• Title/Summary/Keyword: pore plugging

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Placement of Colloidal Silica gel for the construction of a subsurface containment system

  • Kim, Meejeong;Park, Joo-Yang
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.66-69
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    • 2001
  • A subsurface containment system which is constructed by pumping a gelling liquid (Colloidal Silica) into the unsaturated medium is investigated by developing a mathematical model and conducting numerical simulations. The proposed model is verified by comparing experimentally and numerically determined hydraulic conductivities of gel-treated soil columns at different Colloidal Silica (CS) injection volumes. The numerical experiments indicate that an impermeable gel layer is formed within the time period twice the gel-point. At the Same normalized time, the CS solutions with lower NaCl concentrations result ill further migration and poor Performance in plugging the pore space.

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Direct liquefaction characteristics of Alaskan subbituminous coal using oil soluble transition metals as catalyst precursors (II) (유용성 전이금속 촉매전구체에 의한 Alaska산 아역청탄의 직접액화반응특성 (II))

  • 윤왕래;이득기;이인철;정구민;이봉희
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.141-145
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    • 1995
  • 석탄액화반응의 촉진을 위하여 기존에 사용되어 온 담지촉매는 coking, metal deposition, pore plugging의 문제로 인하여 촉매의 활성을 지속적으로 유지할 수 없으며 고가이기때문에 최근에는 이러한 문제점을 보완할 수 있는 고분산 균일촉매에 관한 연구가 집중적으로 수행되고 있다. 그러나 분산촉매 중에서도 고활성을 나타내는 Mo, Ni, Co 성분은 고가이므로 이를 대체할 수 있는 촉매로서 값이 싼 Fe 성분에 관심이 모아지고 있지만 현재로서는 자체활성이 상대적으로 낮으므로 퍼센트단위의 많은 양을 사용해야하는 문제점을 안고 있다고 할 수 있다.

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Fouling control in a woven fibre microfiltration membrane for water treatment

  • Chollom, Martha Noro;Rathilal, Sudesh;Pikwa, Kumnandi;Pillay, Lingham
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.418-426
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    • 2019
  • Current available commercial membranes are not robust and are therefore destroyed if left to dry out or handled roughly. Woven fibre microfiltration (WFMF) membranes have advantages over its competitors with respect to durability, thus, favourable for the developing economies and operation during rough conditions. Evaluation of the effects of aeration and brushing as a flux enhancement strategies for WFMF membrane was the purpose of this study. The WFMF membrane was found to be susceptible to pore plugging by colloidal material and adsorption/attachment by microbiological contaminants. This led to a 50% loss in flux. Aeration as a single flux enhancement strategy proved insufficient to maintain high flux successfully. Therefore combined flux enhancement strategies yielded the best results.

Response of Open-ended Pipe Pile Foundation at Offshore Sites to Seaquake Induced by the Vertical Seismic Excitation of the Seafloor (해저면의 수직 지진 진동에 의해 유발된 해진에 대한 해상 개단 강관 말뚝 기초의 거동)

  • 최용규;남문석
    • Journal of the Earthquake Engineering Society of Korea
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    • v.2 no.1
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    • pp.11-21
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    • 1998
  • During an earthquake, there are three main components of excitation : horizontal excitation of the ground, vertical excitation of the pile due to superstructure feedback produced by vertical excitation of the ground, and the seawater excitation induced by the vertical ground shaking, that is, "the seaquake." These excitations could have effects on the soil plugs in open-ended pie piles installed at offshore sites. In this study, seaquake excitation induced by the vertical ground shaking was simulated by pulsing the water pressure at the seabed. During a seaquake, due to the induced excess porewater pressure and pressure gradients in the soil, the capacity of open-ended pipe piles installed in a simulated sea depth of greate than 220 m was reduced serevely and the soil plugging resistance was degraded by more than 80% The soil plug was failed because of eh upward seepage forces that developed in the soil plug due to excess pore water pressure produced in the bottom of the soil plug during the seaquake, The compressive capacity of ar open-ended pile in a simulated sea depth of less than 220 m was reduced only by about 10% and the soil plug resistance was degraded by less than 5%.s than 5%.

