• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.4
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• pp.28-34
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• 1998

Polyvinyl acetate emulsion has been widely used as adhesives for wood and paper, paint additives and binders for fiber, leather, and other materials because it is an excellent adhesive with many advantages including low in toxicity risks and manufacturing cost. It is expected the consumption of polyvinyl acetate emulsion as adhesives will increase in cigarette industry as well as in paperboard coating industry. Recently the operation speed of the cigarette tip wrapper increased so substantially that improvement of the emulsion properties is required including good wet tack development, narrow and controlled particle size distribution, low viscosity, etc. In this study the effects of such polymerization conditions as the type and amount of emulsifier, internal or external plasticizing, and emulsification methods on the viscosity and particle size of polyvinyl acetate emulsions were examined. Results showed that polyvinyl alcohol with a high degree of hydrolysis and low molecular weight and nonionic surfactants are superior to anionic surfactant in improving adhesion and emulsion stability. They also tend to produce emulsions with smaller particle size. External plasticization with dipropylene glycol dibenzoate was more effective in improving flexibility than internal plasticization with butyl acrylate. Monomer emulsification under high shear was more effective in decreasing the particle size.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.100-101
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• 2017

LEFC(Light Emotion Friendly Conceret) was developed in Korea with demands of esthentic requirements in line with the recent developmental trend of concrete technology. The LEFC is made by inserting transparent transparent rods, and this forms a heterogeneous structure in the concrete matrix causing the LEFC substrate to crack due low adhesion between the rod and the cement. In this study, as a way to strengthen the bonding to the rod inserted in the LEFC, high strength vinylon fibers of varying mixture ratios were applied and physical properties were tested accordingly. To study the effect of different spacing of the bars on the LEFC, physical property testing was conducted on respective specimens with two different diameters (5mm, 10mm) inserted in different intervals of spacing (10mm, 15mm, and 20mm).

• Journal of the Korean Wood Science and Technology
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• v.39 no.2
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• pp.156-162
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• 2011

To evaluate the bonding performance of reinforced glulam, the textile type of glass fiber and aramid fiber, and the sheet type of glass fiber reinforced plastic (GFRP) and carbon fiber reinforced plastic (CFRP) were used as reinforcements. The reinforced glulam was manufactured by inserting reinforcement between the outmost and middle lamination of 5ply glulam. The types of adhesives used in this study were polyvinyl acetate resins (MPU500H, and MPU600H), polyurethane resin and resorcinol resin. The block shear strengths of the textile type in glass fiber reinforced glulam using MPU500H and resorcinol resin were higher than 7.1 N/$mm^2$, and these glulams passed the wood failure requirement of Korean standards (KS). In case of the sheet types, GFRP reinforced glulams using MPU500H, polyurethane resin and resorcinol resin, and CFRP reinforced glulams using MPU500H and polyurethane resin passed the requirement of KS. The textile type of glass fiber reinforced glulam using resorcinol resin after water and boiling water soaking passed the delamination requirement of KS. The only GFRP reinforced glulam using MPU500H after water soaking passed the delamination requirement of KS. We conclude that the bonding properties of adhesive according to reinforcements are one of the prime factors to determine the bonding performance of the reinforced glulam.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.102-112
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• 2019

This paper studies impact fracture behavior under temperature variation and compressive flexural strength of cement composites using VAE(vinyl acetate ethylene) powder polymer and PVA(polyvinyl alcohol) fiber. Impact test were conducted in the temperature range selected for the $-35^{\circ}C$, $0^{\circ}C$ and $35^{\circ}C$. In this experimental study, impact test were carried out using a drop impact testing machine (Ceast 9350) to obtain such as displacement, time, and impact fracture energy of normal specimen and and cement composites specimen. As test results, the use of VAE powder polymer and PVA fiber were observed to enhance the flexural strength of mortar. The compressive strength of PVA fibers reinforced cement composites was slightly decreased at 28 days, but the flexural strength was observed to increase 24.4% of normal mortar strength. As a result of the drop impact tests, PVA fiber reinforced cement composites specimens showed microcracks due to energy dispersion and crack prevention with bridge effect of the fibers, and scabbing or perforation by impact was suppressed. On the other hand, the normal mortar and VAE powder polymer cement composites specimens were carried out to the perforation and macro crack. Most of normal mortar and the cement composites subjected to impact load on specimens shows mostly local brittle failure. The impact resistant performance of the specimen with PVA fiber was greatly improved due to the increase of flexure performance.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3733-3737
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• 2013

