• Title/Summary/Keyword: pretreatment temperature

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Physico-Chemical Pretreatment of Herbaceous Biomass by Organosolv Flow-Through Process (초본계 바이오매스의 물리-화학적 유기용매 전처리 공정)

  • Kim, Jun Seok
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.441-446
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    • 2018
  • Herbaceous biomass is easier at chemical conversion than woody biomass. However, pretreatment must be needed because it has substantially lignin. Organsolv is good at fractionation of enzymatic hydrolysis inhibitors such as lignin and it is reusable by distillation when it has low molecular weight. Flow-through process can prevent recondensation of fractionated components and easily separate liquid from the biomass. In this study, the pretreatment was performed for decreasing additional process by using ethanol without catalyst because this process has a lot of operation expense at bio-alcohol production process. Flow-through pretreatment was performed at $150{\sim}190^{\circ}C$ with 30~99.5 wt% ethanol during 20~60 minutes. Also the phsyco-chemical pretreatment was performed for decreasing reaction time and temperature.

Effects of Dilute Acid Pretreatment on Enzyme Adsorption and Surface Morphology of Liriodendron tulipifera

  • Min, Byeong-Cheol;Koo, Bon-Wook;Gwak, Ki-Seob;Yeo, Hwan-Myeong;Choi, Joon-Weon;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.2
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    • pp.187-195
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    • 2011
  • In this study, dilute acid pretreatment of $Liriodendron$ $tulipifera$ was performed for enzymatic hydrolysis. As the pretreatment temperature was increased, enzymatic hydrolysis and enzyme adsorption yield also increased. The highest enzymatic hydrolysis yield was 57% (g/g) and enzyme adsorption was 44% (g/g). Enzymatic hydrolysis yield was determined with weight loss of pretreated biomass by enzyme, and enzyme adsorption was a percentage of enzyme weight attaching on pretreated biomass compared with input enzyme weight. When $L.$ $tulipifera$ was pretreated with 1% sulfuric acid at $160^{\circ}C$ for 5 min., hemicellulose was significantly removed in pretreatment, but the lignin contents were constant. Other changes in surface morphology were detected on biomass pretreated at $160^{\circ}C$ by a field emission scanning electron microscope (FESEM). A large number of spherical shapes known as lignin droplets were observed over the entire biomass surface after pretreatment. Hemicellulose removal and morphological changes improved enzyme accessibility to cellulose by increasing cellulose exposure to enzyme. It is thus evidence that enzyme adsorption is a significant factor to understand pretreatment effectiveness.

Analysis of Conveyance Environment and Pre-treatment on Quality Maintenance of Cut Dendranthema grandiflorum 'Baekma' during Ship Export to Japan (절화 국화 '백마'의 일본 선박 수출 시 수송환경 분석 및 전처리제에 따른 선도유지)

  • Lee, Ja-Hee;Lee, Ae-Kyung
    • Horticultural Science & Technology
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    • v.33 no.5
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    • pp.697-704
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    • 2015
  • This study was carried out to investigate conveyance environment during shipping export to Japan and the optimum pre-treatment of cut Dendranthema grandiflorum 'Baekma'. Shipping from Korea to Japan, which usually takes three to five days, requires keeping the flower at the ideal temperature. When inspection took place in Japan, the ideal temperature was lost and deterioration began. Once the ideal temperature is lost, deterioration takes place. The results of this work showed that vase life was extended by treatment Chrysal RVB and NaOCl compared to the control (distilled water), and Chrysal RVB was used to maintain the flower from bud to full bloom. Bacterial growth was not observed after pretreatment with NaOCl or $ClO_2$. However, $ClO_2$ pre-treatment was observed to affect the early growth period of the bacteria. The chlorophyll content was the highest after Chrysal RVB or NaOCl pretreatment compared to the other treatments. Therefore, these results support pretreatment with NaOCl and Chrysal RVB of Dendranthema grandiflorum 'Baekma' for export to Japan.

