• Title/Summary/Keyword: porous matrix

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VARIATIONS OF CONTAMINANT RETARDATION FACTOR IN THE PRESENCE OF TWO MOBILE COLLOIDS

  • Kim, Song-Bae;Kim, Dong-Ju
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.115-119
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    • 2001
  • Contaminant retardation factor is derived from the colloidal and contaminant transport equations for a four-phase porous medium: an aqueous phase, two mobile colloidal phases, and a solid matrix. It is assumed that the contaminant sorption to solid matrix and colloidal particles and the colloidal deposition on solid matrix follow the linear isotherms. The behavior of the contaminant retardation factor in response to the change of model parameters is examined employing the experimental data of Magee et al. (1991) and Jenkins and Lion (1993). In the four-phase system, the contaminant retardation factor is determined by both the contaminant association with solid matrix and colloidal particles and the colloidal deposition on solid matrix. The contaminant mobility is enhanced when the affinity of contaminants to mobile colloids increases. In addition, as the affinity of colloids to solid matrix decreases, the contaminant mobility increases.

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Manufacture of SiC matrix for PAFC (인산형 연료전지용 SiC MATRIX 제조)

  • 김영우;이주성
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.187-193
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    • 1993
  • Porous matrices to contain and support phosphoric acid were prepared with PTFE as binder and SiC whisker or SiC powders of various particle size for phosphoric acid fuel cell(PAFC). Among the matrix characteristics the most important factors in stack performances were thought to be the bubble pressure and electrolyte wettability And then matrix was constructed to have pore size smaller than that of electrode. The bubble pressures and wettabilities of matrices manufactured with various size of SiC and different PTFE contents were investigated and related with the porosities measured by porosimeter, and then the optimum manufacturing condition of matrix for PAFC was determined.

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A Theoretical Study on the Colloid-facilitated Radionuclide Transport with Decay Chain in the Fractured Rock (균열암반에서 방사성 붕괴사슬과 콜로이드를 동반한 방사성 핵종의 이동에 관한 이론적 연구)

  • 박진백;황용수;강철형
    • Tunnel and Underground Space
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    • v.13 no.1
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    • pp.20-32
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    • 2003
  • To understand the behavior of migration of contaminants in a fractured porous medium is a key to assure the overall safety of a potential radwaste repository. The feasible retention mechanism of contaminant transport in a tinctured medium are sorption of contaminants on solid surface and matrix diffusion of contaminants from a fracture into an adjacent porous medium. The acceleration mechanisms are the migration of contaminants in the form of pseudo-colloids and the limit of a volume f3r matrix diffusion. In this paper, the effects of these two acceleration mechanisms are studied mathematically, then semi-analytically computed by the application of the Talbot theorem and verified. Results indicate that the acceleration processes cannot be neglected in the modeling of contaminant transport in a fractured porous medium.

Development of Environmentally Favorable Porous Concrete and Water Purification Characteristics by the Pavement System (친환경 도로포장용 투수콘크리트의 제조와 이를 이용한 도로포장시스템의 수질정화특성)

  • Hong, Chong-Hyun;Kim, Moon-Hoon;Yang, Churl-Shin
    • Journal of Environmental Science International
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    • v.15 no.11
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    • pp.1045-1052
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    • 2006
  • Stormwater pollution is a major problem in urban areas. Pollutants like heavy metals and harmful chemicals in the runoff can endanger soil and ground water, when they are not sufficiently removed doting infiltration. Strength and infiltration capacity of porous concrete are the major problems that must be considered if permeable pavement system are demanded to be used in a drive way application. In this study, a series of compacted porous concrete mixtures and the system of pavement ate tested for the physical characteristics like compressive strength, flexural strength, unit weight, porosity, water permeability, and the purification capacity of contaminated water. The test results obtained indicate that the strength and infiltration capacity of porous concrete are strongly related to its matrix proportion and compaction energy and providing adequate filter layers underneath pavement surface course is one of the most important design considerations of permeable pavement system for pollution retention purpose.

