• Economic and Environmental Geology
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• v.7 no.4
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• pp.157-173
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• 1974

The Red Hill deposit of the Dongjom Copper Mine is the most promising deposit of the mine and under intensive exploration at present although there are eight more deposits of vein type. With total 2160m drilling of 9 holes completed and 400m drilling on two holes underway, the nature of the Red Hill deposit has come more clear. The copper content in the whole ore body is meager so far as the exploration done up to present indicates, but there are evidences that mineralization covers all over the granodiorite cupola at the Red Hill area. The petrological work and assay on the samples taken by the writers indicate that granodiorite rocks can be divided into fresh zone and alteration zone. Alteration zone consists of potassic and argillic zones accompanyied by silicification zone on basis of Lowell and Guilbert model Argillic zone has closely related with a mineralization in the Red Hill deposit. It has been cleared that the alteration acompanyied with the mineralization took place not only &long vertical fissures but also in the irregular lateral zone, the nature of which is unknown. Judging from the results of exploration and petrochemical study on the Red Hill deposit which is imbedded in a southern part of the granodiorite cupola, it can be concluded by the writer's opinion that the Red Hill deposit is possibly a porphyry copper deposit, because the shape of the ore body, mineral zoning and paragenesis and wall rock alteration resemble to those of typical porphyry copper deposits. It is the writers' opinion that more exploration work is required so as to evaluate the deposit.

• Economic and Environmental Geology
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• v.31 no.1
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• pp.1-10
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• 1998

Copper mineralization of the Donghwa and Hwanghagsan mines was deposited in hydrothermal quartz veins which filled fissures in Cretacous sedimentary rocks. Ore minerals are pyrite, sphalerite, chalcopyrite, bornite, galena, wittichenite and unidentified Cu-Bi-Pb-Sb-S mineral. On the basis of salinities and homogenization temperatures for fluid inclusions, the Donghwa deposit was deposited from $300^{\circ}C$ to $220^{\circ}C$ with 2.5 to 0.2 wt.% eq. NaCl, and the Hwanghagsan deposits was deposited from $300^{\circ}C$ to $160^{\circ}C$ with 4.0 to 0.0 wt.% eq. NaCl. Evidence of boiling suggests pressure of 170 to 60 bar, these pressures correspond to 1700 m to 600 m. The ${\delta}^{34}S_{H_2S}$ values of the Donghwa deposit (4.8~7.4%) are higher than those of the Hwanghagsan deposit (3.5~4.5%), sulfur isotope compositions indicate that ore fluids partially reacted with meteoric water and wall-rock. Equilibrium thermodynamic interpretation indicates that the temperature versus $fs_2$ of the Donghwa deposit (> $420^{\circ}C$, $10^{-3.2}atm$) is higher condition than that of the Hwanghagsan deposit (> $290^{\circ}C$, $10^{-7.0}atm$). K-Ar ages for biotite granite and quartz porphyry in the study area are 64.7 Ma, and 60.9 Ma, reapectively. Mineralization age using sericite in the Donghwa deposits is 59.8 Ma. Therfore, Copper mineralization in the study area was associated with acidic igneous activity such as biotite granite or quartz porphyry.

• Journal of the Mineralogical Society of Korea
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• v.29 no.1
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• pp.23-34
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• 2016

Tsogttsetsii area, an intrusive complex associated with Cu porphyry mineralization, is located in the Gurvansaikhan island arc terrane of the Central Asian Orogenic belt, Southern Mongolia. We performed a reconnaissance survey in Tsogttsetsii area. Cu mineralization in Tsogttsetsii area is porphyry Cu type related with alkali granite intruded in Permian. Mineralogical and textural properties of the ores and associated minerals were analyzed using X-ray diffraction, thin section petrography, and Scanning electron microscopy-Energy dispersive spectroscopy (SEM-EDS). Ore minerals identified in polarizing microscope are magnetite, pyrite and bornite. Propylitic alteration zone occurs broadly in the area where malachite occurrences are shown to be spread intensively in alkali granite area. Quartz, sericite, chlorite and epidote were observed in the alteration zone samples. As results of XRD and SEM-EDS analysis, samples of copper oxides were composed mainly of malachite, cuprite and small amounts of quartz. Average and maximum Cu contents of samples collected from malachite occurrences area are 759 ppm and 6190 ppm, respectively. The characteristics of mineralization in Tsogttsetsii area is similar to Oyu Tolgoi Cu-Au (Mo) deposit and Tsagaan Suvarga Cu-Mo deposit which are 56 km south and 120 km northeast from Tsogttsetsii area, respectively. Characteristics of the study area, such as the geology, tectonic environment, lithology, mineralization, and alterations of the rocks within the survey area, resemble the characteristics of other porphyry deposits. Therefore further exploration including Induced Polarization (IP) survey for identifying subsurface orebody is required.

