• 제목/요약/키워드: pore evolution

검색결과 79건 처리시간 0.023초

Impedance Spectroscopy Analysis of Hydration in Ordinary Portland Cements Involving Chemical Mechanical Planarization Slurry

  • Hwang, Jin-Ha
    • 한국세라믹학회지
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    • 제49권3호
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    • pp.260-265
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    • 2012
  • Impedance spectroscopy was used to monitor the hydration in the electrical/dielectric behaviors of chemical mechanical planarization (CMP)-blended cement mixtures. The electrical responses were analyzed using their equivalent circuit models, leading to the separation of the bulk and electrode based responses. The role of the CMP slurry was monitored as a function of the relative compositions of the CMP-blended cements, i.e. water, CMP slurry, and ordinary Portland cement. The presence of $Al_2O_3$ nanocrystals in the CMP slurries appeared to accelerate the hydration process, along with a more tortuous microstructure in the hydration, with enhanced hydration products. The frequency-dependent impedance spectroscopy was proven to be a highly efficient approach for evaluating the electrical/dielectric monitoring of the change in the pore structure evolution that occurs in CMP-blended cements.

국내 양식 지렁이 Eisenia andrei와 Perionyx excavatus의 구분 (Identity of Two Earthworms Used in Vermiculture and Vermicomposting in Korea:Eisenia andrei and Perionyx excavatus)

  • Yong Hong;Kim, Tae-Heung;Na, Young-Eun
    • Animal Systematics, Evolution and Diversity
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    • 제17권2호
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    • pp.185-190
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    • 2001
  • 양식 지렁이 붉은줄지렁이(Eisenia andrei)와 팔딱지렁이(Perionyx excavatus) 2종에 대한 기재를 하으며, 이 2종에 대한 국내에서 분류학적 기록은 처음이다. 붉은지렁이는 뚜렷한 가로줄무늬가 없으며, 파딱이지렁이는 환대는 13-17마디이다.

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하이드레이트 함유 퇴적물의 역학적 성질 및 지구물리 특성 (Mechanical and Electrical Properties of Hydrate-bearing Sediments)

  • 이주용
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.594-596
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    • 2007
  • Using an oedometer cell instrumented to measure the evolution of electromagnetic properties, small strain stiffness, and temperature, we conducted consolidation tests on four types of sediments. The tested specimens include sediments with different gas hydrate saturation at four stages of loading. The test results show that the electromagnetic and mechanical properties of hydrate-bearing marine sediments are governed by the vertical effective stress, stress history, porosity, hydrate saturation, fabric, ionic concentration of the pore fluid, and temperature. The results also show that permittivity and electrical conductivity data can be combined to estimate hydrate volume fraction in laboratory sediments, methodology that might eventually be extended for estimation of hydrate concentrations in field settings.

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Effects of nanomaterials on hydration reaction, microstructure and mechanical characteristics of cementitious nanocomposites: A review

  • Kim, Gwang Mok
    • 도시과학
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    • 제9권1호
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    • pp.7-16
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    • 2020
  • Application of nanomaterials to cementitious composites has been attempted with the rapid development of nanotechnology since the 1990s. Various nanomaterials such as carbon nanotube, graphene, nano-SiO2, nano-TiO2, nano-Al2O3, nano-Clay, and nano-Magnetite have been applied to cementitious composites to improve the mechanical properties and the durability, and to impart a variety of functionality. In-depth information on the effect of nanomaterials on the hydration reaction, the microstructure, and the mechanical properties of cementitious nanocomposites is provided in the present study. Specifically, this paper mostly deals with the previous studies on the heat evolution characteristics of cementitious nanomaterials at an early age of curing, and the pore and the compressive strength characteristics of cementitious nanocomposites. Furthermore, the effect of nanomaterials on the cementitious nanocomposites was systematically discussed with the reviews.

A New Species of the Genus Pithemera (Oligochaeta: Megascolecidae) from Namat NBCA, Laos

  • Hong, Yong;James, Samuel W.;Inkhavilay, Khamla
    • Animal Systematics, Evolution and Diversity
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    • 제24권2호
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    • pp.161-164
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    • 2008
  • As a result of a taxonomic study on the earthworm material collected from Namat National Biodiversity Conservation Area (NBCA), Hoaphane Province, Laos, a new species, Pithemera viengthongensis sp. novo is described from near Namchong river, Viengthong district. The new species bearing two pairs of spermathecal pores in 7/8, 8/9 is not assignable to any other species of Pithemera as defined by Sims and Easton (1972). In the new species, the male pore region has kidney-shaped pads extending between XVII-19/20, the male pores and spermathecal pores are 0.31 circumference apart, and genital papillae are lacking. The ventral view of anterior body region and the spermathecae are illustrated.