Optimization of Microwave-Assisted Pretreatment Conditions for Enzyme-free Hydrolysis of Lipid Extracted Microalgae (탈지미세조류의 무효소 당화를 위한 마이크로파 전처리 조건 최적화)

  • Jung, Hyun jin;Min, Bora;Kim, Seung Ki;Jo, Jae min;Kim, Jin Woo
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.229-239
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    • 2018
  • The purpose of this study was to effectively produce the biosugar from cell wall of lipid extracted microalgae (LEA) by using microwave-assisted pretreatment without enzymatic hydrolysis process. Response surface methodology (RSM) was applied to optimization of microwave-assisted pretreatment conditions for the production of biosugar based on enzyme-free process from LEA. Microwave power (198~702 W), extraction time (39~241 sec), and sulfuric acid (0~1.0 mol) were used as independent variables for central composite design (CCD) in order to predict optimum pretreatment conditions. It was noted that the pretreatment variables that affect the production of glucose (C6) and xylose (C5) significantly have been identified as the microwave power and extraction time. Additionally, the increase in microwave power and time had led to an increase in biosugar production. The superimposed contour plot for maximizing dependent variables showed the maximum C6 (hexose) and C5 (pentose) yields of 92.7 and 74.5% were estimated by the predicted model under pretreatment condition of 700 w, 185.7 sec, and 0.48 mol, and the yields of C6 and C5 were confirmed as 94.2 and 71.8% by experimental validation, respectively. This study showed that microwave-assisted pretreatment under low temperature below $100^{\circ}C$ with short pretreatment time was verified to be an effective enzyme free pretreatment process for the production of biosugar from LEA compared to conventional pretreatment methods.

Catalytic Combustion of Acetaldehyde by Metal Phthalocyanines (금속 프탈로시아닌을 이용한 아세트알데히드의 촉매연소)

  • 서성규
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.4
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    • pp.409-414
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    • 2000
  • Catalytic combustion of acetaldehyde has been investigated as a representative of unpleasant odor by its reaction with metal-phthalocyanines(PC). The experiment was conducted at the reaction temperature of 200~41$0^{\circ}C$ and the concentratio of acetaldehyde in air at the range of 0.07~0.94 mole% The pretreated metal-PC has been characterized by UV-VIS and XRD analysis. According to this study catalytic activity of metal -PC was improved by air pretreatment at 45$0^{\circ}C$ for 1hr. Under this pretreatment condition Co-PC and Cu($\alpha$)-PC were destroyed and new metal oxides were formed such as Co3O4 and CuO respectively. However Zn-PC retained its basic structure even afte air pretreatment. The order of catalytic activity on acetaldehyde combustion was summarized as follows : Zn-PC$\alpha$)-PC. It was found that the complete combustin of acetaldehyde with Cu($\alpha$)-PC was accomplished at its concentrations below 0.2mole% (32$0^{\circ}C$) and 0.6 mole%(35$0^{\circ}C$) in air.

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Influence of Growth Environment of Anther - Donor Plant and Chilling treatments to Flower Bud on Haploid Plantlets Production in Anther culture of Nicotiana tabacum L. (연초 약배양시 Anther-donor 식물체의 생육조건 및 약의 저온처리가 반수체 출현빈도에 미치는 영향)

  • 금완수
    • Journal of the Korean Society of Tobacco Science
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    • v.16 no.1
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    • pp.64-68
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    • 1994
  • The present experiments were conducted to investigate some of the factors affecting the number of haploids derived from anther culture of Nicotiana tabacum. Anther - donor plants grown under controlled environment room at 3$0^{\circ}C$ yielded more haploid than room at 18, 25 and 26-22-18$^{\circ}C$ in anther culture. Donor plants starved of fertilizer yielded more haploids as compared to those of the well fed with fertilizer in anther culture. Pretreatment of exercised flower bud at 5$^{\circ}C$ was shown to be more effective in anther culture than pretreatment at 7 and 1$0^{\circ}C$, and the optimum temperature and period of pretreatment were 4 or 6 days at 5$^{\circ}C$.