• Economic and Environmental Geology
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• v.46 no.6
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• pp.561-568
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• 2013

The copper mineralization in Peru is intimately associated with porphyry Cu deposits and subdivides into three porphyry Cu belt as Paleocene, Eocene-Oligocene, and Miocene. Up to now, the total copper production from them reach 28 Mt Cu. The total copper production from the Paleocene Cu belt, including Toquepala, Cuajone, and Cerro Verde, accounts for approximately 57% of total copper production from Peru. But focusing mineral exploration on middle southern (Eocene-Oligocene) and northwestern part (Miocene) of Peru results in new discoveries, including La Granja, El Galeno, Las Bambas, Toromocho, and Rio Blanco, which have an estimated annual production more than 200,000 t Cu. In addition to them, thirteen Cu deposits are discovered from the Paleocene, Eocene-Oligocene, and Miocene Cu belts. Thus, Peru is supposed to produce Cu production from 2014 and increases annual production from 143 Mt Cu in 2012 to 490 Mt Cu in 2019. Due to new discoveries, it is expected that mineral exploration activities in Peru are likely to move from Paleocene Cu belt to Eocene-Oligocene and Miocene Cu belts.

• Proceedings of the KSEEG Conference
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• 2005.04a
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• pp.78-81
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• 2005

• Economic and Environmental Geology
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• v.5 no.4
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• pp.211-217
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• 1972

The Second Yeon Hwa Mine which belongs to a so called Lead-Zines Belt Area in the central east Korea is located at about 10 km northeast of the Seogpo railway station on Yeongdong Line. The exploitation of the mine started in June, 1969 and furnished the machinary ore dressing plant in November, 1971. The current monthly production of rude ore is 15,000 meteric tons. The results of the study on the lead-zinc-copper deposits of the Second Yeonhwa mine are summerized as follows: (1) main ore deposits of the mine are localized in the Pungchon Limestion formation of Cambrian age, (2) related ingneous rock with ore deposits is granite porphyry, which distributed in NS and $N50^{\circ}W$ trend, (3) ore solution ascended along the $N50^{\circ}W$ trend which represents folding axis and fault plane and mineralized selectively in the limestone formation. (4) high grade ore deposits are localized in concave and convex boundaries of granite porphyry, and hanging walls of shale bed ($P_2S$ shale bed) in Pungchon Limestone formation and (5) skarn minerals are consisted of garnet, hedenbergite, diopside, and sulfide minerals are composed of zincblenede, galena, phyrhotite, pyrite and some amount of chalcopyrite and arsenopyrite.

• Economic and Environmental Geology
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• v.25 no.3
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• pp.283-296
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• 1992

The Keumryeong deposits is a low grade copper deposits in which copper minerals form disseminated grains and thin veinlets in felsic volcanics seem to be dacite. Alteration of the volcanics consists mainly pervasive propylitization and silicification. Potassic alteration characterized by biotite developed locally adjacent to southwestern contact of granodiorite body. Principal sulfide minerals in altered zone are mainly pyrite and lesser chalcopyrite. Chalcopyrite content in potassic zone is relatively higher than that of surrounding propylitized zone. Pyrite and chalcopyrite accompanies magnetite, molybdenite, sphalerite, pyrrhotite, arsenopyrite, pentlandite, marcasite, hematite, ilmenite, rutile, bismuthinite and native Bi as disseminations, veinlets and knots. Granodiorite body is propylitized and contains veinlets of pyrite, chalcopyrite and molybdenite. Fluid inclusions in sulfide-bearing quartz veinlets and quartz grains of felsic volcanics and granodiorite in altered zone consist of liquid-rich, vapor-rich, $CO_2-bearing$ and halite-bearing inclusions. These four types of inclusion intimately associated on a microscopic scale and indicate condensing or boiling of ore fluid during mineralization. Homogenization temperature of coexisting fluid inclusions are mostly in the range of 350 to $450^{\circ}C$. High salinity fluid contains 28.6 to 48.4 weight percent NaCI equivalent and moderate salinity fluid cotains 0.5 to 12.5 weight percent NaCl equivalent. Pressure estimated from $CO_2$ mole fraction of $CO_2-bearing$ inclusion range 160 to 375 bars. The Kigu copper deposits is a fissure filling copper vein developed 500 m south from the Keumryong deposits. Mineralogy and fluid inclusion data of the Kigu deposits are similar to that of the Keumryeong deposits. Homogenization temperature of fluid inclusions from the Kigu deposits are reasonable agreement with temperature estimated from sulfidation curve of cubanite-chalcopyrite-pyrite-pyrrhotite and pyrite-pyrrhotite mineral assemblages. Not only mineral occurrence and wall rock alteration in the Keumryeong deposits but also fluid inclusion data such as temperature, salinity, pressure and boiling evidences are similar to those of porphyry copper deposits.

