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A Study on the Formaldehyde Release from Durable Press Finished Rayon Fabrics (DP 가공된 레이온 직물의 포름알데하이드 방출에 관한 연구)

  • Yeo Sook-Young;Kim Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.1 s.29
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    • pp.59-66
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    • 1989
  • This paper is concerned with formaldehyde release from durable press finished rayon fabrics. $100\%$ rayon fabrics were treated with 3 kinds of commercial N-methylol crosslinking agents using a pad-dry cure technique. Aqueous extractions of fabric samples were carried out at $40^{\circ}C$ under pH's of 4, 7, 10. Formaldehyde release was evaluated for the types of resins, catalyst concentrations and extraction conditions. Results indicated that the higher concentration of catalyst leads to the more fixation of resin on the fabric. Total formaldehyde released to the extract was decreased as the catalyst concentration increased. For the resin types, the amount of formaldehyde released was in the order of DMU>MDMDHEU>DMDHEU. Free formaldehyde content in the extract was in the order of pH10>pH4>pH7. This result proved that resins are least resistant to alkaline hydrolysis and the N-C bond cleavage under alkaline condition. Under acidic condition, however, N-methylol formaldehyde was accumulated before the release of free formaldehyde. This suggested the C·0 bond cleavalge to form carbonium - immonim intermediate.

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Delamination analysis of inhomogeneous viscoelastic beam of rectangular section subjected to torsion

  • Victor I. Rizov
    • Coupled systems mechanics
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    • v.12 no.1
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    • pp.69-81
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    • 2023
  • This paper considers a delamination analysis of a statically undetermined inhomogeneous beam structure of rectangular section with viscoelastic behavior under torsion. The beam is built in at its two ends. The beam has two longitudinal inhomogeneous layers with a delamination crack between them. A notch is made in the upper crack arm. The external torsion moment applied on the beam is a function of time. Under these conditions, the beam has one degree of indeterminacy. In order to derive the strain energy release rate, first, the static indeterminacy is resolved. Then the strain energy release rate is obtained by analyzing the balance of the energy with considering the viscoelastic behavior. The strain energy release rate is found also by analyzing the compliance of the beam for checkup. Solution of the strain energy release rate in a beam without a notch in the upper crack arm is derived too. In this case, the beam has two degrees of static indeterminacy (the torsion moment in the upper crack arm is treated as an additional internal redundant unknown). A parametric investigation of the strain energy release rate is carried-out.

Microplastic release from damaged commercial teabags

  • Kim, Sion;Jo, Eun Ha;Choi, Soohoon
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.21-28
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    • 2022
  • The use of plastics in our everyday lives have been drastically increased during the last few decades. However with the usage of commercial plastic products there is a possibility of microplastic consumption, due to the fragmentation of the products. Additionally, the potential for microplastic ingestion may also be increased by using damaged products. Hence, the current study was conducted to understand the potential release of micro/nano plastics and organic matter from damaged teabags. To check the leakage tendency, the amount of damage to the tea bags from 1-10 cm were tested along with temperatures of 25-70℃, and exposure times from 5 min to 1 hr was tested. Release of fibrous micro/nanoplastics, and organic leachate from the damaged teabags were observed to understand the outflow conditions. Results showed that with the increased degree of damage, temperature, and exposure time increased the release of fiberous matter, where the increase of temperature, and exposure time increased organic leachate. Additional analysis confirmed the leachate of nylon polymers into the heated water.

Analysis of the strain energy release rate for time-dependent delamination in multilayered beams with creep

  • Rizov, Victor I.
    • Advances in materials Research
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    • v.11 no.1
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    • pp.41-57
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    • 2022
  • This paper is focused on delamination analysis of a multilayered inhomogeneous viscoelastic beam subjected to linear creep under constant applied stress. The viscoelastic model that is used to treat the creep consists of consecutively connected units. Each unit consists of one spring and two dashpots. The number of units in the model is arbitrary. The modulus of elasticity of the spring in each unit changes with time. Besides, the modulii of elasticity and the coefficients of viscosity change continuously along the thickness, width and length in each layer since the material is continuously inhomogeneous in each layer of the beam. A time-dependent solution to the strain energy release rate for the delamination is derived. A time-dependent solution to the J-integral is derived too. A parametric analysis of the strain energy release rate is carried-out by applying the solution derived. The influence of various factors such as creep, material inhomogeneity, the change of the modulii of elasticity with time and the number of units in the viscoelastic model on the strain energy release rate are clarified.

