• 한국입자에어로졸학회지
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• 제12권3호
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• pp.65-72
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• 2016

Nanoporous $SiO_2$ particles containing different pore volume and size were prepared from silicic acid by a spray pyrolysis. The pore size, pore volume and particle size could be controlled with varying the precursor concentration, reaction temperature, and amount of organic templates such as Urea and poly ethylene glycol (PEG). The pore size distribution, pore volume and specific surface area of as-prepared particles were analyzed by BET and BJH methods, and the average particle sizes were measured by a laser diffraction method. The nanoporous $SiO_2$ particles ranged $0.6-0.9{\mu}m$ in diameter were successfully synthesized and the average particle size increased as the silicic acid concentration increased. The morphology of nanoporous $SiO_2$ particles was spherical and pores ranged 1 - 40 nm in diameter were measured in the particles. In case of Urea added into silicic acid, it showed no much difference in the morphology, pore size and pore volume at different Urea concentration. On the other hand, when PEG was added, it was clearly observed that pore diameter and pore volume of the particles surface increased with respect to PEG concentration.

• 한국세라믹학회지
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• 제25권3호
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• pp.217-224
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• 1988

Alkoxide 법으로 합성한 알루미나의 동공 구조를 BET 법으로 구한 흡 탈착 등온선의 hysteresis loop와 동공 분포로부터 고찰하였다. 알루미나는 aluminum isopropoxide를 화학량의 물로 가수분해하여 제조하였고, 가수분해 온도는 3$^{\circ}C$와 8$0^{\circ}C$에서 수행하였다. 이어 20$0^{\circ}C$부터 50$0^{\circ}C$까지 단계적으로 승온시키며 일정시간 열처리하였다. 3$^{\circ}C$ 가수분해 시료의 동공부피는 열처리 온도에 비례하여 증가하였으며, 동공크기는 쌍입분포(twin peaked pore size distribution)형으로 나타났다. 그러나 8$0^{\circ}C$ 가수분해 시료는 열처리에 의하여 동공부피가 감소하고, 동공크기는 단입분포(single peaked pore size distribution)로 나타났다. 이러한 관찰 결과로부터 전자의 동공형태는 slit형, 후자는 ink-bottle형을 하고 있는 것으로 추정되었다. 이와 같이 가수분해 온도는 동공 형태를 결정하는 중요한 인자일 뿐만 아니라, 층상 알루미나의 구조수 일탈 거동을 결정하는데 중요하다. 열처리 효과는 단지 최종 제품의 동공 분포를 결정하는데 영향을 주고 있는 것으로 해석되었다.

• 한국입자에어로졸학회지
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• 제8권2호
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• pp.89-95
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• 2012

Spherical mesoporous silica particles, of which main pore diameter was 3.8 nm, were successfully prepared by spray pyrolysis from aqueous silicic acid. The effect of precursor concentration, reaction temperature, and the addition of urea and PEG on the particle diameter and pore properties such as pore diameter, total pore volume, and specific surface area were investigated by using FE-SEM, particle size analyzer, and nitrogen absorption-desorption analysis. With an increase of the precursor concentration from 0.2 M to 0.7 M, the average particle diameter, total pore volume, and specific surface area of the porous silica particles increased from 0.56 to $0.96\;{\mu}m$, 0.434 to $0.486\;cm^3/g$, 467.8 to $610.4\;m^2/g$, respectively. Within the temperature range $(600\;^{\circ}C{\sim}800\;^{\circ}C)$, there was no significant difference in the pore diameter, total pore volume, and specific surface area. In addition, the addition of urea as an expansion aid led to slight increases in particle diameter, pore diameter, and specific surface area. However, when the polyethylene glycol (PEG) as an organic template was used, the total pore volume of porous particles increased dramatically.

• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.388-395
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• 2018

Significant efforts have been applied toward fabricating three-dimensional (3D) scaffolds using 3D-bioprinting tissue engineering techniques. Gelatin has been used in 3D-bioprinting to produce designed 3D scaffolds; however, gelatin has a poor printability and is not useful for fabricating desired 3D scaffolds using 3D-bioprinting. In this study, we fabricated pore size controlled 3D gelatin scaffolds with two step 3D-bioprinting approach: a low-temperature ($-10^{\circ}C$) freezing step and a crosslinking process. The scaffold was crosslinked with 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride (EDC) and N-hydroxysuccinimide (NHS). The pore sizes of the produced 3D gelatin scaffolds were approximately 30% smaller than the sizes of the designed pore sizes. The surface morphologies and pore sizes of the 3D gelatin scaffolds were confirmed and measured using scanning electron microscopy (SEM). Human dermal fibroblasts (HDFs) were cultured on a 3D gelatin scaffold to evaluate the effect of the 3D gelatin scaffold pore size on the cell proliferation. After 14 days of culture, HDFs proliferation throughout the 3D gelatin scaffolds prepared with more than $580{\mu}m$ pore size was approximately 14% higher than proliferation throughout the 3D gelatin scaffold prepared with a $435{\mu}m$ pore size. These results suggested that control over the 3D gelatin scaffold pore size is important for tissue engineering scaffolds.