물리화학적 활성법이 다공성 탄소의 기공발현에 미치는 영향 (Effect of Physical/Chemical Activation on the Porosity Evolution of Porous Carbons)

  • Park, Yun-Heum;Park, Chong-Rae;Park, Chong-Rae;Oh, Gyu-Hwan
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.303-305
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    • 2001
  • Porous carbons have beef used as adsorbents, filters, catalyst supports, etc. due to well-development pore structure. Porous carbons can be prepared by two different activation processes i.e. physical activation by steam or CO$_2$, and chemical activation by KOH, H$_3$PO$_4$ etc. from various raw material. Recently, agricultural wastes such as rice hulls [1], coconut shell [2-31 and straws [4] are growing interest as precursors fur porous carbons due to its easy availability and cheapness. (omitted)

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A survey on the application of oxide nanoparticles for improving concrete processing

  • Khayati, Gholam Reza;Ghasabe, Hojat Mirzaei;Karfarma, Masoud
    • Advances in concrete construction
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    • 제3권2호
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    • pp.145-159
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    • 2015
  • The evolution of nanotechnology provides materials with advance properties. It's a fast growing area of research to introduce the oxide nanoparticles into the cement pastes to improve their performance. The purpose of this paper is to review the effects of oxide nanoparticles (such as $SiO_2$, $TiO_2$, $Fe_2O_3$, $ZnO_2$, $Cr_2O_3$ and $Al_2O_3$) on both of hardened concrete properties (i.e., compressive strength, split tensile strength and flexural strength, water permeability, Abrasion resistance and pore structure of concrete) and fresh concrete properties (i.e., workability and setting time). Graphical representations of all these parameters were presented to facilitate the comparison of the effect of oxide nanoparticles on concrete processing. The paper also introduces some discussion about future work in this direction by identifying some open research area.

알코홀 증류폐액의 Pilot Scale 정밀여과와 여과액의 발효 재활용에 대한 연구 (A Pilot Study for Microfiltration of Alcohol Stillage Condensate and Permeate Recycle to Fermentation Broth)

  • 김영범;이기세;남궁견;김종현
    • KSBB Journal
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    • 제16권4호
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    • pp.403-408
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    • 2001
  • 알코홀 증류폐액은 통상적으로 COD 50,000-60,000 ppm, TS 3-8%, SS 2-4%, TN 0.05-0.2% 정도가 포함되어 있어 높은 SS와 TN 함량 때문에 종합폐수로써 생물학적 처리를 하거나 혐기성 소화를 통하여 처리하는 데 문제가 있다. SS의 주성분으로는 미발효 원료 잔류물과 함께 균체, 단백질, 섬유질, 그리고 기타 현탁성 또는 용해성 물질들이 포함된다. 본 연구에서는 알코홀 증류폐액 처리의 한 해결책으로써 0.1 $\mu$m Pore size를 갖는 스테인레스 재질의 분리막을 이용한 pilot scale 정밀여과(microfiltration)를 실시하였다. Decanter로 처리된 증류폐액을 정밀여과 처리한 결과 2.5 bar, 6$0^{\circ}C$ 조건에서 VCR 농축도 10X 정도가지 원활한 permeate flux를 얻으며 24시간 이상 장시간 여과가 가능하였고 feed 중 0.7%였던 SS가 100% 가까이 제거된 permeate를 얻을 수 있었다. SS는 retentate 중에 7%까지 농축 가능하였으며 COD는 25-27% 정도 제거되었다. SS가 2.6%인 decanter를 거치지 않은 증류 원폐액의 경우, VCR 3X 이내의 조건으로 여과할 때 SS를 100% 가까이 그리고 COD는 약 50% 정도 제거 가능하였다. 무방류 시스템으로의 전용을 위하여 정밀여과로 얻어진 permeate와 retentate를 발효배지 사입수으로 재활용하여 알코홀 발효에 미치는 영향을 검토한 결과, 재활용 사입수를 사용하지 않은 경우에 비해 발효 도중 이상 현상이나 발효속도와 알코홀 생산량에 부정적인 영향을 미치는 징후는 발견되지 않았다. 발효에 의한 총 $CO_2$ 발생량과 최종 알코홀 함량은 약간 증가하고 큰 차이를 보이지 않았으나, 발효시간 동안의 $CO_2$ 발생속도는 비교적 빨라져서 $CO_2$ 발생량 450 L/ton에 도달하는 시간은 재활용 사입수를 15% 사용했을 때 83-87%, 30%를 사용했을 때 72-76% 정도 단축되는 효과를 얻었다. 증류폐액을 처리하기 위해 사용되는 기존 decanter를 대체하여 정밀여과 막분리장치를 이용한다면 SS가 완벽하게 제거됨으로써 폐수처리의 부하를 줄이는 한편 부가적인 농축 공정을 줄일 수 있을 것으로 기대된다. 또한 여과 permeate를 발효배지 사입수로 재활용함으로써 발효속도를 증진시킬 수 있으며 용수사용량을 절약할 수 있다.

