• 공업화학
• /
• 제17권2호
• /
• pp.188-193
• /
• 2006

용액의 pH, 주입방법, 온도, 유량의 변화를 주면서 질산알루미늄($Al_{3}(NO_{3})_3{\cdot}9H_{2}O$)을 암모니아수($NH_{4}OH$)로 침전시켜 베마이트(Boehmite)를 합성하였다. 베마이트 상이 형성되는 pH 범위와 입자의 형상과 기공특성에 미치는 합성 조건의 영향을 조사하였다. 베마이트는 반응 용액의 pH가 7.5~9일 때 형성되었고, P2jet 주입방법은 침전이 일어나는 동안 pH를 일정하게 유지할 수 있어 용액내의 반응에 참여하는 이온의 농도가 일정하게 유지되어 균일한 크기의 입자와 기공을 형성할 수 있게 하였다. 따라서 비표면적과 기공부피 두 가지 동시에 향상되었다. 온도가 올라갈수록, 유량이 감소할수록 비표면적과 기공부피가 증가함을 보이고, $60^{\circ}C$ 이상에서는 미세섬유모양의 입자를 얻을 수 있었다. 최적의 조건은 pH 9에서 P2jet 방법으로 주입하고 반응온도 $90^{\circ}C$와 유량 2.5 mL/min을 유지하였을 경우로 비표면적은 $385.46m^2/g$이고 기공 부피는 1.0252 mL/g을 가지는 평균 10 nm의 기공이 형성된 다공성 베마이트를 얻을 수 있었다.

• 한국터널지하공간학회 논문집
• /
• 제15권3호
• /
• pp.333-344
• /
• 2013

본 연구에서는 절리 암반 내 터널굴착 시 지하수 유출량 예측량이 실제 계측치와 큰 차이가 나는 이유 중 하나인 터널주변 절리암반의 투수계수의 감소 현상에 대해 논의하였다. 현재 터널 설계 시 일반적으로 사용되고 있는 지하수 유출량 산정식은 터널주변 암반이 등방, 균질하고 일정한 투수계수를 유지한다고 가정한다. 하지만, 실제로는 터널주변 절리암반의 투수계수는 터널주변 유효응력 상태에 따라 변화하며, 절리 내 지하수 흐름에 따라 다시 터널주변 유효응력 분포가 영향을 받는 수리-역학적 상호거동을 보인다. 터널굴착 직후 터널 접선방향 유효응력이 응력집중과 간극수압 감소로 인해 급증하고 그에 따라 절리의 닫힘현상이 발생하며, 결과적으로 터널인접 절리암반 링 구간에서 투수계수가 급격히 감소하게 된다. 이러한 터널인접 링 구간 내에서 상당히 큰 간극수압 감소가 발생하게 되어 터널주변 간극수압 분포는 등방 균질의 절리암반으로 가정한 산정식과 큰 차이를 보인다. 본 연구에서는 절리암반의 수리-역학적 상호거동의 개념을 도입하여 터널주변 간극수압 분포와 터널 내 지하수 유입량 산정방법을 제안하고 이를 수치해석을 통해 검증하였다.

• Corrosion Science and Technology
• /
• 제17권5호
• /
• pp.203-210
• /
• 2018

This paper compares the inhibition properties of aspartic and lactic acid salts with nitrite ions and their effect on critical chloride concentration. The tests were carried employing carbon steel specimens in saturated lime solution with varying pH in the range between13 to 13.6. The critical chloride concentration was estimated through multiple specimen potentiostatic tests at potentials in the usual range for passive rebar in the alkaline concrete of atmospheric structures. During tests, chloride salt was added every 48 h until all the specimens showed localized attacks. The cumulative distribution curves, i.e. the number of corroded specimens as a function of the chlorides concentration was obtained. Furthermore, IR spectra were recorded for the evaluation of the presence of the organic inhibitors on the passivity film. The results confirmed the inhibitory effect of 0.1M aspartate comparable with nitrite ions, at a similar concentration. Addition of calcium lactate did not result in an increase in the critical chloride concentration. However, the formation of a massive scale containing the substance that could reduce the corrosion propagation was observed.

• 상하수도학회지
• /
• 제30권2호
• /
• pp.131-137
• /
• 2016

The development of alternative water resources has emerged as an effective method for solving drought of water resources due to extreme weather and increase in water consumption. Recently, in Korea, there has been active research on reverse osmosis desalination technology, wastewater reuse using forward osmosis membranes, and the forward osmosis(FO)-reverse osmosis(RO) hybrid process combining these two technologies. In this study, the basic performance of FO membranes manufactured by three domestic and international manufactures such as Microfilter Co., Ltd., Toray Chemical Korea Inc., and Hydration Technologies Inc., were investigated for wastewater reuse. In addition, as an experiment to select feed solution, the selected membranes were operated 48 consecutive hours using three secondary effluents pretreated by the UF membrane with a pore size of $0.1{\mu}m$ and auto strainer with pore sizes of $1{\mu}m$ and $100{\mu}m$ as feed solution. Although there was not much difference in the operating performance. Thus, the treated water using the $100{\mu}m$ auto strainer was selected as feed solution applied to the assessment.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2003년도 추계학술발표회
• /
• pp.426-430
• /
• 2003

Subsurface biobarrier technology has potential applications to contain contaminated groundwater and/or to degrade toxic pollutants in groundwater. Effective biobarrier formation is need to assess of hydrogeologic characteristics and to conduct practical operation strategies and design based on this prior to design biobarrier. Thus, in this study, we examined hydrogeologic characteristics in biobarrier construction site. Hydraulic conductivities which calculated from slug test data have shown difference with each well as 1.20$\times$10$^{-3}$ -6.00$\times$10$^{-5}$ cm/sec. Tracer test is a method in which concentration of tracer solution during withdrawal in each well by vacuum extraction system is measured with time. Tracer solution was continuously injected by constant head tank. Measured tracer concentration versus time data were fitted to analytical solution of convection dispersion equation (CDE). The fitting data of CDE to the measured data at each extraction well yielded were 0.61cm/min(pore velocity), 5.38$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.47 1/min and 1.75cm/min(pore velocity), 36.34$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.93 1/min. As a result, we acquired fundamental parameters which need to design biobarrier and operation strategies.