• Economic and Environmental Geology
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• v.35 no.3
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• pp.211-220
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• 2002

The Xiaoxinancha Cu-Au deposit in the Jilin province, located in NNE 800 km of Beijing, is hosted by diorite. The ore mineralization of Xiaoxinancha Cu-Au deposit show a stockwork occurrence that is concentrated on the potassic and phyllic alteration zones. The Xiaoxinancha Cu-Au deposit in the south is being mined with its reserves grading 0.8% Cu, 3.64 g/t Au and 16.8 g/t Ag and in the north, grading 0.63% Cu, 3.80 g/t Au and 6.8 glt Ag. The alteration assemblage occurs as a supergene blanket over deposit. Hydrothermal alteration at the Xiaoxinancha Cu-Au deposit is centered about the stock and was extensively related to the emplacement of the stock. Early hydrothermal alteration was dominantly potassic and followed by propylitic alteration. Chalcocite, often associated with hematite, account for the ore-grade copper, while chalcopyrite, bornite, quartz, epidote, chlorite and calcite constitute the typical gangue assemblage. Other minor opaque phases include pyrite, marcasite, native gold, electrum, hessite, hedleyite, volynskite, galenobismutite, covellite and goethite. Fluid inclusion data indicate that the formation of this porphyry copper deposit is thought to be a result of cooling followed by mixing with dilute and cooler meteoric water with time. In stage II vein, early boiling occurred at 497$^{\circ}$C was succeeded by the occurrence of halite-bearing type III fluid inclusion with homogenization temperature as much as 100$^{\circ}$C lower. The salinities of type 1II fluid inclusion in stage II vein are 54.3 to 66.9 wt.% NaCI + KCI equiv. at 383$^{\circ}$ to 495$^{\circ}$C, indicating the formation depth less than 1 km. Type I cupriferous fluids in stage III vein have the homogenization temperatures and salinity of 168$^{\circ}$ to 365$^{\circ}$C and 1.1 to 9.0 wt.% NaCI equiv. These fluid inclusions in stage III veins were trapped in quartz veins containing highly fractured breccia, indicating the predominance of boiling evidence. This corresponds to hydrostatic pressure of 50 to 80 bars. The $\delta$$^{34}S$ value of sulfide minerals increase slightly with paragenetic time and yield calculated $\delta$$^{34}S_{H2S}$ values of 0.8 to 3.7$\textperthousand$. There is no mineralogical evidence that fugacity of oxygen decreased, and it is thought that the oxygen fugacity of the mineralizing fluids have been buffered through reaction with magnetite. We interpreted the range of the calculated $\delta$$^{34}S_{H2S}$ values for sulfides to represent the incorporation of sulfur from two sources into the Xiaoxinancha Cu-Au hydrothermal fluids: (1) an isotopically light source with a $\delta$$^{34}S$ value of I to 2$\textperthousand$, probably a Mesozoic granitoid related to the ore mineralization. We can infer from the fact that diorite as the host rock in the Xiaoxinancha Cu-Au deposit area intruded plagiogranite; (2) an isotopically heavier source with a $\delta$$^{34}S$ value of > 4.0$\textperthousand$, probably the local porphyry.

