• Title/Summary/Keyword: potassium carbonate

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Manufacturing of Korean Traditional Handmade Paper with Reduced Fiber Damage(III)-Potassuim Carbonate Cooking of Paper Mulberry (Broussonetia Kazinoki Sieb) (섬유의 손상이 적은 한지 제조(제 2보) -닥나무 백피의 K2CO3 증자 특성)

  • 문성필;임금태
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.83-89
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    • 1999
  • Bast fibers of paper mulberry ( Broussonetia Kazinoki Sieb) were cooked with a weak alkaline salt, potassium carbonate which has been known as a major inorganic component of the traditional lye, and its cooking characteristics were investigated . The bast fiber was easily cooked by potassium carbonate. The pulp yield was rapidly decreased up to 20-30 mol of potassium carbonate, but the Kappa number was slowly decreased with increasing of potassium carbonate. The potassium carbonate pulps were easily defibered at low cooking chemical charge of 25mm on and high pulp yield of about 80%. These results were confirmed that pectin was easily removed during the potassium carbonate cooking. In contrast, when sodium carbonate was used as a cooling agent, the bast fiber was only partially defibered. Thus, sodium carbonate was a less effective cooling chemical of the bast fiber. The results of this experiment indicated that potassium carbonate could not only be used as a good cooling agent of bast fiber, but also as an alternative agent of sodium hydroxide.

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Manufacturing of Korean Traditional Handmade Paper with Reduced Fiber Damage(III) (섬유의 손상이 적은 한지 제조(제 3보)-K2CO3 증자하여 제조한 한지의 열 열화특성-)

  • 이명기;문성필
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.90-95
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    • 1999
  • The durability of handmade paper prepared by potassium carbonate cooking of paper multiberry (Broussonetia Kazinoki Sieb).was investigated. The potassium carbonate paper before and after heat aging had better strength properties, breaking length and folding endurance than those of the soda paper, except of lower brightness .After 30 days of heat aging , these strength properties were still maintained . however, there was almost no difference in the infrared spectra and the crystallinities calculated by X-ray diffraction curves between the potassium carbonate paper and the soda a paper. The durability of the potassium carbonate paper was though to be due to decrease in the pulp damage caused by weak alkaline cooking condition. The results indicated that the paper prepared by the potassium carbonate cooling method could have better permanence than that prepared by the conventional soda cooking method.

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Effects of pH Control Agent and Co-Precipitate Washing Agent on Nickel Ferrite Preparation by Co-Precipitation Method (공침법에 의한 Nickel Ferrite의 분말제조에서 pH-조절제 및 공침물-세척제의 영향)

  • Jeong, Hong-Ho;Seong, Gi-Ung
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.445-449
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    • 2000
  • Nickel ferrite $(Ni_{0.75}Fe_{2.25}O_4$ was synthesized by co-precipitation method in order to investigate its behavior under conditions of the reactor coolant system in pressurized light water nuclear power plants. Ammonia or potassium carbonate was used as a solution pH control agent, and aqueous ammonia or potassium carbonate solution or secondary distilled water was used as a co-precipitate washing agent. The effects of the pH control agent and the co-precipitate washing agent on the production yield on the basis of the Ni/Fe molar ratio and the particle characteristics of final products were investigated by XRD, SEM, EDX and XPS. The production yield was almost congruent with that of the initial aqueous mixture in case of using potassium carbonate as a pH control agent, while in case of using ammonia, it was quite changed. The difference seemed to be due to the effects of $Ni^{2+}{\leftarrow}NH_3$complexation in the aqueous solution and of the pH of co-precipitate washing agent.