Preparation of Biodegradable Porous Calcium Metaphosphate Matrix (생분해성 다공질 Calcium Metaphosphate Matrix의 제조)

  • 이중환;김석영
    • Journal of Biomedical Engineering Research
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    • v.19 no.5
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    • pp.449-454
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    • 1998
  • It is well known that new tissue or blood vessel is grown into a porous calcium phosphate ceramics used as a bone graft substitute due to their excellent biocompatibility. In this study, the most chemically stable porous $\beta$-crystalline form in various forms of calcium metaphosphate, Ca(PO$_3$)$_2$is prepared by the controlled thermolysis of monocalcium phosphate, Ca(H$_2$PO$_4$)$_2$.The diameter of cylindrical pores formed during cooling was controlled by a holding time at the melting point of a monocalcium phosphate and by the change of a crystallization temperature, to obtain the most appropriate size (about 200$\mu$m) of pores for the application of bone substitutes and matricuts. It was observed that the increasing holding time at the melting point of monocalcium phosphate results in the decreases of cylindrical pore sizes.

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Effect of Forming Process and Particle Size on Properties of Porous Silicon Carbide Ceramic Candle Filters (성형공정(成形工程)과 원료입도(原料粒度)가 다공성(多孔性) 탄화규소(炭火硅素) 세라믹 캔들 필터 특성(特性)에 미치는 영향(影響))

  • Han, In-Sub;Seo, Doo-Won;Hong, Ki-Seog;Woo, Sang-Kuk
    • Resources Recycling
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    • v.19 no.5
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    • pp.31-43
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    • 2010
  • To fabricate porous SiC candle filter for filtration facility of the IGCC system, the candle type filter preforms were fabricated by ramming and vacuum extrusion process. A commercially available ${\alpha}$-SiC powders with various particle size were used as starting raw materials, and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as non-clay based inorganic sintering additive. The candle typed preforms by ramming process and vacuum extrusion were sintered at $1400^{\circ}C$ for 2h in air atmosphere. The effect of forming method and particle size of filter matrix on porosity, density, strength (flexural and compressive strength) and microstructure of the sintered porous SiC candle tilters were investigated. The sintered porous SiC filters which were fabricated by ramming process have more higher density and strength than extruded filter in same particle size of the matrix, and its maximum density and 3-point bending strength were $2.00\;g/cm^3$ and 45 MPa, respectively. Also, corrosion test of the sintered candle filter specimens by different forming method was performed at $600^{\circ}C$ for 2400h using IGCC syngas atmosphere for estimation of long-term reliability of the candle filter matrix.

Characteristics of Energy Dissipation in Vibration Absorbing Nano-Damper According to the Architecture of Silica Particle (세라믹 분말의 입자구조에 따른 나노 진동 흡수장치의 에너지 소산 효율 특성에 대한 연구)

  • Moon, Byung-Young;Kim, Heung-Seob
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.144-149
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    • 2003
  • This study shows an experimental investigation of a reversible nano colloidal damper, which is statically loaded. The porous matrix is composed from silica gel (labyrinth or central-cavity architecture), coated by organo-silicones substances, in order to achieve a hydrophobic surface. Water is considered as associated lyophobic liquid. Reversible colloidal damper static test rig and the measuring technique of the static hysteresis are described. Influence of the pore and particle diameters, particle architecture and length of the grafted molecule upon the reversible colloidal damper hysteresis is investigated, for distinctive types and mixtures of porous matrices. Variation of the reversible colloidal damper dissipated energy and efficiency with temperature, pressure, is illustrated. As a result, he proposed nano damper is effective one, which can be replaced the conventional damper.

Characteristics and Fabrication of GRIN glass by ion-stuffing method (Ion-stuffing방법에 의한 GRIN glass의 제조와 특성)

  • 진영훈;한덕희;이병철;류봉기
    • Journal of the Korean institute of surface engineering
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    • v.34 no.3
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    • pp.240-246
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    • 2001
  • The possibility of using a glass block with the composition of sodium borosilicate as starting materials for GRIN glass was examined from the view points of the phase separation of the matrix glass, the effects of leaching and the heating conditions for a porous structure, and the change in the refractive index. Glass specimens with similar compositions were prepared in the form of porous glass using a phase-separation technique. An examination of the heating and leaching conditions and the microstructure dependence of these conditions was made.; Specimens with porous structure were obtained when the heat treatment and leaching conditions were fixed at $540^{\circ}C$ for 30hrs and in a 0.3N$ H_2$$SO_4$ solution at $100^{\circ}C$, respectively. The resultant specimens had some important features on the GRIN glass.; the depth of the gradient and the change in refractive index (Δn) were 4mm and 0.015~0.02, respectively.

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