• Title/Summary/Keyword: pore plugging

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A Study of Hydrodemetallation of VO-TPP over CoMo/γ-Al2O3 Catalyst (CoMo/γ-Al2O3촉매상에서 VO-TPP의 수소 첨가 탈금속반응에 관한 연구)

  • Shim, Hyeon-Seop;Park, Hea-Kyung;Ko, Eul-Suk;Kim, Kyung-Lim
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.701-708
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    • 1993
  • Hydrodemetallation(HDM) of VO-tetraphenylporphyrin(VO-TPP) was studied over $CoMo/{\gamma}-Al_2O_3$ catalyst at emperatures between $300^{\circ}C$ and $400^{\circ}C$, the total pressure between $15{\times}10^5$ and $30{\times}10^5$ Pa and the contact times between 0.008 and 0.020gcat. hr./ml teed. HDM of VO-TPP was inhibited by pyridine because the increase of pyridine concentration(up to 4mole%) caused the decrease of HDM conversion. The reaction rate of VO-TPP was found to be apparently 1st order over $350^{\circ}C$ and its activation energy was determined to be about 23kca1/mo1e by Arrhenius plot. Pore mouth-plugging phenomena were shown by ad/desorption isotherm and pore size distribution of fresh and aged catalysts.

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Hydrogen Permeance of Silica Membrane Prepared by Chemical Vapor Deposition Method on an $\alpha$-Alumina Support Tube (기상 화학증착법에 의해 $\alpha$-Alumina 지지관 상에 제조한 Silica막의 수소투과 특성)

  • 김성수;이재홍;서동수;박상욱;서봉국
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.669-677
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    • 1998
  • A porous $\alpha$-alumina tube of 2.5 mm O.D. and 1.9 mm I.D. was used as the support of an inorganic membrane. Macropores of the tube, about 150 nm in size, were plugged with silica formed by thermal decomposition of tetraethylorthosilicate at $600^{\circ}C$. The forced cross-flow CVD method that reactant was evacuated through the porous wall of the support was very effective in plugging macropores. The H$_2$ permeance of the prepared membrane was of the order of $10^{-8}/ molㆍs^{-1}/ㆍm^{-2}/. Pa{-1}$/, while the $N_2$ permeance was below $10^{-11}/ molㆍs^{-1}/ㆍm^{-2}/ㆍPa^{-1}$/ at $600^{\circ}C$. This was comparable to that of silica-modified Vycor glass whose size was 4 nm.

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Reduction of Hydraulic Conductivity by Soil Injection of Bacteria (Bacteria 토양주입을 통한 투수계수 감소)

  • 송영우;김건하;구동영
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.03b
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    • pp.331-337
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    • 2000
  • When microorganism is injected into porous medium such as soils, biomass retained in the pore. Bacteria within these microcolonies produced large amounts of exopolysaccharides and formed a plugging biofilm. Soil pore size and shape are varied from the initial condition as a result of biofilm formation, which make hydraulic conductivity reduced and friction rate between soil aggregates increased. In this research, hydraulic conductivity reduction was measured after microorganism are inoculated and cultured with synthetic substrate and nutrient. Also, pore sand of before and after biofilm formation compared with scanning electron microscopy. Hydraulic conductivity of Sand and Poorly Graded Sand was decreased approximately 1/10∼1/100 after biomass inoculation and cultivation. Biofilm attached on soil aggregates is resistant to acidic or basic condition.

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Permeation Characteristics of Wastewater Containing Si Fine Particles through Ultrafiltration

  • Park, Ho-Sang;Park, Young-Tae;Lee, Seok-Ki
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.31-35
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    • 2003
  • The permeation characteristics of the wastewater containing Si fine particles were examined by ultrafiltration using the polyolefin tubular membrane module. Flux with time was due to the growth of Si cake deposited on the membrane surface and the pore plugging by fine particles. The rate of flux decline in the initial stage increased with the trans-membrane pressure. The pore blocking resistance was the dominant resistance at the initial period of filtration and the cake resistance began to dominate with the initial pore blocking resistance. The larger pores compared with the fine particles, the more the membrane pores could be blocked by the fine particles. Before and after treatment, the distribution of particle size was shifted toward to the left. Then, the average size of fine particles in the permeate was 20 nm.

