• Title/Summary/Keyword: pore distribution

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A model to characterize the effect of particle size of fly ash on the mechanical properties of concrete by the grey multiple linear regression

  • Cui, Yunpeng;Liu, Jun;Wang, Licheng;Liu, Runqing;Pang, Bo
    • Computers and Concrete
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    • v.26 no.2
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    • pp.175-183
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    • 2020
  • Fly ash has become an important component of concrete as supplementary cementitious material with the development of concrete technology. To make use of fly ash efficiently, four types of fly ash with particle size distributions that are in conformity with four functions, namely, S.Tsivilis, Andersen, Normal and F distribution, respectively, were prepared. The four particle size distributions as functions of the strength and pore structure of concrete were thereafter constructed and investigated. The results showed that the compressive and flexural strength of concrete with the fly ash that conforming to S.Tsivilis, Normal, F distribution increased by 5-10 MPa and 1-2 MPa, respectively, compared to the reference sample at 28 d. The pore structure of the concrete was improved, in which the total porosity of concrete decreased by 2-5% at 28 d. With regarding to the fly ash with Andersen distribution, it was however not conducive to the strength development of concrete. Regression model based on the grey multiple linear regression theory was proved to be efficient to predict the strength of concrete, according to the characteristic parameters of particle size and pore structure of the fly ash.

Comparison of Soil Pore Properties between Anthropogenic and Natural Paddy Field Soils From Computed Tomographic Images

  • Chun, Hyen Chung;Jung, Ki-Yuol;Choi, Young Dae;Jo, Su-min;Lee, Sanghun;Hyun, Byung-Keun;Shin, Kooksik;Sonn, Yeonkyu;Kang, Hang-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.5
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    • pp.351-360
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    • 2015
  • Human influence on soil formation has dramatically increased with human civilization and industry development. Increase of anthropogenic soils induced researches on the anthropogenic soils; classification, chemical and physical characteristics of anthropogenic soils and plant growth from anthropogenic soils. However there have been no comprehensive analyses on soil pore or physical properties of anthropogenic soils from 3 dimensional images in Korea. The objectives of this study were to characterize physical properties of anthropogenic paddy field soils by depth and to find differences between natural and anthropogenic paddy field soils. Soil samples were taken from two anthropogenic and natural paddy field soils; anthropogenic (A_c) and natural (N_c) paddy soils with topsoil of coarse texture and anthropogenic (A_f) and natural (N_f) paddy soils with topsoil of fine texture. The anthropogenic paddy fields were reestablished during the Arable Land Remodeling Project from 2011 to 2012 and continued rice farming after the project. Natural paddy fields had no artificial changes or disturbance in soil layers up to 1m depth. Samples were taken at three different depths and analyzed for routine physical properties (texture, bulk density, etc.) and pore properties with computer tomography (CT) scans. The CT scan provided 3 dimensional images at resolution of 0.01 mm to calculate pore radius size, length, and tortuosity of soil pores. Fractal and configuration entropy analyses were applied to quantify pore structure and analyze spatial distribution of pores within soil images. The results of measured physical properties showed no clear trend or significant differences across depths or sites from all samples, except the properties from topsoils. The results of pore morphology and spatial distribution analyses provided detailed information of pores affected by human influences. Pore length and size showed significant decrease in anthropogenic soils. Especially, pores of A_c had great decrease in length compared to N_c. Fractal and entropy analyses showed clear changes of pore distributions across sites. The topsoil layer of A_c showed more degradation of pore structure than that of N_c, while pores of A_f topsoil did not show significant degradation compared with those of N_f. These results concluded that anthropogenic soils with coarse texture may have more effects on pore properties than ones with fine texture. The reestablished paddy fields may need more fundamental remediation to improve physical conditions.