Polyacrylonitrile (PAN)-based ultrafine fibers and carbon fibers were produced by wet-spinning, and the crystal sizes and thermal and mechanical properties of the fibers were investigated. Scanning electron microscopy revealed that the superfine fibrils in the surfaces of the PAN/polyvinyl acetate (PVA) blend fibers increased slightly with increasing PAN content before removal of the PVA. Differential scanning calorimetry indicated that the PAN and PVA in the blend fibers do not mix and, therefore, each maintains their inherent thermal characteristics. The crystal sizes of the blend fibers prepared by removing PVA with water increased at 5 wt % water. The extent of the reaction of the PAN carbon fibers, as calculated from the FT-IR spectra, is maximized at the stepwise temperature of $230^{\circ}C$, and the density increased significantly above this temperature. The carbon fibers had relatively good mechanical properties, as shown by their tensile strength and modulus values of 2396 MPa and 213 GPa, respectively.

• Journal of the Korean Ceramic Society
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• v.46 no.1
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• pp.74-80
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• 2009

Electrospinning process is the useful and unique method to produce nanofibers from metal precursor and polymer solution by controlled viscosity. In this study, the NiZn ferrite nanofibers were prepared by electrospinning with a aqueous metal salts/polymer solution that contained polyvinyl pyrrolidone and Fe (III) chloride, Ni (II) acetate tetrahydrate and zinc acetate dihydrate in N,N-dimethylformamide. The applied electric field and spurting rate for spinning conditions were 10 kV, 2 ml/h, respectively. The obtained fibers were treated at $250^{\circ}C$ for 1 h to remove the polymer. Finally, the NiZn ferrite fibers were calcined at $600^{\circ}C$ for 3 h and annealed at $900{\sim}1200^{\circ}C$ in air. By tuning the viscosity of batch solution before electrospinning, we were able to control the microstructure of NiZn ferrite fiber in the range of $150{\sim}500\;nm$ at 770 cP. The primary particle size in $600^{\circ}C$ calcined ferrite fiber was about 10 nm. The properties of those NiZn ferrite fibers were determined from X-ray diffraction analysis, electron microscopy, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, and magnetic measurement.

• Journal of the Korean Wood Science and Technology
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• v.37 no.4
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• pp.364-371
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• 2009

This study was carried out to investigate the bending strength of the Larix glulam beams which were reinforced with CFRP (Carbon fiber reinforced plastic) of which the reinforcement ratios were 0.7% and 2.1% by volume. In the bending test, the rupture shape of the reinforced glulam shows that the reinforced glulam broke firstly in the lowest bottom layer on which tension was loaded, but did not in the upper part reinforced with the CFRP layer. The upper part of the reinforced layer kept strength and did not break when the reinforced glulam broke firstly at the bottom part of the reinforced layer, but broke secondly as loading was increased. In the glulam beams reinforced with CFRP of which the reinforcement ratio was 0.7% by volume, the bending strength of the reinforced beams was increased by 28% at the first break. When beams broke up to the upper part of the reinforced layer, the bending strength of the reinforced beams was increased by 55%, compared to those of control glulam beams. When the glulam beams were reinforced with CFRP of which the reinforcement ratio was 2.1% by volume, the bending strength of the reinforced beams was increased by 77%, compared to those of control glulam beams. The ratio of the height of calculated neutral axis using failure mode recommended by Romani and the height of actual neutral axis using strain gauge was 1.03 and agreed well.

• Journal of the Korean Wood Science and Technology
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• v.36 no.4
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• pp.19-25
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• 2008

This study was carried out to investigate the bending strength properties of the unreinforced glulam beams and the GFRP laminated glulam beams according to the volume ratio of GFRP. The 7-layer glulam beams ($10cm(b){\times}14cm(h){\times}180cm(l)$) were manufactured, using Larch (Larix kaempferi Carr.) laminae ($2cm(h){\times}10cm(b){\times}360cm(l)$), which were dried to the moisture content of 8% and specific gravity of 0.54. GPRP of 0.1 and 0.3 cm was reinforced between the outmost layer of bottom and next layer. When the glulam beams were reinforced with GFRP at the volume ratio of 0.7% and 2.1%, respectively, the bending strength was increased by 12% and 28%, respectively, in the reinforced beams than in control glulam beams. Also, the GFRP reinforced layer of the glulam beams with GFRP laminations blocked the progression of rupture, and the unbroken part held about 90% of the bending strength. In the results of glue joints test, the block shear strength is higher than $7.1N/mm^2$, the standard of KS F3021, and in the result of delamination, the adhesive strength is good as the water soaking and boiling delamination was less than 5%.