• Composites Research
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• v.32 no.5
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• pp.290-295
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• 2019

In the present study, composite insulation mat was reinforced over polyurethane foam (PUF) to improve the thermal performance and impact resistance of the PUF applied to the liquefied natural gas carrier insulation system. The composite insulation mat used Kevlar, aerogel, and cryogel composite mat that can be applied in a cryogenic environment. The thermal conductivity was measured at $20^{\circ}C$ to investigate the thermal performance, and the drop impact test was carried out under impact energy of 30 J at $20^{\circ}C$, $-163^{\circ}C$ to investigate the impact resistance. The measured thermal performance was compared with neat PUF through effective thermal conductivity theoretical value. The shock resistance was evaluated of contact force, contact time, and absorb energy. In experimental results, cryogel composite mat was the best performance in terms of thermal performance, and aerogel composite mat was the best performance in terms of impact resistance.

• Elastomers and Composites
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• v.50 no.4
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• pp.297-303
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• 2015

Ammonium polyphosphate-polyurethane foam composite (APP-PUF) was prepared from poly(adipate)diol/ammonium polyphosphate composite (f = 2), polyether polyol (f = 4.6), and PMDI (f = 2.5). As a blowing agent, $H_2O$ was used at various concentrations. The thermal decomposition behavior, morphology, closed-cell content, and density of APP-PUF were characterized. At the $H_2O$ concentrations lower than 3.5 php, the cell size of pure polyurethane foams (PUF) and APP-PUFs were close each other. As the $H_2O$ concentration became greater than 5.0 php, the cell size of the PUFs greatly increased compared to that of APP-PUFs. Addition of 1.5~1.9 wt% ammonium polyphosphate to the PUFs greatly enhanced the thermal stability of the PUFs, so 50 wt% residual temperature of APP-PUFs increased to $380{\sim}488^{\circ}C$, which were $30{\sim}70^{\circ}C$ higher than those of the PUFs. Thermal stability of the PUFs and APP-PUFs increased with $H_2O$ content and then decreased once $H_2O$ content exceeded 5 php.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.4
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• pp.497-509
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• 1996

Evacuated powder insulations have long been known to have better thermal performance than existing commercially available insulators, such as fiber glass and CFC-blown foam. To make a composite powder panel, a series of individually evacuated panels was encapsulated in a rigid closed cell foam matrix. The panels were encapsulated in a thin glass sheet barrier to preserve the vacuum. The thermal conductivity of the individual panel was found to be $0.0062W/m^{\circ}K$ by experiment and the polyurethane foam above had a thermal conductivity of $0.024W/m^{\circ}K$. In this study, numerical analysis using finite element method was carried out to investigate insulation performance of rigid foam/evacuated powder composite panel with respect to panel geometries such as panel pitch, panel aspect ratio and panel area ratio. Numerical analysis has indicated that more optimal vacuum panel geometries, much lower overall thermal conductivities can be achieved.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.04a
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• pp.194-197
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• 2004

In this paper, compressive characteristics of carbon fabric skin with polymeric foam core sandwich structure were investigated by FE analyses and compressive tests of polyurethane foam were also conducted with respect to temperature changes, which were determined by curing processes of epoxy or polyester resin to obtain mechanical behaviour of polyurethane foam. FE analyses indicated variation of parameters with respect to manufacturing pressure, which have comparatively massive effect upon mechanical properties of sandwich structures, i.e. wavelength as well as crimp angle of carbon fabric

• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.30-35
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• 2020

In this study, polyurethane-silica composite foams were synthesized to analyze thermal insulation characteristics and mechanical properties. In order to synthesize polyurethane-silica composite foams, polyester-silica composite polyols were first synthesized via a polymerization reaction with silica sol, dicarboxylic acid and glycol in monomer state. Physical properties of polyurethane-silica composite foams synthesized using the composite polyols were analyzed. From the thermal conductivity analysis, no significant differences among HPUF0, HPUF1, HPUF3 and HPUF5 were found. The compressive strength of polyurethane-silica composite foams increased as the silica content increased. The mechanical property of HPUF5 was also about 25% higher than that of HPUF0.

• Journal of the Korean Institute of Gas
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• v.7 no.1 s.18
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• pp.28-32
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• 2003

In order to apply the properties of fiber reinforced plastic(FRP) to support panel of polyurethane foam in LNG storage tank, we estimated the mechanical properties, degree of vapour barrier, chemical stability and thermal conductivity changes as ageing. According to the results, the mechanical strength (i.g. compressive strength, bending strength, tensile strength and shear strength) are more than 30 times higher than those of plywood. The FRP-polyurethane foam(PUF) composites have lower thermal conductivity changes as ageing than plywood-PUF composites. FRP-PUF sandwich composite for LNG storage tank with these remarkable properties are compared the abilities of these structures with those of the conventional structures(plywood-PUF sandwich composite). Finally, we can obtain the effects such as superior mechanical properties and fuel saving through improved ability of vapor barrier.

• Steel and Composite Structures
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• v.28 no.4
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• pp.461-470
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• 2018

In this study, the effect of polyurethane foam filler, in addition to surface layer thickness and core material thickness, on vibration characteristics of sandwich structures was investigated. The manufacturing process was carried out according to the Taguchi method. The natural frequencies and damping ratios of the produced samples were determined experimentally for fixed-free boundary conditions. In addition, solid models were developed for test samples and their finite element analyses were performed with $ANSYS^{(R)}$ to obtain their natural frequencies and mode shapes. An acceptably good agreement was found with the comparison of experimental results with the numerically obtained ones. The most effective parameters on the vibration characteristics of the sandwich structure were determined by the Taguchi method.

• Steel and Composite Structures
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• v.20 no.1
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• pp.43-56
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• 2016

Polyurethane foam with low density used in sandwich panels is examined in the paper. A series of experiments was carried out to identify mechanical parameters of the foam. Various experimental methods were used for determining the shear modulus, namely a four and three point bending tests (the most common in engineering practice), a double-lap shear test and a torsion test. The behavior of PU in axial compression and tension was also studied. The experiments revealed pronounced anisotropy of the PU foam. An orthotropic model is proposed. Limitations of application of isotropic model of PU in engineering practice is also discussed.

• Composites Research
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• v.34 no.1
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• pp.16-22
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• 2021

Polyurethane foam (PUF) can be manufactured in soft, semi-rigid, and hard forms, so it is used in various fields industrially. Among them, rigid PUF has excellent mechanical properties and low thermal conductivity, and is used as a thermal insulation material for buildings and as a cold insulation material in the natural gas transportation field. In this field, there is a steady demand on higher mechanical strength and lower thermal conductivity. In this study, a rigid PUF was manufactured, and the microstructure and physical properties were studied according to the impeller type (propeller, dispersed turbine) of the agitator. Through FE-SEM and Micro-CT analysis, it was confirmed that the average pore size of the foam manufactured with the dispersed turbine was 21.5% smaller than that of the pore made by the propeller. The compressive strength was improved by 15.4%, and the thermal conductivity decreased by 3.1% in the foam with small pores. This result can be utilized for fabricating PUF composites.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.71-75
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• 2000

The effects of stitching thread on fatigue characteristics of polyurethane foam cored sandwich structures are investigated. Fatigue test and static test, being used in four point bending test, are performed with various diameters and distances of stitching thread. The Results show that the maximum load for bending tests is similar to each other, but after $1O^6$ fatigue cycles, the stiffness degradation of the stitching thread diameter $\emptyset$ 3mm specimen is a much larger than that of the $\emptyset$ 5mm specimen.