• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.104-107
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• 2004

In this work, the blend of diglycidylether of bisphenol A (DGEBA) and modified polyurethane (PU) was prepared and characterized in the cure behaviors and mechanical interfacial properties. The N-benzylpyrazinium hexafluoroantimonate was used as a cationic initiator for cure, and the content of PU was varied within 0-20 phr. The cure behaviors and mechanical interfacial properties were studied by DSC, near­IR, and the critical stress intensity actor $(K_{IC})$ measurements. Also thermal stabilities were carried out by TMA and TGA analyses. As a result, the cure activation energy $(E_a)$ and the conversion $(\alpha)$ were slightly increased with increasing the PU content, and a maximum value was found at 10 phr PU. The mechanical interfacial properties measured from $K_{IC}$ showed a similar behaviors with the results of conversion. These results were probably due to the increase of the hydrogen bonding between the hydroxyl groups of DGEBA and isocyanate groups in PU.

• Textile Coloration and Finishing
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• v.35 no.2
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• pp.98-106
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• 2023

The recent surge in night walkers and pedestrian traffic accidents has led to an increased interest in retro-reflection-based products, leading to several studies on retro-reflection. Nonetheless, achieving high durability and dispersibility of retro-reflective glass beads in viscous polyurethane coating resin remains challenging. To address this issue, this study conduct to functionalize the surface of glass beads for covalent conjugation to coating resin to enhance their dispersibility and durability in the coating resin. The study evaluated the dispersibility, chemical composition, and retro-reflection properties of the functionalized glass beads and coating resin. The results showed that the functionalized glass beads conjugated to the polyurethane coating resin and exhibited excellent dispersibility, high durability, and maintained retro-reflection efficiency.

• Polymer(Korea)
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• v.31 no.6
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• pp.543-549
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• 2007

We synthesized various polyurethanes(PU) haying different hard segments with different molecular weights of the soft segment to explore the effect of structure on the dispersion of silver particle in the phase of synthesized polyurethanes matrix. The thermal stability was increased by increasing the number of aromatic compound, while the degree of dispersion for silver particle was decreased. Silver particles showed better dispersion in the PU matrix having aromatic compounds when the soft segments were held constant. On the contrary, when the hard segment was held constant, silver particles on the PU matrix haying low $M_w$ of soft segment showed better dispersion than high $M_w$ of soft segment because poor chain mobility of low $M_w$ of soft segment restricted re-aggregation of silver particle. A sheet resistance of composite materials showed different aspects. In this case, the inter connection between silver particles was more important than its dispersion. In this study, the NDI-PEG 900/silver particle composite film showed the best thermal stability and electro conductivity.

• Elastomers and Composites
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• v.39 no.3
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• pp.234-243
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• 2004

The elastomeric and conductive polyurethane (PU) films were prepared by poly(propylene glycol) (PPG), toluene 2,4-diisocyanate, 3-methylthiophene (3-MT) at various preparation conditions, such as the reaction time, the $FeCl_3$ concentration, the weight ratio of the 3-MT to PU and the reaction temperature for the diffusion-oxidative reaction. The conductive poly (3-methylthiophene) (PMT) layers via the diffusion-oxidative reaction of 3-MT and ferric chloride were formed by immersing the film in organic solution of $FeCl_3$/ethyl acetate. The preparation conditions greatly affected the electrical conductivity of the 3-MT/PU composite. The effects of the reaction time and temperature on morphology and surface free energy were investigated by scanning electron microscopy (SEM) analysis and contact angle measurement, respectively. The conductivity of the composite was as high as 42 S/cm.

• Nuclear Engineering and Technology
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• v.52 no.5
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• pp.1093-1097
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• 2020

A composite iodine sorbent was obtained in the form of porous polymer matrix with activated carbon particles impregnated with triethylenediamine deposited on its surface. A comparative assessment of the radioactive methyliodide capturing efficiency by the composite sorbent and a sample of industrial charcoal sorbent was conducted. It was shown that under the selected testing conditions, the hydraulic resistance of the composite sorbent is lower, and the sorption capacity is higher than that of the industrial charcoal sorbent. A method for comparing the effectiveness of iodine sorbents, based on the calculation of the ratio of the sorption capacity index to the minimum capacity index, needed for the required purification degree was proposed.