Pore structure evolution characteristics of sandstone uranium ore during acid leaching

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Zhang, Ni;Zhang, Shuwen;Feng, Song
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.4033-4041
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    • 2021
  • To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.

Application of the H Infinity Control Principle to the Sodium Ion Selective Gating Channel on Biological Excitable Membranes

  • Hirayama, Hirohumi
    • International Journal of Control, Automation, and Systems
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    • v.2 no.1
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    • pp.23-38
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    • 2004
  • We proposed the infinity control principle to evaluate the Biological function. The H infinity control was applied to the Sodium (Na) ion selective gating channel on the excitable cellular membrane of the neural system. The channel opening, closing and inactivation processes were expressed by movements of three gates and one inactivation blocking particle in the channel pore. The rate constants of the channel state transition were set to be voltage dependent. The temporal changes in amounts per unit membrane area of the channel states were expressed by means of eight differential equations. The biochemical mimetic used to complete the Na ion selective channel was regarded as noise. The control inputs for ejecting the blocking particle with plugging in the channel pore were set for the active transition from inactivated states to a closed or open state. By applying the H infinity control, we computed temporal changes in the channel states, observers, control inputs and the worst case noises. The present paper will be available for evaluating the noise filtering function of the biological signal transmission system.

Inhibition of Rebar Corrosion by Carbonate and Molybdate Anions

  • Tan, Y.T.;Wijesinghe, S.L.;Blackwood, D.J.
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.167-174
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    • 2017
  • Bicarbonate/carbonate and molybdate anions have been characterized for their inhibitive effect on pitting corrosion of carbon steel in simulated concrete pore solution by using electrochemical tests such as electrochemical impedance (EIS) and linear polarization (LP). It was revealed that bicarbonate/carbonate has a weak inhibitive effect on pitting corrosion that is approximately one order of magnitude lower compared to hydroxide. Molybdate is effective against pitting corrosion induced by the concentration of chloride as low as 113 mM and can increase the pitting potential of a previously pitted sample to the oxygen evolution potential by the concentration of molybdate as much as 14.6 mM only. The formation of a $CaMoO_4$ film on the surface hinders the reduction of dissolved oxygen on the steel surface, reducing corrosion potential and increasing the safety margin between corrosion potential and pitting potential further. In addition, pore-plugging by $FeMoO_4$ as a type of salt film within pits increases the likelihood of repassivation.

Ablative Properties of 4D Carbon/Carbon Composites by Combustion Test

  • Park, Jong-Min;Ahn, Chong-Jin;Joo, Hyeok-Jong
    • Carbon letters
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    • v.9 no.4
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    • pp.316-323
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    • 2008
  • The factors that influence ablation resistance in fiber composites are properties of the reinforced fiber and matrix, plugging quantity of fiber, geometrical arrangement, crack, pore size, and their distributions. To examine ablation resistance according to distribution of crack and pore size that exist in carbon/carbon composites, this study produced various sizes of unit cells of preforms. They were densified using high pressure impregnation and carbonization process. Reinforced fiber is PAN based carbon fiber and composites were heat-treated up to $2800^{\circ}C$. The finally acquired density of carbon/carbon composites reached more than $1.932\;g/cm^3$. The ablation test was performed by a solid propellant rocket engine. The erosion rate of samples is below 0.0286 mm/s. In conclusion, in terms of ablation properties, the higher degree of graphitization is, the more fibers that are arranged vertically to the direction of combustion flame are, and the less interface between reinforced fiber bundle and matrix is, the better ablation resistance is shown.