• Membrane and Water Treatment
• /
• 제7권6호
• /
• pp.495-505
• /
• 2016

Mesoporous MCM-41 was deposited on an inexpensive disk shaped ceramic support through hydrothermal technique for ultrafiltration of $Fe^{3+}$ from aqueous solution. The ceramic support was fabricated using uni-axial compaction technique followed by sintering at $950^{\circ}C$. The characteristics of MCM-41 powder as well as the composite membrane were examined by X-ray diffraction (XRD), thermogravimetric analysis (TGA), field emission scanning electron microscope (FESEM), porosity and pure water permeation test. The XRD result revealed the good crystallinity and well-resolved hexagonally arranged pore geometry of MCM-41. TGA profile of synthesized MCM-41 zeolite displayed the three different stepwise mechanisms for the removal of organic template. The formation of MCM-41 on the porous support was verified by FESEM analysis. The characterization results clearly indicated that the accumulation of MCM-41 by repeated coating on the ceramic disk directs to reduce the porosity and pore size from 47% to 23% and 1.0 to $0.173{\mu}m$, respectively. Moreover, the potential of the fabricated MCM-41 membrane was investigated by ultrafiltration of $Fe^{3+}$ from aqueous stream at various influencing parameters such as applied pressure, initial feed concentration and pH of solution. The maximum rejection 85% was obtained at applied pressure of 276 kPa and the initial feed concentration of 250 ppm at pH 2.

• 한국표면공학회지
• /
• 제51권6호
• /
• pp.405-414
• /
• 2018

The present study investigated the adhesion and corrosion resistance of subsequent electrophoretic paint (E-paint) on "electroless" paint coated AZ31 Mg alloy, which was formed by immersion of AZ31 Mg alloy in E-painting solution. It was found that with increasing immersion time of AZ31 in E-painting solution, the amount of paint deposited by electroless process increased but it decreased the electrochemical equivalent of E-painting process and the adhesion of the subsequent E-paint layer. The E-paint on electroless paint coated AZ31 contained pores with the highest pore density and the largest pore size was obtained on the samples with electroless times of 2 and 5 minutes, respectively. Results of the salt-spray test showed an accelerated growth of blisters over the entire surface of the sample immersed for less than 5 minutes whereas blisters were observed only in the vicinity of the scratch in case of samples treated for 15 and 30 minutes. The E-paint on AZ31 with shorter electroless immersion time in E-painting solution was found to have good adhesion and better corrosion resistance.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2023년도 봄 학술논문 발표대회
• /
• pp.59-60
• /
• 2023

The corrosion of steel rebar embedded in the coastal areas is corroding once the chloride ions ingress through the pores of the concrete. Therefore, in the present study, a 100 ㎛ thick Al and Zn coating was deposited by an arc thermal spray process onto the steel. The corrosion studies of these deposited coatings were assessed in 3.5 wt.% NaCl contaminated concrete pore (CP) solution with immersion periods. The results show that the Al coating is more corrosion resistance compared to the Zn coating attributed to the formation of gibbsite (γ-Al(OH)₃) whereas Zn coating exhibits Zn(OH)₂ onto the coating surface as passive layer. The Zn(OH)₂ is readily soluble in an alkaline solution. Alternatively, γ-Al(OH)₃ on the Al coating surface is less solubility in the alkaline pH, which further provides barrier protection against corrosion.

• 한국세라믹학회지
• /
• 제36권10호
• /
• pp.1040-1047
• /
• 1999

After alumina sol was prepared by Yoldas process supported membranes were fabricated by adding ce and Re solution and SiO2 sol into alumina sol. The particle size of alumina sol was 11 nm and it was monodispersed transparent and stable for long time. The pore size of un-doped membrane started to increase to about 7,5nm at 1000$^{\circ}C$ and it was grown to twice (about 15nm) at 1100$^{\circ}C$ However the pore size of doped alumina was uniform to 1100$^{\circ}C$. The effect of retardation of grain growth was superior in SiO2 addition to that of Ce and Ru Because SiO2 doped samples transformed to needed-like phase and densified at 1200$^{\circ}C$ their application in membranes was limited. Ce and Ru doped sample showed vermicular structure identical to the un-doped ones at 1200$^{\circ}C$ But the particle size was smaller than that of un-doped ones.

• 한국세라믹학회지
• /
• 제30권10호
• /
• pp.838-844
• /
• 1993

To control the pore size of silcia gel, formamide (FA), N,N-dimethyl formamide (DMF), polyethylene glycol (PEG) and polyacrylic acid (PAA) were added in the sol-gel process from starting solution with tetramethyl orthosilicate (TMOS). The gels were characterized using porosimeter, TG-DTA and SEM. As a result, the more contents of FA and PAA was increased the more gelation time was decreased, also the more contents of DMF and PEG was increased the more gelling time was increased. The mean pore size of gels was larger in the order of PAA, DMF, FA and PEG. And the mean pore size of porous silica glass was 59.0$\AA$, 31.5$\AA$, 29.9$\AA$ and 29.0$\AA$, respectively, heated at 75$0^{\circ}C$/100$0^{\circ}C$.