• 한국입자에어로졸학회지
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• 제8권2호
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• pp.89-95
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• 2012

Spherical mesoporous silica particles, of which main pore diameter was 3.8 nm, were successfully prepared by spray pyrolysis from aqueous silicic acid. The effect of precursor concentration, reaction temperature, and the addition of urea and PEG on the particle diameter and pore properties such as pore diameter, total pore volume, and specific surface area were investigated by using FE-SEM, particle size analyzer, and nitrogen absorption-desorption analysis. With an increase of the precursor concentration from 0.2 M to 0.7 M, the average particle diameter, total pore volume, and specific surface area of the porous silica particles increased from 0.56 to $0.96\;{\mu}m$, 0.434 to $0.486\;cm^3/g$, 467.8 to $610.4\;m^2/g$, respectively. Within the temperature range $(600\;^{\circ}C{\sim}800\;^{\circ}C)$, there was no significant difference in the pore diameter, total pore volume, and specific surface area. In addition, the addition of urea as an expansion aid led to slight increases in particle diameter, pore diameter, and specific surface area. However, when the polyethylene glycol (PEG) as an organic template was used, the total pore volume of porous particles increased dramatically.

• 콘크리트학회논문집
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• 제15권2호
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• pp.345-351
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• 2003

The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

• 한국연초학회지
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• 제16권2호
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• pp.181-190
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• 1994

Various active carbons were made from plant sources of coconut shell, pine tree, oak tree and lignite coal. Pore characteristics of these adsorbents were investigated. 1, With increasing activation time, specific surface area and pore volume increased, but the development of micropores was limited at a certain level. The average pore diameter, by BET, of coconut active carbon was 15.5-21.8$\AA$ and that of lignite carbon was 15.6-31.3$\AA$. The pore diameters of silica-gel, sepiolite and zeolite was 30.9$\AA$, 58.6$\AA$ and 55.7$\AA$, respectively. 2. The Horvath - Kawazoe micropore diameter of coconut shell active carbon was under 10.5$\AA$ and that of the other active carbon was under 20.9$\AA$ but silica-gel 33$\AA$, sepiolite 103 $\AA$ and zeolite was unexpectedly large to be 175$\AA$. From the difference between BET micropore diameter and Howath - Kawazoe diameter, it could be said that silica - gel has comparatively uniform pore diameter but sepiolite and zeolite have very uneven diameter. 3. Total pore volume of coconut shell active carbon was 0.27-1.04 cm3/g but that of the other active carbon, 0.23-0.62 cm3/g, was much lower than that of coconut shell active carbon. Hydrophilic adsorbent silica - gel and sepiolite showed big difference in specific surface area, but pore volumes of these were 0.47 and 0.56 cm3/g showing similar value and micropore volumes of these were, respectively, 0.06 cm3/g and 0.04 cm3/g. Total pore volume of zeolite was 0.1 cm3/g and that of micropore was only 0.02 cm3/g.

• 한국진공학회지
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• 제2권4호
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• pp.491-500
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• 1993

The adsorption of nitrogen (77K) and carbon dioxide(273K) was performed on a series of activated carbon fiber. Theadsorption iotherm of nitrogen was typical type 1 and that of carbon dioxide was convex. As the specific surface area increases, there are linear increases in BET constant C mean pore diameter, the width of pore size distribution, wide micropore volume, total micropore volume, total pore volume and external surface area, however, narrow micropore volume was nealy constant . The total micorpore volume fraction in total pore volume is above 97%.