• Economic and Environmental Geology
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• v.16 no.1
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• pp.1-10
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• 1983

The Yeonhwa (I, II) and Keodo mines, neighboring in the middle part of the Taebaegsan mineral belt, contain three distinct classes of skarn deposits: the zinc-lead skarn at Yeonhwa (I, II), the iron skarn at Keodo south (Jangsan orebodies), and the copper skarn at Keodo north (78 orebodies). The present study characterizes the three classes of skarn deposits mainly in terms of skarn/ore associations examined from chemical compositional point of view, and applies existing quantitative phase diagrams to some pertinent mineral assemblages in these mines. At Yeonhwa I the Wolam I orebody shows a vertical variation in skarn minerals ranging from clinopyroxene/garnet zone on the lower levels through clinopyroxene (without garnet) zone on the intermediate levels, and finally to rhodochrosite veins on the upper levels and surface. Ore minerals, sphalerite and galena, associate most closely with the intermediate clinopyroxene zone. At Keodo, the Jangsan iron skarn hosted in quartz monzodiolite as a typical endoskarn, shows a skarn zoning, from center of orebody to outer side, magnetite zone, magnetite/garnet zone, garnet clinopyroxene zone, and clinopyroxene/epidote/plagioclase zone. The 78 copper skarn in the Hwajeol limestone indicates a zoning, from quartz porphyry side toward limestone side, orthoclase/epidote zone, epidote/clinopyroxene zone, and clinopyroxene/garnet zone; chalcopyrite and other copper sulfides tend to be in clinopyroxene/garnet zone. Mioroprobe analyses of clinopyroxenes and garnets from the various skarn zones mentioned above revealed that the Yeonhwa zinc/lead skarns are characterized by johansenitic clinopyroxene (Hd 25-78, Jo 15-23) and manganoan andraditic garnet (Ad 13-97, Sp 1-24), whereas the Jangsan iron skarn at Keodo by Mn-poor diopsidic clinopyroxene (Di 78-93, Jo 0.2-1.0) and Mn-poor grossularitic grandite (Gr 65-77, Sp 0.5-1.0). The 78 copper skarn at Keodo is characterized by Mn-poor diopsidic-salite (Di 66-91, Jo 0.2-1.1) and Mn-poor andraditic grandite(Ad 40-74, Sp 0.5-1.1). The compositional charateristics of iron, copper, and zinc-lead skarns in the Yeonhwa-Keodo mines are in good correlations with those of the foreign counterparts. Compiling a $T-XCO_2$ phase diagram for the Jangsan endoskarns, a potential upper limit of temperature of the main stage of skarn formation is estimated to be about $530^{\circ}C$, and a lower limit to be $400^{\circ}C$ or below assuming $XCO_2=0.05$ at P total=1kb. Applying a published log $fS_2$-log $fo_2$ diagram to the Keodo 78 and Yeonhwa exoskarns, it is revealed that copper sulfides and zinc-lead sulfides do not co-exist stably below log $fS_2=-4$ and log $fO_2=-23$ at $T=400^{\circ}C$ and ${\times}CO=1$ atm.

• Economic and Environmental Geology
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• v.41 no.6
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• pp.773-795
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• 2008

The major import minerals of South Korea are copper ore, lead-zinc ore, iron ore, manganese ore and molybdenum ore. Oversea resources development of South Korea have 92 projects in 14 nations of Asia, 29 projects in 10 nations of America and Europe, and 14 projects in 9 nations of Middle Asia and Africa. But, most projects of them are found in Australia, China, Mongolia and Indonesia. The most projects of the Australia, China and Indonesia are interested in coal and a little projects of them have manganese, iron, lead-zinc, nickel, copper, gold, molybdenum, rare earth elements and uranium. The most projects of the Mongolia are interested in gold and rare earth elements. Representative ore deposits models of metal resources are Orogenic lode deposits, Volcanogenic massive sulphide deposits, Porphyry deposits, Sedimentary exhalative deposits, Mississippi valley type deposits, Iron oxide copper-gold deposits and Magmatic nickel-copper-platinum group element deposits based on global distribution, reverses and grades of their deposits models. If oversea mineral resources will be examined the mineral reserves, mineral mine production and ore deposits models of nations and then survey and investigate of mineral resources, we may be maintained ore body of high grade at survey area and decrease the investment risk.