• 제목/요약/키워드: positively charged

검색결과 208건 처리시간 0.026초

Swelling and Drug Release Characteristics of Poly (ethylene oxide)-Poly (methacrylic acid) Interpenetrating Networks (폴리에틸렌 옥사이드-폴리메타크릴산 IPN 공중합체의 팽윤 및 약물 방출특성)

  • Lee, Seung-Jin
    • Journal of Pharmaceutical Investigation
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    • 제21권3호
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    • pp.149-153
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    • 1991
  • Polyethylene oxide (PEO)-polymethacrylic acid (PMAA) interpenetrating polymer networks (IPN) were synthesized via radical polymerization of PMAA and simultaneous crosslinking of PEO using triisocyanate. The equilibrium swelling of PEO-PMAA IPN was determined at different pHs. The swelling of PEO-PMAA IPN, ranged from 20% to 90%, was more sensitive than that of homo polymer PMAA gel This is probably due to protonation and deprotonation of the PMAA network and interpolymer complex formation between PEO and PMAA. Several model drugs were loaded into the IPN matrices and the release mechanisms were investigated. The release of nonionizable drugs such as ftorafur and prednisolone was controlled by swelling of the matrices. However, he release of propranolol, positively charged drug, was more affected by the ionic interaction between the drug and PMAA newtork, and the interpolymer complexation.

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Stability of Coated Green Phosphors for Enhancing Picture Quality of PDP

  • Han, B.Y.;Kim, J.H.;Yoo, J.S.;Kim, Y.K.;Hur, Y.K.;Choi, C.K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.942-945
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    • 2006
  • The picture quality of a plasma display panel is very sensitive to the phosphor characteristics such as luminescence, decay time, surface properties, and even longevity of phosphor material in itself. In our previous work, the discharging characteristics in green cell of PDP were demonstrated to be enhanced by coating $Zn_2SiO_4:Mn^{2+}$ phosphors with positively charged metal oxide such as MgO. Here, $Zn_2SiO_4:Mn^{2+}$ phosphors were coated by various metal oxides for examining the coating effect on the picture quality. Specially, longevity while fabricating the panel was investigated for panel application in this work. Also the effects of ion and electron bombardment on the phosphor surface will be discussed in this work.

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Charge Distribution in a capacitor observed by PEA Method (PEA법에 의한 캐패시터내 전하분포 측정)

  • Endrowednes, Kuantama;Han, Deok-Woo;Kwak, Dong-Joo;Sung, Youl-Moon
    • Proceedings of the KIEE Conference
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.1156-1157
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    • 2008
  • The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about 205 $C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}$ = 2.5 V, while the positively charged density became the maximum, about 61.1 $C/m^3$ at the region where it was located around the cathode layer. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

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Purification and Characterization of Metalloproteases from Pleurotus sajor-caju

  • SHIN, HYUN-HEE;HYE-SEON CHOI
    • Journal of Microbiology and Biotechnology
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    • 제9권5호
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    • pp.675-678
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    • 1999
  • Fibrinolytic protease activity was detected in the fruit body of Pleurotus sajor-caju using a fibrin plate method. Two fibrinolytic activities (FPI and Ⅱ) were found at the regions of 14.5 and 86.0 kDa by using gel-filtration column chromatography. FPⅡ was identified as an alkaline protease, whereas FPⅠ was a neutral protease. Both were inhibited by phenanthrolin and EDTA, suggesting that they are metalloprotease. Inactivated enzyme activities were restored by adding Co/sup 2+/ or Zn/sup 2+/. Iodoacetate inhibited FPⅠ, but not FPⅡ. Both enzymes cleaved B/sub β/ and γ chains of the human fibrinogen. FPⅡ showed a preference to hydrophobic and bulky residues of nitroanilidine compounds as substrates, whereas FPⅠ preferred positively charged residues.

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Pulsed Electron Paramagnetic Resonance Application on the Photoinduced Charge Separation of Alkylphenothiazine Derivatives in Molecular Assemblies

  • Kang, Young-Soo;Park, Chan-Young
    • Journal of the Korean Magnetic Resonance Society
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    • 제4권2호
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    • pp.82-90
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    • 2000
  • Photoinduced charge separation of alkylphenothiazines in molecular assemblies such as positively, negatively and neutrally charged micelle interface results in the paramagnetic phenothiazine cation radical. This was studied as a model system for the light energy conversion into chemical energy. The photoproduced phenothaizne cation radical was identified and its amount was quantized with electron spin resonance (ESR). The microenvironment of photoproduced cation radical was studied with pulsed-ESR. Such a charge separation is enhanced by the optimization of various structural factors of the molecular assemblies. The structural factors of molecular assemblies have focused on the interface charge, interface structure with different headgroups and interfacial perturbation by disolving interface active organic additives.