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Porewater Pressure Buildup Mode Induced in Near-field of Open-ended Pipe Pile during Earthquake and Sequake (지진과 해진시 개단강관말뚝 주변에 유발된 간극수압의 발생 양상)

  • 최용규
    • Journal of the Earthquake Engineering Society of Korea
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    • v.2 no.4
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    • pp.23-30
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    • 1998
  • During an earthquake, there are three components of excitation : horizontal excitation of the ground, vertical excitation of the pile due to superstructure feedback produced by vertical excitation of the ground, and the seawater excitation by the vertical ground shaking, that is, "the seaquake." These excitations could have effects on the pore pressure buildup mode induced in the near-field of open-ended pile and the soil plugs in open-ended pipe piles installed at offshore sites. While the ground and pile excitation could be modeled by exciting the soil and pile with simulated motions, seaquake excitation induced by the vertical ground shaking can be modeled by pulsing the water pressure at the seabed. The objectives of this study were to observe buildup trend for the porewater pressures developed in near-field of open-ended pipe pile installed in the calibration chamber during the simulated earthquake and seaquake and, also to confirm the cause for reduction of soil plugging according to pore pressure buildup. During the simulated horizontal seismic motion, there was no upward flow through soil plug because the similar magnitude of excess porewater pressure were occurred at the top and under the toe of soil plug. During the horizontal seismic motion, relatively higher hydraulic gradients caused upward flow in the soil plug and then the degradation of plugging resistance was about 20%. During seaquake, in the case of the open-ended pile installed in a deep sea with more than 220m of water depth, soil plug failed completely because of high upward hydraulic gradients through soil plug.soil plug.

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Permeation Behavior of Semiconductor Rinsing Wastewater Containing Si Particles in Ultrafiltration System -II. Permeation Characteristics of Tubular Membrane (Si 입자를 함유한 반도체 세정폐수의 한외여과 특성 [II] -Polyolefin 관형막에 의한 투과분리-)

  • 남석태;여호택;전재홍;이석기;최호상
    • Membrane Journal
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    • v.9 no.1
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    • pp.36-42
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    • 1999
  • Permeation behavior of the semiconductor rinsing wastewater contammg Si particles was examined by ultrafiltration using the polyolefin tubular membrane. Flux decline with time was due to the growth of Si cake deposited on the membrane surface and the pore plugging by Si particles. Cake filtration from the cross flow application is compared to the combination of pore blocking and cake filtration from the dead-end application. The cake resistance is 3.16 x $10^{12}$ -4.34 X $\times$$10^{12}$ $m^{-1}$ for the cross flow and 6.6 x $\times$$10^{12}$ -12.19 X $\times$$10^{12}$ $\times$$m^{-1}$for the dead-end flow, respectively. At the initial stage of operation, permeation flux of cross flow type was 1.7 time higher than that of the dead end flow type. Permeation flux of cross flow was about 42 e 1m2 hr and the rejection rate of Si particles was about 96 %. The average particle size of Si particle in the permeate was 20 nm.

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A Study on the Characteristics of Activated Carbons Supported Metal by Microwave Irradiation (마이크로파 조사에 따른 금속이 담지 된 활성탄의 특성 연구)

  • Kim, Sung-Wook;Kim, Jung-Bae;Choi, Sung-Woo
    • Journal of Environmental Science International
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    • v.18 no.5
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    • pp.501-508
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    • 2009
  • In this study, the characteristics of granular activated carbon (GAC) supported metal was investigated in an area influenced by flame discharge and temperature variation during irradiating microwave. The modified GAC was formulated by impregnating metal hydroxides of nickel (Ni/GAC), barium (Ba/GAC), copper (Cu/GAC), zinc (Zn/GAC), cobalt (Co/GAC) and lanthanum (La/GAC). Ba/GAC was selected as it showed lack of spark discharge and temperature increasing aspects. Comparison of adsorption and desorption amount of GAC and Ba/GAC showed that adsorption and desorption rate of the GAC were higher than those of Ba/GAC. The results show that the presence of barium can decrease adsorption/desorption rate because of plugging pore of GAC. Toluene regeneration rate of Ba/GAC was better than that of GAC due to barium loading. Finally, GAC with barium can be controled a rapid increasing temperature and spark discharge, increased the regeneration rate of toluene during desorption by irradiating microwave.