• 한국입자에어로졸학회지
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• 제12권3호
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• pp.65-72
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• 2016

Nanoporous $SiO_2$ particles containing different pore volume and size were prepared from silicic acid by a spray pyrolysis. The pore size, pore volume and particle size could be controlled with varying the precursor concentration, reaction temperature, and amount of organic templates such as Urea and poly ethylene glycol (PEG). The pore size distribution, pore volume and specific surface area of as-prepared particles were analyzed by BET and BJH methods, and the average particle sizes were measured by a laser diffraction method. The nanoporous $SiO_2$ particles ranged $0.6-0.9{\mu}m$ in diameter were successfully synthesized and the average particle size increased as the silicic acid concentration increased. The morphology of nanoporous $SiO_2$ particles was spherical and pores ranged 1 - 40 nm in diameter were measured in the particles. In case of Urea added into silicic acid, it showed no much difference in the morphology, pore size and pore volume at different Urea concentration. On the other hand, when PEG was added, it was clearly observed that pore diameter and pore volume of the particles surface increased with respect to PEG concentration.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.329-332
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• 2004

This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the pore structure of NSC Matrix. The result of experiment of pore structure properties, showed no considerable difference for total pore volume by cement mixing ratio but shows a large distinction in distribution of pore diameter. On the whole, pore-diameter of paste of NSC show that occupation ratio of pore diameter below 10mm is larger and is smaller than OPC and BFSC at pore diameter of over 10nm. Such a reason is that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

• Geomechanics and Engineering
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• 제2권3호
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• pp.191-202
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• 2010

The porosity (including the specific surface area and pore volume-diameter distribution) of montmorillonitic soft rock (MSR) was studied experimentally with an electrochemical treatment, based on which the change in porosity was further analyzed from the perspective of its electrokinetic potential (${\zeta}$ potential) and the isoelectric point of the electric double layer on the surface of the soft rock particles. The variation between the ${\zeta}$ potential and porosity was summarized, and used to demonstrate that the properties of softening, degradation in water, swelling, and disintegration of MSR can be modified by electrochemical treatment. The following conclusions were drawn. The specific surface area and total pore volume decreased, whereas the average pore diameter increased after electrochemical modification. The reduction in the specific surface area indicates a reduction in the dispersibility and swelling-shrinking of the clay minerals. After modification, the ${\zeta}$ potential of the soft rock was positive in the anodic zone, there was no isoelectric point, and the rock had lost its properties of softening, degradation in water, swelling, and disintegration. The ${\zeta}$ potential increased in the intermediate and cathodic zones, the isoelectric point was reduced or unchanged, and the rock properties are reduced. When the ${\zeta}$ potential is increased, the specific surface area and the total pore volume were reduced according to the negative exponent law, and the average pore diameter increased according to the exponent law.

• 한국연초학회지
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• 제16권2호
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• pp.191-197
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• 1994

Relationships between surface structure and adsorption properties of smoke components were investigated in surface-modified and un-modified activated carbon filter cigarettes. Commercially available activated carbon was treated with nitric acid and hydrogen peroxide as oxidant, and their pore volume, surface structure, BET surface area, pore type and size were studied. BET surface area and pore volume were decreased by nitric acid treatment, but median pore diameter was 8.1 $\AA$, which showed better development of pore compared with that of un-modified activated carbon, 6.9 $\AA$. In case of hydrogen peroxide treatment, BET surface area and pore volume were increased. Their pore was found to be a slit type based on V-t plot analysis. Neutralization capacities for bases of different strength (NaHCO3, Na2CO3, NaOEt and NaOH) showed that the majority of the acidic surface groups are of weak acidity. Modification of the activated carbon surface led to a slight change in adsorption properties when analyzing the smoke of triple-filter cigarette with surface-modified activated carbon.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.711-714
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• 2003

Factors causing deterioration of concrete structures under marine environment are various, especially penetration and diffusion of chloride ion, carbon dioxide, and water through pore effects on the durability of concrete as well as mechanical properties of concrete. Pore of porous materials like concrete can be classified as micro-, meso-, and macro-pore. And pore of cement matrix is classified as pore which occupied by water, air void, and ITZ between cement paste and aggregates. In this study, to verify the relationship between pore of cement matrix and the property of chloride ion diffusivity, the regression analysis is producted. From the result of regression analysis, the average pore diameter more than total pore volume effects on the diffusivity of chloride ion.

• 한국재료학회지
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• 제28권1호
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• pp.62-67
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• 2018

Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.