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Effect of Kerfing and Incising Pretreatments on High-Temperature Drying Characteristics of Cedar and Larch Boxed-Heart Timbers with Less than 150 mm in Cross Section Size (배할 및 인사이징 전처리가 횡단면 크기 150 mm 이하 삼나무와 낙엽송 수심재의 고온건조특성에 미치는 영향)

  • LEE, Chang-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.345-363
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    • 2020
  • This study was conducted to identify the effect of kerfing and incising pretreatments on high-temperature drying characteristics of cedar and larch boxed-heart timbers with a cross section of less than 150 mm. The result showed that the pretreatments have made a significant difference regarding surface check and shrinkage. Although the kerfing was suitable as a pretreatment to reduce the occurrence of surface check, the incising was not suitable as a pretreatment since the knives of timber joined together, causing the conversion to the surface checks. The shrinkage showed a significant result that the final moisture content was reduced in the order of incising, kerfing, and kerfing-incising after the drying process based on the pretreatment condition. Twist was more affected by the grain angle than the anisotropy of the juvenile wood, and there was no effect of pretreatments.

The Effect of Rapid Freeze Pretreatment on Grinding of Organic Ion Exchange Resins (금속동결 전처리에 의한 유기이온 교환수지의 분쇄효과)

  • Yim, Sung-Pal;Kim, Joun-Hyeong;Son, Jong-Sik
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.23-29
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    • 1990
  • The effect of a rapid freeze pretreatment of organic ion exchange resins on their grinding properties was studied. It was found that the structure of ion exchange resins was defected by freezing pressure formed in the process of rapid freezing. The defected resins didn't recover their own structure after thawing and those could be easy to be broken at room temperature by small force. Therefore, organic ion exchange resins could be ground readily at room temperature after rapid-freezing the fully swelled resins using by solid carbon dioxide, or liquid nitrogen. The rapid freeze pretreatment of cation exchange resins was very effective on grinding in particular. However, the effect of the pretreatment of anion exchange resins on grinding was less than that of cation exchange resins. In case of anion exchange resins, the ionic form of affected the grindability remarkably.

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Callus Induction and Embryogenesis Through Pollen Culture in Paeonia albiflora PALL (작약의 화분배양에 의한 캘러스 및 배발생)

  • 김영숙;이병기
    • Korean Journal of Plant Tissue Culture
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    • v.22 no.1
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    • pp.13-17
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    • 1995
  • In order to induce haploid plant through pollen culture, pollens of Paeonia albiflora were cultured on MS liquid medium The development of micospore through pollen culture was examined The effect of low temperature (5$^{\circ}C$, 10 days) pretreatment on callus induction and embryogenesis in pollen culture was not evident Calli derived from pollen gave rise to globular embryos when transferred onto solid medium containing 0.5 mg/, 2,4-L. The effect of low temperature pretreatment and medium. combination to pollen viability was unrecognized. Pollen viability was reduced as the culture proceeded.

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Improvement of Migration Fastness of Perfluorocarbons-free Synthetic Suede by Chitosan Pretreatment (키토산 전처리를 통한 과불화탄소 무함유 합성 스웨이드의 이염성 견뢰도 향상)

  • Lee, Hye Mi;Kim, Ah Rong;Kim, Dae Geun
    • Textile Coloration and Finishing
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    • v.31 no.4
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    • pp.258-267
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    • 2019
  • Synthetic suede without PFCs(perfluorinated compounds) are followed by subsequent high temperature treatment. But migration fastness of synthetic suede may be reduced due to sublimation of disperse dyes that results from the high temperature treatment. Therefore, in this study, chitosan treatment was used to improve the migration fastness before polyurethane dipping process. Polyester fiber was treated with sodium hydroxide aqueous solution before chitosan processing. This samples treated with a chitosan concentration upto 0.5% were dyed and coated with PUD(polyurethane dispersion). The migration fastness was most improved at 0.35% application. This is presumably due to the fact that the chitosan may increase the dye-binding capability through intermolecular hydrogen bonding.