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Effects of Alkaline reagents on Textural and Sensory Properties of Ramyon (알카리제의 조성에 따른 라면의 조직감과 관능적 특성)

  • Jeong, Jae-Hong
    • Journal of the Korean Society of Food Culture
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    • v.13 no.4
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    • pp.261-266
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    • 1998
  • In an attempt to evaluate the effects of alkali agents on properties of Ramyon, cooking quality, textural and sensory properties were examined. The shear extrusion force of Ramyon made from sample A(potassium carbonate 64%, sodium carbonate 14%, sodium pyrophosphate 2% and sodium metaphosphate 20%), sample B(potassium carbonate 31%, sodium carbonate 39% , sodium pyrophosphate 1%, sodium metaphosphate 15%, sodium polyphosphate 8%, sodium phosphate monobasic 4% and sodium phosphate dibasic 2%), sample C(potassium carbonate 60%, sodium carbonate 33% and sodium pyrophosphate 7%), and sample D(potassium carbonate 44%, sodium carbonate 27%, sodium metaphosphate 27% and sodium polyphosphate 2%) were 12.80(kgf), 10.35(kgf), 9.05(kgf) and 8.45(kgf), respectively, but that of control I was 5.24(kgf). The hardness of Ramyon manufactured with sample A, B, C and D were 18.57(kgf), 16.48(kgf), 14.26(kgf) and 12.34(kgf), respectively, but that of control I was 11.23(kgf). At cooking quality examination of Ramyon made from several alkali agents, weight of cooked Ramyon was increased but volume was appeared in vice versa. Extraction amounts of Ramyon manufactured with several alkali agents during cooking were from 35% to 38%, but that of control I was 70%. These changes will provided many advantages in the preparation of Ramyon. The $I_2$ reaction value(${\alpha}-degree$ of noodle) of Ramyon manufactured with several alkali agents and control were shown to almost same values, from 2.10 to 2.20. Sensory properties of cooked Ramyon which was manufactured with several alkali agents showed quite acceptable.

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Carbon Dioxide Capture and Carbonate Synthesis via Carbonation of KOH-Dissolved Alcohol Solution (KOH-알코올 용액의 탄산화를 통한 이산화탄소 포집 및 탄산염 합성)

  • Kim, Eung-Jun;Han, Sang-Jun;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.11
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    • pp.597-606
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    • 2015
  • This work investigates the carbonation of KOH-dissolved methanol and ethanol solution systems carried out for $CO_2$ fixation. Potassium methyl carbonate (PMC) and potassium ethyl carbonate (PEC) were synthesized during the reaction in each solution as the solid powder, and they were characterized in detail. The amount of $CO_2$ chemically absorbed to produce the PMC and PEC precipitates were calculated to be 97.90% and 99.58% of their theoretical values, respectively. In addition, a substantial amount of $CO_2$ was physically absorbed in the solution during the carbonation. PMC precipitates were consisted of the pure PMC and $KHCO_3$ with the weight ratio of 5:5, respectively. PEC precipitates were also mixture of the pure PEC and $KHCO_3$ with the weight ratio of 8:2, respectively. When these two precipitates were dissolved in excess water, methanol and ethanol were regenerated remaining solid $KHCO_3$ in the solutions. Therefore, the process has the potential to be one of the efficient options of CCS and CCU technologies.

Effect of Carbon Dioxide in the Air on Zinc-air Cell (대기중의 이산화탄소가 공기-아연전지에 미치는 영향)

  • Kim, Nam-In;Park, Ki-Hong;Choi, Yong-Kook;Lee, Woo-Tae
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.177-182
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    • 1999
  • The electrolyte was brought into contact with air and potassium carbonate concentration was measured with various contact time in order to check the effect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration increased due to carbon dioxide absorption with increasing contact time with air, but the cell capacity linearly decreased with increasing potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere.