Response of Soil Plug to Seaquake Induced by the Vertical Seismic Excitation (수직 지진 진동에 의해 유발된 해진에 대한 관내토의 거동)

  • 최용규
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 1998.04a
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    • pp.81-88
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    • 1998
  • During an earthquake, there are three main components of excitation : horizontal excitation of the ground, vertical excitation of the pile due to superstructure feedback produced by vertical excitation of the ground, and the seawater excitation induced by the vertical ground shaking, that is, "the seaquake." These excitations could have effects on the soil plugs in open-ended pipe piles installed at offshore sites. In this study, seaquake excitation induced by the vertical ground shaking was simulated by pulsing the water pressure at the seabed. During a seaquake, due to induced excess porewater pressure and pressure gradients in the soil, the capacity of open-ended pipe piles installed in a simulated sea depth of greater than 220 m was reduced serevely and the soil plugging resistance was degraded by more than 80%. The soil plug was failed because of the upward seepage forces that developed in the soil plug due to excess pore water pressure produced in the bottom of the soil plug during the seaquake. The compressive capacity of an open-ended pile in a simulated sea depth of less than 220m was reduced only by about 10%, and the soil plug resistance was degraded by less than 5%.s than 5%.

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Permeation Behavior of Semiconductor Rinsing Wastewater Containing Si Particles in Ultrafiltration System -I. Permeation Characteristics of Polysulfone Flat Plate Membrane- (Si 입자를 함유한 반도체 세정폐수의 한외여과 특성[I] -Polysulfone 평판막에 의한 투과분리-)

  • 곽순철;이석기;전재홍;남석태;최호상
    • Membrane Journal
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    • v.8 no.2
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    • pp.102-108
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    • 1998
  • Permeation behavior of the semiconductor rinsing wastewater containing Si particles was examined by ultrafiltration using the polysulfone plate membrane. The permeation flux was gradually decreased with time. It was due to the growth of cake deposited on the membrane surface and the pore plugging by Si particles. Permeation flux of cross flow type was 1.4 times higher than that of the dead end flow type. Nitrogen back flushing which is the removing method of membrane fouling was superior to the water sweeping. With nitrogen back flushing, the decrease of permeation flux due to the fouling was recovered about 85 % to the initial flux in the flat plate membrane system. The rejection rate of Si particles was about 90 % and the size of Si particle in the permeate was about 70 nm.

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Effects of Different Precursors on the Surface Mn Species Over $MnO_x/TiO_2$ for Low-temperature SCR of NOx with $NH_3$

  • Kim, Jang-Hoon;Yoon, Sang-Hyun;Lee, Hee-Soo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.29.1-29.1
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    • 2011
  • The selective catalytic reduction (SCR) of $MnO_x$ with $NH_3$ is an effective method for the removal of $MnO_x$ from stationary system. The typical catalyst for this method is $V_2O_5-WO_3(MoO_3)/TiO_2$, caused by the high activity and stability. However, This catalyst is active within $300{\sim}400^{\circ}C$ and occurs the pore plugging from the deposition of ammonium sulfate salts on the catalysts surface. It needs to locate the SCR unit after the desulfurizer and electrostatic precipitator without reheating of the flue gas as well as deposition of dust on the catalyst. The manganese oxides supported on titania catalysts have attracted interest because of its high SCR activity at low temperature. The catalytic activity of $MnO_x/TiO_2$ SCR catalyst with different manganese precursors have investigated for low-temperature SCR in terms of structural, morphological, and physico-chemical analyses. The $MnO_x/TiO_2$ were prepared from three different precursors such as manganese nitrate, manganese acetate (II), and manganese acetate (III) by the sol-gel method and then it calcinated at $500^{\circ}C$ for 2 hr. The structural analysis was carried out to identify the phase transition and the change intensity of catalytic activity by various manganese precursors was analyzed by FT-IR and Raman spectroscopy. These different precursors also led to various surface Mn concentrations indicated by SEM. The Mn acetate (III) tends to be more suppressive the crystalline phase (rutile), and it has not only smaller particle size, but also better distributed than the others. It was confirmed that the catalytic activity of MA (III)-$MnO_x/TiO_2$ was the highest among them.

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