Preparation of Nanoporous Silica Particles containing Various Pore Sizes from Silicic Acid by Spray Pyrolysis (분무열분해 공정에 의한 규산수용액으로부터 다양한 미세기공을 갖는 실리카 나노다공체 제조)

  • Kim, Sun Kyung;Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.3
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    • pp.65-72
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    • 2016
  • Nanoporous $SiO_2$ particles containing different pore volume and size were prepared from silicic acid by a spray pyrolysis. The pore size, pore volume and particle size could be controlled with varying the precursor concentration, reaction temperature, and amount of organic templates such as Urea and poly ethylene glycol (PEG). The pore size distribution, pore volume and specific surface area of as-prepared particles were analyzed by BET and BJH methods, and the average particle sizes were measured by a laser diffraction method. The nanoporous $SiO_2$ particles ranged $0.6-0.9{\mu}m$ in diameter were successfully synthesized and the average particle size increased as the silicic acid concentration increased. The morphology of nanoporous $SiO_2$ particles was spherical and pores ranged 1 - 40 nm in diameter were measured in the particles. In case of Urea added into silicic acid, it showed no much difference in the morphology, pore size and pore volume at different Urea concentration. On the other hand, when PEG was added, it was clearly observed that pore diameter and pore volume of the particles surface increased with respect to PEG concentration.

Estimation of Water Retention Characteristics Using Lognormal Distribution Model (로그분포모형을 이용한 토양수분특성 추정)

  • Sang Il Hwang
    • Journal of Soil and Groundwater Environment
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    • v.8 no.4
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    • pp.21-26
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    • 2003
  • Hwang and Powers (2003) developed a simple model for estimating water retention characteristic (WRC) directly from particle-size distribution (PSD) data, by applying a lognormal distribution law to both PSD and pore-size distribution. The objective of this work was to determine if the performance of the model developed by Hwang and Powers (2003) would be affected by soil texture. The results of this research proved that the performance of the model was indeed affected by soil texture. In particular, its performance diminished with increases in the fine particle fractions. Also, the nonlinear model, which assumes a nonlinear relation between particle-size and pore-size, performed better than the linear model, regardless of soil texture classes.

Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
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    • v.4 no.2
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    • pp.157-166
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    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

Influence of the Quality of Recycled Aggregates on Microstructures and Strength Development of Concrete

  • Moon Dae-Joong;Moon Han-Young;Kim Yang-Bae
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.875-881
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    • 2004
  • The quality of recycled aggregate is affected by original concrete strength and the manufacturing process of recycled aggregates. In this study, the porosity of old and new mortar, and the compressive strength of concrete were investigated to examine the influence of recycled aggregate on the concrete. Six kinds of recycled coarse aggregates were produced from concrete blocks of differing strength levels (A:60. 1MPa, B:41.7MPa, C:25.5MPa). Original concrete strength and the bond mortar of recycled aggregate influences the pore structures of both old and new mortar. The pore size distribution of old mortar was found to be greatly affected by age, and the reduction of the porosity of bond mortar on low strength recycled aggregate increased at a greater rate than that of bond mortar on high strength recycled aggregate. The pore size distribution of new mortar in recycled aggregate concrete changed in comparison with that of new mortar in virgin aggregate concrete. The total porosity of new mortar using B level recycled aggregates was smaller than that of new mortar with A, and C level recycled aggregates. Moreover, the compressive strength of recycled aggregate concrete was found to have been affected by original concrete strength. The compressive strength of concrete only changed slightly in the porosity of new mortar over $15\%$, but increased rapidly in the porosity of new mortar fewer than $15\%$.

Effects of Porosity on Durability in a Porous Nozzle for Continuous Casting (연속주조용 Porous Nozzle의 기공율이 내구성에 미치는 영향)

  • Yoon, Sanghyeon;Cho, Mun-Kyu;Jeong, Doo Hoa;Lee, Heesoo
    • Korean Journal of Metals and Materials
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    • v.48 no.7
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    • pp.625-629
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    • 2010
  • This study investigates the effects of porosity on the thermal stability and the thermal shock resistance of a porous nozzle used for blowing an inert gas. The samples of $Al_2O_3-SiO_2-ZrO_2$ system, which had the apparent porosity of 16~30% and bulk density of $2.6{\sim}3.2g/cm^3$, were prepared by adding different graphite contents (5, 10, 20 wt%) as a pore-forming agent. The thermal shock test was conducted at ${\Delta}T=500$, 1000, and $1400^{\circ}C$ also and the thermal stability was also carried out at 1550, 1600, and $1650^{\circ}C$ for 5 hrs. The specimen contained 10 wt% graphite had uniform pore size distribution, whereas the specimen with 20 wt% graphite showed non-uniform pore size distribution. As a result of thermal shock test, the specimen containing 10 wt% graphite appears to have higher mechanical strength than the other specimens (5, 20 wt% graphite). Both the 5 wt% and 20 wt% graphite specimens developed a non-uniform pore size distribution and cracks that were generated by intensive thermal stress.