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태백산분지 (백운산 향사대) 장성지역에 분포하는 하부페름기 장성층의 고지온 (Paleotemperatire of the Lower Permian Jangseong Formation, jangseong Area, Taebaegsan Basin (Baegunsan Synclin))

  • 유인창
    • 자원환경지질
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    • 제32권3호
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    • pp.293-306
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    • 1999
  • The lower Permian jungseong Formation, Taebaegsan basin (Baegunsan Syncline), represents a coal-bearing siliciclastic succession which was later modified by the Songrim or Dabo orogeny. Sandstone perography and clay mineralogy were studied to understand the thermal history of the Jangseong Formation during basin evolution. Petrographic study indicates the Jangseong sandstones are composed of quartz, feldspar, lithic fragments (metamorphic and sedimetary), and varying proportions of matrix and cement. The dominance of quartz(<97%) over feldspar (<1%) and lithic fragments (<2%) classifies most Jangseong sandstones as quartz arenotes or quartzwackes, but lithic graywackes and sublithic arenite locally occur. The diagentic features of these sandstones include mechanical compaction, cemenation by quartz and clay minerals indentified in the Jangseong Formation by X-ray diffraction analysis are late-stage clay pore-filling. Clay minerals isdentified in the Jangseong Formation by X-ray diffaction analysis are illite, kaolinte, and pyrophyllite with a minor amount of chlorite and micas. The illite, kaolinite, and pyrophyllite appear to be largely autjigenic based on their well-crystallinity forms. There authigenic clay minerals form clay minerals form clay coats/rims and late-stage pore-filling cements, Illitecrystallinity shows that the Jangseong formation has been in late-diagenetic zone to early-epizone, which ranges in temperature from $200^{\circ}C$ to $300^{\circ}C$. In assition, kaolinite-pyrophyllite transition suggests that paleotemperature of the formation has reached at least $265^{\circ}C$. Such temperatureis likely to be consistent with homogenixation temperatures of fluid inclusions in quartz veins in the formation. Thus, the Jangseong Formation has been subjected to paleotemperature of about $265^{\circ}C$. The major heat source responsible for paleotemperature may be hydrothermal solutions. The passage of hydrothermal solutions was probably assisted by fractures created during the basin-modifying tectonism of the taebaegsan basin.

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나노 구조를 가지는 다공성 주석 산화물의 전기화학적 특성 (Electrochemical Characterization of Anodic Tin Oxides with Nano-Porous Structure)

  • 이재욱;박수진;신헌철
    • 한국재료학회지
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    • 제21권1호
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    • pp.21-27
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    • 2011
  • A nano-porous structure of tin oxide was prepared using an anodic oxidation process and the sample's electrochemical properties were evaluated for application as an anode in a rechargeable lithium battery. Microscopic images of the as-anodized sample indicated that it has a nano-porous structure with an average pore size of several tens of nanometers and a pore wall size of about 10 nanometers; the structural/compositional analyses proved that it is amorphous stannous oxide (SnO). The powder form of the as-anodized specimen was satisfactorily lithiated and delithiated as the anode in a lithium battery. Furthermore, it showed high initial reversible capacity and superior rate performance when compared to previous fabrication attempts. Its excellent electrode performance is probably due to the effective alleviation of strain arising from a cycling-induced large volume change and the short diffusion length of lithium through the nano-structured sample. To further enhance the rate performance, the attempt was made to create porous tin oxide film on copper substrate by anodizing the electrodeposited tin. Nevertheless, the full anodization of tin film on a copper substrate led to the mechanical disintegration of the anodic tin oxide, due most likely to the vigorous gas evolution and the surface oxidation of copper substrate. The adhesion of anodic tin oxide to the substrate, together with the initial reversibility and cycling stability, needs to be further improved for its application to high-power electrode materials in lithium batteries.