Precise ultrasonic coating and controlled release of sirolimus with biodegradable polymers for drug-eluting stent

  • Joung, Yoon Ki;Jang, Bu Nam;Kang, Jong Hee;Han, Dong Keun
    • Biomaterials and Biomechanics in Bioengineering
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    • v.1 no.1
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    • pp.13-25
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    • 2014
  • In the current study, a drug-eluting stent coated with biodegradable polymers and sirolimus was developed by using an ultrasonic nanocoater and characterized in aspects of surface smoothness and coating thickness. In addition, in vitro release profiles of sirolimus by changing top coating layer with different biodegradable polymers were investigated. Smooth surfaces with variable thickness could be fabricated by optimizing polymer concentration, flow rate, nozzle-tip distance, gas pressure, various solvents and ultrasonic power. Smooth surface could be generated by using volatile solvents (acetone, chloroform, and methylene chloride) or post-treating with solvent vapor. Coating thickness could be controlled by varying injection volume or polymer concentration, and higher concentration could reduce the coating time while obtaining the same thickness. The thickness measurement was the most effectively performed by a conventional cutting method among three different methods that were investigated in this study. Release profiles of sirolimus were effectively controlled by changing polymers for top layer. PLGA made the release rate 3 times faster than PDLLA and PLLA and all top layers prevented burst release at the initial phase of profiles. Our results will provide useful and informative knowledge for developing drug-eluting stents, especially coated with biodegradable polymers.

Study of stability and evolution indexes of gobs under unloading effect in the deep mines

  • Fu, Jianxin;Song, Wei-Dong;Tan, Yu-Ye
    • Geomechanics and Engineering
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    • v.14 no.5
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    • pp.439-451
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    • 2018
  • The stress path characteristics of surrounding rock in the formation of gob were analysed and the unloading was solved. Taking Chengchao Iron Mine as the engineering background, the model for analysing the instability of deep gob was established based on the mechanism of stress relief in deep mining. The energy evolution law was investigated by introducing the local energy release rate index (LERR), and the energy criterion of instability of surrounding rock was established based on the cusp catastrophe theory. The results showed that the evolution equation of the local energy release energy of the surrounding rock was quartic function with one unknown and the release rate increased gradually during the mining. The calculation results showed that the gob was stable. The LERR per unit volume of the bottom structure was relatively smaller, which mean the stability was better. The LERR distribution showed that there was main energy release in the horizontal direction and energy concentration in the vertical direction which meet the characteristics of deep mining. In summary, this model could effectively calculate the stability of surrounding rock in the formation of gob. The LERR could reflect the dynamic process of energy release, transfer and dissipation which provided an important reference for the study of the stability of deep mined out area.

Multilayered frame structure subjected to non-linear creep: A delamination analysis

  • Rizov, Victor I.;Altenbach, Holm
    • Coupled systems mechanics
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    • v.11 no.3
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    • pp.217-231
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    • 2022
  • The present paper is concerned with a delamination analysis of a multilayered frame structure that exhibits non-linear creep behavior. A solution to the strain energy release rate is obtained by considering the time-dependent complementary strain energy in the frame. The mechanical behavior of the frame is treated by using a non-linear stress-strain-time relationship. The time-dependent solution to the strain energy release rate obtained in the present paper holds for a multilayered frame made of arbitrary number of adhesively bonded layers of different thicknesses and material properties. Besides, the dealamination is located arbitrary along the thickness. The solution to the strain energy release rate is verifiedby applying the J-integral approach. A parametric study of the strain energy release rate is carried-out. Two three-layered frame configurations are analyzed in order to evaluate the influence of the delamination crack location along the thickness on the strain energy release rate. The strain energy release is analyzed also for the case when a notch is cut-out in the inner delamination crack arm. The results obtained are compared with these for a frame without a notch.