• 한국해안·해양공학회논문집
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• 제27권5호
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• pp.324-338
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• 2015

진행파 혹은 임의 반사율을 갖는 부분중복파 혹은 완전중복파-흐름-해저지반의 상호작용에 관한 해석해가 Lee et al.(2014; 2015a; 2015b; 2015c; 2015d) 및 Yamamoto et al.(1978)과 같은 다수의 연구자들에 의해 유도되었으며, 그들은 진동간극수압과 잔류간극수압을 별개로 취급하여 각 파동에 의한 지반응답을 논의하였다. 그러나, 실제 현장이나 실험에서 해저지반내 간극수압은 진동성분과 잔류성분이 별개로 나타나는 것이 아니고 그의 합 (전간극수압)으로 주어지기 때문에 전간극수압의 관점에서 반드시 검토될 필요가 있다. 따라서, 본 연구에서는 진동간극수압과 잔류간극수압뿐만 아니라 전간극수압의 측면에서 파동조건, 지반조건 및 흐름조건의 변화에 따른 지반응답의 변동특성을 논의하였으며, 더불어 이에 따른 액상화의 연직깊이에서 특성변화를 검토하였다. 이로부터 진행파와 순방향의 흐름의 공존장에서는 흐름속도가 증가할수록 무차원진동간극수압이 증가하고, 무차원잔류간극수압은 감소하여 결과적으로 무차원전간극수압이 작아지며, 무차원액상화 깊이도 감소하는 등의 지반응답특성을 확인할 수 있었다.

• 한국막학회:학술대회논문집
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• 한국막학회 2001년도 제14회 심포지엄 : 제2회 분리막 표준화(The 2nd Standardization of Membranes)
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• pp.39-50
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• 2001

The performance of membranes is governed their pore struture. Pore structures of porous materials can be determined by a number of techniques. However, The novel technique, capillary folw porometry has a number of advantages. In this technique, the sample is brought in contact with a liquid that fills the pores in the membrane spontaneously. Gas under pressure is used to force the liquid from the pores and increase gas flow. Gas flow rate measured as a function of gas pressure in wet and dry samples yield data on the largest pore size, the mean flow pore size, flow distribution and permeability. Pore characteristics of a number of membranes were measured using this technique. This technique did not require the use of any toxic material and the pressure employed was low. Capillary flow porometry is a suitable technique for measurement of the pore structure of many membranes.

• 한국농공학회지
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• 제14권4호
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• pp.2770-2776
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• 1972

The needs for reproducing in situ neutral pressure, and for having fully saturated specimens and pore pressure measuring system for consoildation testing were examined in respect to pore pressure development. undisturbed specimens of a sensitive development. undisturbed specimens of a sensitive marine soft clay were tested in the ANTEUS consolidometer with the application of four different magnitudes of back pressure(0,5, 40 and $70lb/in^2$) in order to investigate the effect of back pressure on pore pressure development during consolidation test. The effect of back pressure on pore pressure development during consolidation is striking for back pressure up to $40lb/in^2$) but, above this value, no measurable effects of back pressure variations on pore pressure development are evidenced.

• 한국농공학회논문집
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• 제47권2호
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• pp.87-96
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• 2005

In this research, an attempt is made to derive the practical estimation of the degree of consolidation in soft clay from field measurements under embankments. For the practical estimation of pore water pressure in soft clay, the elasto-viscous rheological model was proposed, with a transform of parameters and a field geotechnical measurements in southern Korea. By using the rheological properties of soft clays and the dissipation of excess pore water pressure behaviour during step loading, a degree of consolidation or pore water pressure estimation in the future can be performed, and are shown to be generally close to the field measurements of pore water pressure. Finally, a pore water pressure behaviour in soft clay can be explained through measured data in field and the excess pore water pressure data can also be used to estimate settlement.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.399-404
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• 2008

The influence of gas hydrate dissociation on submarine slope stability was studied in this paper. Gas hydrates are stable under high pressure and low temperature conditions. Once gas hydrate dissociates due to natural or human activities, it generates large amount of gas and water. During gas hydrate dissociation, a pore pressure between soil particles increases and results in the loss of an effective stress and degradation of soil stiffness. A pore pressures model was proposed to calculated excess pore pressures generated by gas hydrate dissociation at the Storegga Slide. A slope stability analysis for the Storegga Slide using a two dimensional finite difference method was carried out by considering excess pore pressures due to gas hydrate dissociation. Since the excess pore pressure calculated by the proposed method resulted in the considerable loss of stiffness and strength in slope, a submarine slope failure occurred at the Storegga slide was well simulated.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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• pp.494-496
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• 1996

The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.