• Journal of the Korean Institute of Gas
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• v.20 no.1
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• pp.1-6
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• 2016

In order to reduce the anthropogenic emission of greenhouse gases, CCS technology has emerged as the most promising and practical solution. Among CCS technology, post-combustion $CO_2$ capture is known as the most mature and effective process to remove $CO_2$ from power plant, but its energy consumption for chemical solvent regeneration still remains as an obstacle for commercialization. In this study, a process alternative integrating $CO_2$ capture with compression process is proposed which not only reduces the amount of thermal energy required for solvent regeneration but also produces $CO_2$ at an elevated pressure.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.153.2-153.2
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• 2010

화력발전 분야에서 $CO_2$ 분리는 크게 연소전 탈탄소화(pre-combustion capture)와 연소후 포획(post-combustion capture)으로 나누어진다, 연소후 포획은 연료를 연소한 후 발생하는 $CO_2$와 $N_2$가스에서 $CO_2$를 분리하는 기술로 흡수나, 흡착, 막분리 등을 주로 이용한다, 연소전 탈탄소화는 연소 전에 $CO_2$가 발생되지 않도록 하는 기술로써, 부분 산화나 개질 및 수성가스 변위반응 등이 포함되며 생성된 $H_2$와 $CO_2$를 분리하여 수소를 생산하는 기술($CO_2/H_2$분리가 핵심)이다. 우리나라는 대부분 연소후 포획 위주로 많은 연구가 진행되어 왔다, 하지만 최근 고유가 시장이 형성되면서 석탄화력 발전 및 복합가스발전(IGCC)에 필요한 연소전 탈탄소화($H_2/CO_2$ 가스로부터 $CO_2$ 회수) 연구에 산업적 관심이 급상승되고 있다. 특히, 연소전 탈탄소화 과정에서는 높은 자체압력(약 2.5 - 5.0MPa)과 비교적 높은 농도의 $CO_2$(약 40%의)가 발생되기 때문에, 연소전 탈탄소화는 가스하이드레이트 형성/분해 원리가 가장 잘 적용될 수 있는 기술이라 할 수 있다. 본 연구에서는 가스 하이드레이트 형성원리를 이용하여 정온 정압 조건에서 $CO_2/H_2$ 하이드레이트를 제조하였으며 특히, 하이드레이트 형성 촉진제인 THF(Tetrahydrofuran)와 TBAB(Tetra-n-butyl ammonium bromide)를 첨가하여 각각 0.5, 1, 3mol% 농도에 따른 상평형 및 속도론 실험을 수행 하였다. 또한 라만 분석을 통하여 $CO_2$ 회수 분리에 대한 연구도 병행하였다. 이러한 연구는 연소전 탈탄소화 기술에서의 $CO_2$ 회수 분리에 대한 핵심 연구임과 동시에 탄소배출권 규제에 실질적인 기여를 할 수 있을 것으로 사료된다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.522-525
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• 2009

DC-shift phenomenon can be observed in Hybrid rocket combustion. This phenomenon makes performance drop which is structure problem or reduce thrust. Understanding of DC-shift phenomenon, the condition of the hybrid rocket combustion stability can be found. In this paper, the condition of Negative DC-shift was found and made by changing oxidizer flow with pre-post chamber. The Negative C-shift phenomenon and characteristic were defined from the experimental study.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.63-68
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• 2006

Effects of oxidizer inlet velocity on NO emission characteristics of 0.2MW oxy-fuel combustor have been experimentally investigated. The NO formation process in the oxy-fuel combustion is extremely sensitive even for the small fraction of nitrogen in oxidizer. By increasing the oxidizer velocity, flame length is reduced due to the enhanced turbulent mixing. The increased oxidizer velocity also results in the decreased flame temperature through the elevated entrainment rate of the recirculated product and the corresponding NO emission is drastically decreased. Experimental results clearly indicate that the entrained product gases play a crucial role to decrease the temperature at the flame zone and the post flame zone where the thermal NO is mainly formed.

• Journal of the Korean Society of Combustion
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• v.13 no.1
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• pp.1-9
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• 2008

Emission characteristics of NOx and CO with heat loss under high efficiency combustion conditions of $CH_4$/Air prmixed flame were examined numerically using detailed-kinetic chemistry. The one-dimensional combustor length was fixed 5cm, and the equivalence ratio was varied from 0.75 to 0.95. To consider the effects of heat loss on NOx and CO formation, the radiative heat loss rate and combined heat loss rate of conductive and convective heat transfer are included. The following conclusions were drawn. In order to reduce the NOx and CO emission level simultaneously, the temperature of product gases must be reduced under 1,800K as soon as possible but kept over 1,300K during the residence time which is needed to converge CO to $CO_2$.