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Effect of Exogenous Potassium on the Reduction in Tar, Nicotine and Carbon Monoxide Deliveries in the Mainstream smoke of Cigarettes (가리염 첨가가 궐련 주류연중 타르, 니코틴, 일산화탄소 이행량에 미치는 영향)

  • 안기영;김천석
    • Journal of the Korean Society of Tobacco Science
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    • v.17 no.1
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    • pp.62-67
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    • 1995
  • Deliveries of tar, nicotine and carbon monoxide in mainstream smoke decreased with increment of exogenous potassium content of tobacco. Potassium malate was more effective than potassium nitrate, potassium carbonate, potassium citrate and potassium oxalate for the reduction of carbon monoxide, but potassium nitrate was more effective than potassium palate, potassium carbonat, potassium citrate and potassium oxalate for the reduction of carbon in the case of nicotine. Puff count and burning rate were slightly changed with added potassium salts.

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Chlorination of Alcohols Using Potassium Carbonate and Silicon Tetrachloride (탄산칼륨 존재하에서 사염화규소를 이용한 알코올의 염소화반응)

  • Ha, Dong Soo;Kim, Hyeung Ae
    • Journal of the Korean Chemical Society
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    • v.41 no.10
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    • pp.535-540
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    • 1997
  • Potassium carbonate reacts with silicon tetrachloride to form trichlorosilyloxy carbonylchloride which reacts subsequently with another molecule of silicon tetrachloride leading to phosgene eventually in chlorinated solvents. This in situ generated trichlorosilyloxy carbonylchloride or phosgene were found to be very effective for the chlorination of a wide variety of alcohols to the corresponding chlorides. Primary, secondary and benzylic alcohols were converted into corresponding chlorides when treated with silicon tetrachloride in the presence of potassium carbonate at room temperature.

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Manufacturing of Koren Traditional Handmade Paper with Reduced Fiber Damage (I) -Inorganic Composition of Traditional Lye- (섬유의 손상이 적은 한지 제조 (제1보) -인피섬유 증자시 사용된 전통 잿물의 화학적 조성-)

  • 문성필
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.89-94
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    • 1999
  • The inorganic compositions of traditional lye, and lyes prepared from the stalks of five different agricultural products: beans, wheat, barley, buckwheat and red peppers, were analyzed. Traditional lye was composed mainly of a weak alkaline salt, potassium carbonate as the major component and neutral salts, potassium chloride and potassium sulfate as minor components. The ash and lye contents of buckwheat have significantly higher then those of the rest agricultgural products. Bean and red pepper stalks lyes were composed mainly of potassium carbonate, similar to the composition of traditional lye, but also contained potassium chloride or sulfate. In contrast, postassium chloride was the major component of wheat and barley stalk lye.

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Effects of Free Alkali and Moisture on Sucrose Polyesters Synthesis (유리 알카리 및 수분이 sucrose polyesters 합성에 미치는 영향)

  • Chung, Ha-Yull;Kim, Suk-Ju;Yoon, Sung-Woo;Yoon, Hee-Nam;Kong, Un-Young
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.247-250
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    • 1992
  • Effects of free alkali and moisture on sucrose polyesters (SPE)-possible non calorie fat substitute-synthesis were investigated using a model system composed of sodium oleate, sucrose, potassium carbonate and methyl oleate. Trace amounts of free alkali in sodium oleate were found to interefere with SPE synthesis. When free alkali content in sodium oleate was varied gradually from 0% to 5%(w/w), the yield of SPE production was reduced from 92% to 45.5%. The moisture absorbed in sodium oleate, sucrose and potassium carbonate during storage also interefered with SPE synthesis. The yield (92%) of SPE production with dried ($105^{\circ}C$.6 hrs) reactants and catalysts was higher than that (89%) of SPE production with non-dried. Soybean oil fatty acid sodium soaps (FASS) not containing free alkali could be manufactured with slightly less than molar ratio of sodium hydroxide to soybean oil fatty acid methyl esters (FAME). Practically, 91.7% yield of soybean oil SPE production was outcomed by minimizing free alkali and moisture which were remaining in sucrose, potassium carbonate, soybean oil FASS and soybean oil FAME.

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