Pore Size and Distribution of Polyester Fabrics Determined by Liquid Extraction Method (액체유출법에 의한 폴리에스테르 직물의 기공 크기 및 분포 측정)

  • Lee, Dong-Hwa;Yeo, Suk-Yeong;Kim, Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.1
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    • pp.206-216
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    • 1997
  • The purpose of this study was to determine the pore size distributions (PSDs) of polyester woven fabrics by using liquid extraction method. Three types of PSDs-percent PSD, PSD per unit area of sample and PSD per unit weight of sample-were evaluated. Plain, twill and satin polyester fabrics with various fabric counts were used as specimens. Results showed that the interyarn PSDs reflected the fabric characteristics such as the fabric count and the weave type and the intrayarn PSDs reflected the thread characteristics such as the number of fibers, the fiber diameter, the thread diameter and the thread twist. Of three types of PSDs, the PSD per unit area of sample best reflect fabric and thread characteritics. As the fabric count decreased, rc increased and interyarn pore volume increased. The PSDs were skewed to the small pore sizes and the pore volumes decreased in the order of plain> twill> satin. As the number of fibers, the fiber diameter and the thread twist decreased, the intrayarn pore volumes were increased.

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Investigation on Relationship Between Pore Structure of Coating Layer and Ink Residual Behavior - Focused on the Effect of Pigments and Inks - (도공층의 공극성이 인쇄후 잉크의 잔류 거동에 미치는 영향 - 안료와 잉크의 효과 -)

  • 김병수;정현채;박종열
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.53-58
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    • 2002
  • This paper was performed to investigate the effect of pore structure on ink residual behavior. To prepare different coating structures as substrates against inks, fine, medium and coarse calcium carbonate were used in the coating color. It is well known ink properties can affect to print qualities. After printing on the coated paper, ink layer can consider as third structure addition to paper and coating layer. To compare effect of ink properties on the surface structure and print qualities, several properties of ink were also adopted as raw material. Particle size of pigment effect on gloss evaluation of coated paper increased with calendering. It was shown that ink transfer rate increased as surface of the sample was smooth. The ink contained low viscosity resin evaluated more print gloss. Finer pigment particle size, smaller pore size and higher porosity. Pore volume of coated paper was slightly decreased with printing as the coating was prepared with the finest particle size. However, it founded that ink resin could not affect on pore volume and distribution of printed paper

The Porosity and the Dyeability of Polyester Fiber Treated with Sodium Hydroxide Aqueous Solution (알칼리 감량 폴리에스테르 섬유의 기공도와 염색성)

  • 김병인;김태경;임용진;조광호;조규민
    • Textile Coloration and Finishing
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    • v.12 no.6
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    • pp.380-388
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    • 2000
  • The porosity of polyester fibers treated with sodium hydroxide aqueous solution was investigated using a nitrogen porosimeter, and the dyeability of the treated fibers was discussed in terms of the porosity. In pore distribution, the polyester fibers treated with sodium hydroxide aqueous solution were characterized by higher amount of pores below $10\AA$ than those of the untreated fibers, and by shift of the pore size having maximum accumulated volume from $10\AA$ for the untreated fibers to $5~6\AA$. As the weight loss of the polyester fibers treated with sodium hydroxide aqueous solution increased, BET surface area and total pore volume increased linearly, but average pore size, showing some different aspect, increased steeply at earlier stage and then approached the maximum value. The dye uptakes of the polyester fibers treated with sodium hydroxide aqueous solution increased with the BET surface area, the total pore volume and the average pore size. The alkali treatment increased the surface area of polyester fibers, so that the chance of contact between the fiber and dye molecules increased. In addition, the pores created on the surface of polyester fibers by alkali treatment might act as pathways for dye molecules into the polyester fibers.

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