• Journal of Mechanical Science and Technology
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• v.17 no.1
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• pp.139-145
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• 2003

Diode laser sensor is conducted to measure the gas temperature in the liquid-gas 2-phase counter flow flame. C$\_$10/H/ sub 22/ and city gas were used as liquid fuel and gas fuel, respectively. Two vibrational overtones of H$_2$O were selected and measurements were carried out in the spray flame region stabilized the above gaseous premixed flame. The path-averaged temperature measurement using diode laser absorption method succeeded in the liquid fuel combustion environment regardless of droplets of wide range diameter. The path-averaged temperature measured in the post flame of liquid-gas 2-phase counter flow flame showed qualitative reliable results. The successful demonstration of time series temperature measurement in the liquid-gas 2-phase counter flow flame gave us motivation of trying to establish the effective control system in practical combustion system. These results demonstrated the ability of real-time feedback from combustor inside using the non-intrusive measurement as well as the possibility of application to practical combustion system. Failure case due to influence of spray flame was also discussed.

• Journal of the Korean Society of Combustion
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• v.21 no.2
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• pp.22-28
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• 2016

High efficient and environment friendly combustion technologies are used to be operated an extreme condition, which results in unintended flame instability such as extinction and oscillation. The use of electromagnetic energy is one of methods to enhance the combustion stability and a microwave as electromagnetic wave is receiving increased attention recently because of its high performance and low-cost system. In this study, an experiment was performed with jet diffusion flames induced by microwave. Micro jet was introduced to simulate the high velocity of industrial combustor. The results show that micro jet flames had three different modes with increasing oxidizer velocity; attached yellow flame, lifted flame, and lifted partially premixed flame. As a microwave was induced to flames, the overall flame stability and blowout limit were extended with the higher microwave power. Especially the interaction between a flame and a microwave was shown clearly in the partially premixed flame, in which the lift-off height decreased and NOx emission measured in post flame region increased with increasing microwave power. It might be attributed to increase of reactivity due to the abundance of radical pool and the enhanced absorption to thermal energy.

• 한국연소학회:학술대회논문집
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• 2002.06a
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• pp.157-162
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• 2002

The characteristics of DeNOx conversion process by plasma/post-heating system with the simulated gas containing ethene is investigated experimentally. Without plasma treatment, $NO-NO_2$ conversion doesn't occur by $400^{\circ}C$ in a mixture of $N_2/O_2$ with a trace gas of ethene. But $NO-NO_2$ conversion occurs as temperature increases above $400^{\circ}C$. The NO can, however, be converted to $NO_2$ at lower temperatures by treating the gas mixture with non-thermal plasma. The $NO-NO_2$ conversion enhances further by passing the plasma treated gas through the post-heating furnace. Results show that 20%${\sim}50%$ more conversion of NO to $NO_2$ is observed when the temperatures of the post-heating furnace are maintained at $300^{\circ}C$ or $400^{\circ}C$. The additional $NO-NO_2$ conversion by post-heating is due to the reaction of ethene with the byproducts or radicals generated from the plasma reaction.

• Journal of the Korean Society of Combustion
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• v.13 no.4
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• pp.1-7
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• 2008

Strict pollutant regulations of NOx emission and increasing awareness of the environmental damage stimulated interest in research to obtain useful information regarding CO and NOx reductions at the same time. In this study, $CH_4$/air premixed flame was examined numerically to reduce CO and NOx emission level simultaneously in the post-flame region by the heat loss models in which radiative and combined conductive and convective heat losses were included. To reduce the NOx emission, first heat exchanger location was decided near the flame. After first heat exchanger was decided for the optimal NOx emission(about 30 ppm), in order to decide the optimal CO emission(about 30ppm), seocond heat exchanger location was tested and decided for several cases. Finally, the optimal location of heat exchanger for minimal CO and NOx emission simultaneously were determined and suggested.

• Resources Recycling
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• v.5 no.4
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• pp.17-24
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• 1996

The computer simulation model was established to verify the applicability of smelting reduction concept to treatment of industrial wastes which becomes issue on the enviromental and recycling view point. Computer simulation model provides as following results. The increase of post combustion ratio(PCR) and heat transfer efficiency of PC energy(HTE) is effective ways to save energy. But, in order to increase PCR, recovery efficiency of post combustion energy(HTE) have to be higher than 85% HTE considering refractory life and saving energy together. Coke is most useful fuel source because it shows lowest dependence of PCR and low hydrogen content. The quality of hot metal of current process would be expected to the similar level with that of blast furnace. The utilization of scrap and Al dross can be also possible to maximize the advantages of current process which is high temperature and chemical dilution with hot metal and slag. In case of scrap, energy consumption was slightly increases because of heating up energy of scrap. Consquently, current process concept provides the possibility of intergrating recycles of industrial wastes materials such as EAF slag, coke oven dust, life terminated acidic refractory, aluminium dross and scrap by smelting reduction process.