• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.523-530
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• 1999

Acrylic pressure-sensitive adhesive has been made utilizing organic solvents, but nowadays it is made by solvent-free system due to environmental problems. In this study, emulsion polymerization were carried out at $40^{\circ}C$ with methacrylic acid(MAA), n-butyl acrylate(n-BA) and 2-ethylhexyl acrylate(2-EHA) as monomers in the presence of anionic(sodium dodecyl sulfate, SDS) and nonionic(ethylene oxide types) surfactant mixtures. The overall conversion of the polymerization reaction in a mixed surfactant system was found to be higher than that in a single surfactant system. Emulsion stability in mixed or anionic surfactant systems was found to be over 12 week, which was better than that in nonionic surfactant system. Emulsion particle size decreased as surfactant content increased. The Tg and molecular weight of emulsion polymer were inependent of the type, the amount and the mixing ratio of surfactant. Based on the results of stability and peel strength, the optimum nonionic surfactant ratio in total 4 g of surfactant mixture systems is found to be 40~60% by weight where the nonionic surfactant has 50 ethylene oxide groups and 16~18 carbon atoms in hydrophobic alkyl chain.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.5
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• pp.530-536
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• 2021

This paper presents the performance measurement results of a hybrid sheet with both shielding and heat dissipation functions developed by laminating copper mesh sheets and natural graphite sheets, which are used widely as electromagnetic shielding and heat-dissipating materials in electronic devices, without a pressure-sensitive adhesive (PSA). The results were compared by measuring the vertical and horizontal thermal conductivity with two other products to confirm the heat dissipation performance. A radiation emission test confirmed the electromagnetic shielding performance using a 3m electromagnetic anechoic chamber according to the CISPR 11 standard. In the case of vertical thermal conductivity, the proposed hybrid sheet was approximately 8.63 times higher than that of an aluminum sheet with heat dissipation coating and 18.7 times higher than that of a copper sheet laminated with artificial graphite with PSA. The proposed hybrid sheet was approximately 0.64 times that of the sheet, and approximately 1.76 times that of the heat-dissipated aluminum sheet in case of horizontal thermal conductivity. Measurements after applying each sheet in the same heat source revealed the proposed hybrid sheet to have the best heat dissipation performance. The radiation emission test showed that significantly radiation noise had been removed.