong-Mee;Park Jong-Kil
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • 제1권1호
    • /
    • pp.19-33
    • /
    • 1997
  • The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorological processes. In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification process through observation is emphasized.

  • PDF

${\cdot}$공간적 고해상도 자동차 배출량 모형의 개발 (Development of Vehicle Emission Model with a High Resolution in Time and Space)

  • 박성규;김신도;박기학
    • 한국환경보건학회지
    • /
    • 제30권3호
    • /
    • pp.293-299
    • /
    • 2004
  • Traffic represents one of the largest sources of primary air pollutants in urban area. As a consequence, numerous abatement strategies are being pursued to decrease the ambient concentration of pollutants. A characteristics of most of the these strategies is a requirement for accurate data on both the quantity and spatial distribution of emissions to air in the form of an atmospheric emission inventory database. In the case of traffic pollution, such an inventory must be compiled using activity statistics and emission factors for vehicle types. The majority of inventories are compiled using passive data from either surveys or transportation models and by their very nature tend to be out-of-date by the time they are compiled. The study of current trends is towards integrating urban traffic control systems and assessments of the environmental effects of motor vehicles. In this study, a model of vehicle emission calculation by using real-time traffic data was studied. Traffic data, which are required on a street-by-street basis, is obtained from induction loops of traffic control system. It is possible that characteristics of hourly air pollutants emission rates is obtained from hourly traffic volume and speed. An emission rates model is allocated with a high resolution space by using geographic information system (GIS). Vehicle emission model was developed with a high resolution spatial, gridded and hourly emission rates.

한반도 도서 지역 대기질 영향요인에 관한 연구 -울릉도, 제주도, 백령도 등을 중심으로 (A Study on the Factors Influencing Air Pollutions in the Islands of Korean Peninsula: Focusing on the Case of Ulleung, Jeju, and Baengnyong Island)

  • 황규원;김동연;진세준;김임현
    • 한국산학기술학회논문지
    • /
    • 제21권11호
    • /
    • pp.814-824
    • /
    • 2020
  • 최근 미세먼지, O3 등의 대기오염물질에 대한 국민 관심이 증대되고, 대기질 개선을 위한 정부의 노력이 지속되고 있다. 특히 대기오염물질로 인한 경제적 피해와 국민 건강 위협이 증대되고 있는 실정이다. 본 연구는 국가배경농도 측정 지점이 위치한 울릉도, 제주도, 백령도 3개의 도서 지역을 대상으로 청정 지역의 대기오염도와 기상조건을 분석하여, 각 지역의 2차 대기오염물질 기여도를 평가하고 지역 간 차이를 비교하였다. SO2, NO2, CO, O3, PM10, PM2.5 등 대기오염물질의 1시간 평균농도와 동일 시간대 풍속, 강수량, 일조시간 등의 기상조건을 활용하였다. 연구방법은 지역별 대기오염물질과 기상조건 간의 상관관계를 분석하고, SO2, NO2, CO 등 1차 생성물질을 독립변수로, PM10, PM2.5, O3 등 1차 생성물질이 포함된 2차 생성물질을 종속변수로 설정하였다. 국내외 선행연구 분석을 통해 대기질 영향요인을 탐색하고, 도서 지역의 기상조건을 통제하여 회귀분석을 수행함으로써 지역별 특성을 파악하였다. 종합하면 도서 지역의 대기질 측면에서 지역별 주요 영향요인과 기여도가 상이하여 오염발생 원인과 영향에 대한 지속적인 모니터링이 필요하다.

담수호 수자원보전을 위한 수질정화 연못-습지 시스템의 초기처리수준 (Treatment Efficiency of a Pond-Wetland System for the Water Quality Conservation of Estuarine Lake)

  • 양홍모
    • 한국환경복원기술학회지
    • /
    • 제4권4호
    • /
    • pp.64-71
    • /
    • 2001
  • Treatment efficiency was examined of a pond-wetland system constructed for water quality conservation of Koheung Estuarine Lake over one year after its establishment in July 2000. The system is composed of primary and secondary ponds in series and six wetland cells in parallel. Cattails (Typha angustiflora) were planted in three wetland cells and common reeds (Phragmites australis) in three other cells. Water pumped from Sinyang Stream flowing into the Lake was funneled into primary pond whose effluent was discharged into secondary pond by gravity flow. Effluent from secondary pond was distributed into each wetland cell. SS, $BOD_5$, T-N, and T-P concentrations in influent to primary pond, and effluent from primary pond, secondary pond, and three wetland cells planted with cattails were analyzed for about one year from August 2000 to August 2001. The removal rates at primary pond for SS, $BOD_5$, T-N and T-P were 29%, 30%, 15%, and 36%, respectively. The abatement rates at secondary pond for SS, $BOD_5$, T-N and T-P were 38%, 40%, 30%, and 47%, respectively. The reduction rates measured at three cattail-planted wetland cells for SS, $BOD_5$, T-N and T-P were 54%, 57%, 60%, and 68%, respectively. Considering early stage of the pond-wetland system and inclusion of winter during the research period, its treatment efficiency was rather good. Cattails had not yet grown to dense stands due to initial establishment period, which resulted in slightly lower treatment efficiencies of wetland cells for these pollutants, compared with those of ponds.

  • PDF

하층대기의 연직 안정도 지표를 이용한 차량 2부제의 수도권 대기오염도 저감효과 분석 (Evaluation of the Effect of Traffic Control Program on the Ambient Air Quality in Seoul Metropolitan Area Using the Lower Level Stability Index of Atmosphere)

  • 김철희;박일수;이석조;김정수;홍유덕;한진석;진형아
    • 한국대기환경학회지
    • /
    • 제21권2호
    • /
    • pp.243-257
    • /
    • 2005
  • The effects of Traffic Control Program (TCP) on the ambient urban air quality of SO$_{2}$, NO$_{2}$, O$_{3}$, and PM$_{10}$ were evaluated in Seoul metropolitan area by using the lower atmospheric vertical stability index and daily mean wind speeds. The vertical stability index; temperature lapse rate between 1000 hPa and 850 hPa geopotential height fields, were used to identify daily vertical stability index during the 2002 World Cup period where traffic amount was reportedly reduced to half the number of vehicles. The indicated air quality levels of TCP days were then compared with those of the cases observed with analogous vertical stability during the recent 3 years from 2000 to 2002. The result indicates that the effect of TCP on the primary air pollutants are found to be approximately 39$\%$, 23$\%$ and 20$\%$ lower for SO$_{2}$, NO$_{2}$ and PM$_{10}$, respectively. The secondary air pollutant; ozone, showed relatively smaller decreasing rate (13$\%$) of daily mean concentrations (even increased during the night time). The comparison of daily maximum or peak concentrations reveals that the pronounced decreasing effects of TCP on the ambient air quality for both primary and secondary air pollutants, suggesting that TCP is one of the effective strategies to control peak or higher concentrations for most urban scale air pollutants in and around the Seoul metropolitan area.