• Journal of the Korean Society for Railway
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• v.9 no.1 s.32
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• pp.43-49
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• 2006

We have evaluated the structural integrity of a sandwich composite train roof structure that can be a lightweight, cost saving solution to large structural components for rail vehicles in design stages. The sandwich composite train roof structure was 11.45 meters long and 1.76 meters wide. The finite element analysis was used to calculate the stresses, deflections and natural frequencies of the sandwich composite train roof against the weight of air-conditioned system. The 3D sandwich finite element model was introduced to examine the structural behavior of the hollow aluminum extrusion frames joined to both sides of the sandwich composite train roof. The results shown that the structural performance of the sandwich composite train roof under loading conditions specified is satisfaction and the use of aluminum reinforced frame and aluminum honeycomb core is beneficial with regard to weight saving and structural performance in comparison with steel reinforced frame and polyurethane foam core. Also, we have manufactured prototype of sandwich composite train roof structure on the basis of analysis results.

• Composites Research
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• v.24 no.3
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• pp.39-45
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• 2011

Adhesive joints are widely used for structural joining applications in various fields and environmental conditions. Polyurethane (PU) and Epoxy adhesives are now being used for liquefied natural gas (LNG) carriers at cryogenic temperatures. This paper presents a comprehensive evaluation of epoxy and PU adhesive bonds between Triplex sheets at normal and cryogenic temperatures. The most significant result of this study is that for all adhesives tested, there is a significant decrease in peel strength at cryogenic temperatures. However, the reasons for the decrease in peel strength for epoxy and PU adhesives differ. Consequently, PU adhesives can be considered better suited for use in applications requiring high bonding performance at cryogenic conditions, such as in LNG carriers.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.3089-3095
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• 2013

The headliner was made of polyurethane(PU) and glass fiber(GF) composite materials are widely used as a sound insulation material. A large amount of waste materials occurs as a by-product in the headliner manufacturing process. In order to efficiently reuse the headliner waste materials, separation process of the components are very necessary. According to the results of thermal analysis, weight loss showed increase in the order polyurethane foam> non-foaming polyurethane> non-woven fabric> 1st layer> glass fiber in the range of up to $400^{\circ}C$. Analysis of the DSC characteristics, HDPE, LLDPE, PP, and Master Batch by adding additives the wasted scrap. As a result, except for the PP, there was no exothermic transition due to the crystallization.

• Steel and Composite Structures
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• v.32 no.3
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• pp.373-388
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• 2019

This study proposes a new concept of an axial damper using the combination of shape memory alloy (SMA), friction devices, and polyurethane springs. Although there are many kinds of dampers to limit the damages, large residual deformation may happen and it causes much repairing cost for restoring the structure to the initial position. Also in some of the dampers, a special technology for assembling and fabricating is needed. One of the most important advantages of this damper is the ability to remove all the residual deformation using SMA plates and simple assembling without any special technology to fabricate. In this paper, four different dampers (in presence or omission of friction devices and polyurethane springs) are investigated. All four cases are analyzed in ABAQUS platform under cyclic loadings. In addition, the SMA plates are replaced by steel ones in four cases, and the results are compared to the SMA dampers. The results show that the axial polyurethane friction (APF) damper could decrease the residual deformation effectively. Also, the damper capacity and dissipated energy could be improved. The analysis showed that APF damper is a good recentering damper with a large amount of energy dissipation and capacity, among others.

• Polymer(Korea)
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• v.32 no.4
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• pp.340-346
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• 2008

The aim of this study is to understand the effect of structure on the dispersion of both CNT and GNF in the phase of synthesized polyurethanes matrix. Various CNT/PU and GNF/PU composite films were prepared. Polyurethane having a different hard segment was blended with both CNT and GNF. PU having HDI as hard segment showed good dispersion with both CNT and GNF because of their linear structural character and molecular kinesis while PU having aromatic ring showed poor dispersion with those due to their structural complexity. Structural effect also induced the increase of its electro conductivity. The PU/CNT composite showed a bad dispersion (because of phase separation between PU matrix and CNT) but good electro conductivity at its surface (because CNT was collected on the surface of composite film due to low density of CNT). PU/CNT and PU/GNF composite films have quite low normalized sheet resistance value compared with silver/PU nanocomposite film because the fiber type filler could have much more contact points than that of sphere shaped silver particles have.