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The 1320-nm Excited FT-Raman Spectra of Lightly Iodine-Doped trans-Polyacetylene

  • Kim, Jin-Yeol;Yukio Furukawa;Akira Sakamoto;Mitsuo Tasumi
    • Macromolecular Research
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    • 제10권5호
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    • pp.286-290
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    • 2002
  • The FT-Raman spectra of trans-polyacetylene films doped lightly with iodine were obtained with the 1320-nm laser line. The observed Raman bands are attributed to positively charged domains created by acceptor doping. The observed Raman wavenumbers of the V$_2$, (CC stretch), V$_3$, and V$_4$ bands (mixed of CC stretch and CH in-plan bending) of iodine-doped form are slightly higher than those of the corresponding bands of pristine trans-polyacetylene, whereas the contrary is the case for V$_1$, and (C=C stretch) of iodine-doped form. In particular, these upshifts of the V$_2$ and V$_3$ bands are distinguished from the downshifts of these bands in donor doping. The origin of doping induced Raman bands is discussed in terms of solitons and polarons.

OPTICAL PROPERTIES OF INDIUM OXIDE AND INDIUM TIN OXIDE FILMS PREP ARED BY SPUTTERING

  • Fujita, Yasuhiko;Kitakizaki, Kaoru
    • Journal of the Korean institute of surface engineering
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    • 제29권6호
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    • pp.660-665
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    • 1996
  • Thin films of indium oxide and indium tin oxide have been prepared by d.c. magnetron sputtering onto the fused silica substrates kept at 90, 200 and $300^{\circ}C$. In order to elucidate the optical absorption process in low energy region below 3 eV, we have analyzed the absorption coefficients obtained from reflectance and transmittance measurements for these films based on the Lucovsky model. It has been found for the first time that a defect center in the band gap is located at 0.8~1.4 eV below the Fermi level in all films and arises from oxygen vacancies in their films. The optical absorption in low energy region is explained to be dominated by the transition of electrons trapped at the positively charged (+2e) oxygen vacancies with s-like nature to the conduction band formed from the 5s-orbit in indium atoms.

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Characterization of Functional Groups of Protonated Sargassum polycystum Biomass Capable of Binding Protons and Metal Ions

  • Yun, Yeoung-Sang
    • Journal of Microbiology and Biotechnology
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    • 제14권1호
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    • pp.29-34
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    • 2004
  • Biosorption technology is recognized as an economically feasible alternative for the removal and/or recovery of metal ions from industrial wastewater sources. However, the structure of biosorbents is quite complex when compared with synthetic ion-exchange resins, which makes it difficult to quantify the ion-binding sites. Accordingly, this report describes a well-defined method to characterize the pK values and numbers of biomass functional groups from potentiometric titration data. When the proposed method was applied to Sargassum polycystum biomass as a model biosorbent, it was found that the biomass contained three types of functional groups. In addition, the carboxyl group (pK=$3.7{\pm}0.09$) was found to be the major binding sites ($2.57{\pm}0.06 mmol/g$) for positively-charged heavy-metal ions.

Investigation of Charge distribution in an Electric double layer capacitor (전기이중층 캐패시터 내의 전하분포 고찰)

  • Endrowednes, Kuantama;Jessi, Darma;Sung, Youl-Moon;Kim, Kwang-Tae
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 한국조명전기설비학회 2008년도 추계학술대회 논문집
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    • pp.201-204
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    • 2008
  • The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about 205 C/$m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}$ = 2.5 V, while the positively charged density became the maximum, about 61.1 C/$m^3$ at the region where it was located around the cathode layer. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

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Spatio-temporal Charge Distribution in Electric Double Layer Capacitors observed by pulsed Electro Acoustic Method

  • Sung, Youl-Moon
    • Transactions on Electrical and Electronic Materials
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    • 제8권4호
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    • pp.182-187
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    • 2007
  • The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about $205C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}=2.5V$, while the positively charged density became the maximum, about $61.1C/m^3$ at the region where it was located around the cathode layer. The performance of the best sample was found to be better in terms of the charge density (Cs) and specific energy ($E_s$) with a maximum value of ${\sim}8.4F/g$ and 26 Wh/kg. The $C_s$ obtained from the PEA method agreed well with that from the energy conversion method. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.