• Bulletin of the Korean Chemical Society
• /
• 제24권3호
• /
• pp.369-376
• /
• 2003

Coulson (ZINDO), Mulliken $(MP2/6-31G^*)$ and Natural $(MP2/6-31G^*)$ population analyses of several large molecules were performed by the Fragment Reassociation (FR) method. The agreement between the conventional ZINDO (or conventional MP2) and FR-ZINDO (or FR-MP2) charges of these molecules was excellent. The standard deviations of the FR-ZINDO net atomic charges from the conventional ZINDO net atomic charges were 0.0008 for $C_{10}H_{22}$ (32 atoms), 0.0012 for $NH_2-C_{16}O_2H_{28}-COOH$ (53 atoms), 0.0014 for $NH_3^+-C_{16}O_2H_{28}-COOH$ (54 atoms), 0.0017 for $NH_2-C_{16}O_2H_{28}-COO^-$ (52 atoms), 0.0019 for $NH_3^+-C_{16}O_2H_{28}-COO^-$ (53 atoms), 0.0024 for a conjugated model $(O=CH-(CH=CH)_{15}-C=O-(CH=CH)_{12}-CH=CH_2)$, 118 atoms), 0.0038 for aglycoristocetin $(C_{60}N_7O_{19}H_{52}^+$, 138 atoms), 0.0023 for a polypropylene model complexed with a zirconocene catalyst $(C_{68}H-{121}Zr^+$, 190 atoms) and 0.0013 for magainin $(C_{112}N_{29}O_{28}SH_{177}$, 347 atoms), respectively. The standard deviations of the FR-MP2 Mulliken (or Natural) partial atomic charges from the conventional ones were 0.0016 (or 0.0016) for $C_{10}H_{22}$, 0.0019 (or 0.0018) for $NH_2-C_{16}O_2H_{28}-COOH$ and 0.0033 (or 0.0023) for $NH_3^+-C_{16}O_2H_{28}-COO^-$, respectively. These errors were attributed to the shape of molecules, the choice of fragments and the degree of ionic characters of molecules as well as the choice of methods. The CPU time of aglycoristocetin, conjugated model, polypropylene model complexed with zirconocene and magainin computed by the FR-ZINDO method was respectively 2, 4, 6 and 21 times faster than that by the normal ZINDO method. The CPU time of $NH_2-C_{16}O_2H_{28}-COOH\;and\;NH_3^+-C_{16}O_2H_{28}-COO^-$ computed by the FR-MP2 method was, respectively, 6 and 20 times faster than that by the normal MP2 method. The largest molecule calculated by the FR-ZINDO method was B-DNA (766 atoms). These results will enable us to compute atomic charges of huge molecules near future.

• Nuclear Engineering and Technology
• /
• 제41권8호
• /
• pp.1101-1108
• /
• 2009

The ocean contains around eighty elements of the periodic table and uranium is also one among them, with a uniform concentration of 3.3 ppb and a relative abundance factor of 23. With a large coastline, India has a large stake in exploiting the 4 billion tonnes of uranium locked in seawater. The development of radiation grafting techniques, which are useful in incorporating the required functional groups, has led to more efficient adsorbent preparations in various geometrical configurations. Separation based on a polymeric adsorbent is becoming an increasingly popular technique for the extraction of trace heavy metals from seawater. Radiation grafting has provided definite advantages over chemical grafting. Studies related to thermally bonded non woven porous polypropylene fiber sheet substrate characterization and parameters to incorporate specific groups such as acrylonitrile (AN) into polymer back bones have been investigated. The grafted polyacrylonitrile chains were chemically modified to convert acrylonitrile group into an amidoxime group, a chelating group responsible for heavy metal uptake from seawater/brine. The present work has been undertaken to concentrate heavy metal ions from lean solutions from constant potential sources only. A scheme was designed and developed for investigation of the recovery of heavy metal ions such as uranium and vanadium from seawater.

• 한국미생물·생명공학회지
• /
• 제23권4호
• /
• pp.492-498
• /
• 1995

Net type polyvinylidene chloride (PVDC) media and cillium type polyethlene polypropylene (PEPP) media were installed in the aereted submerged biofilm reactors. Synthetic phenol wastewater for feed were made to contain 1,480 mg of phenol per liter of water. The organic loading range of reactors were 0.439-0.456 kg COD/m$_{3}$, 0.882 - 0.919 kg COD/m$_{3}$ and 1.199-1.339 kg COD/m$_{3}$. Comparing PVDC to PEPP media, the bacterial number found in biofilm on PEPP were slightly higher. With the low temperature (10$\circ$C), the number of bacteria was some what deceered. Number of bacterial strains identified from PVDC were 23 and those from PEPP were 42. Genera identified in the PVDC media were Flavobacterium (47.8%), Unidentified (17.6%), Pseudomonas (13.0%), Micrococcus (8.7%) and Beggratoa (8.7%). Genera identified in the PEPP media reactor were Pseudomonas (35.7%), Alcaligenes (19.0%), Aeromonas (14.33%) and Micrococcus (11.9%), In the steady, state, a filamentous bacteria, type 1701 was identified in all of the reactors. Paramecium sp. and fungi were present in the PVDC media reactor. While, Difflugia sp, Paramecium sp. and fungi were found in the PEPP media reactor. The low diversity of protozoa was ascribed to high concentration of phenol.

• 고려인삼학회:학술대회논문집
• /
• 고려인삼학회 1980년도 학술대회지
• /
• pp.39-47
• /
• 1980

The harvesting and export of Canadian ginseng from the cool, shady hardwood forests of southern Canada can be traced to 1796. Because of its high dollar value and diminishing woodland supplies it was decided in 1896 that it should be cultivated under wood lath screens. Present day economics dictate changes in production techniques to allow for a decreasing supply of expensive labour. Traditional wooden lath screens have a surface area of wood of 70 per cent and permit light penetration of only about 18 per cent. Experimental woven black polypropylene shade has an estimated surface area of 72 per cent and permits light pentration of about 28 per cent. While differences in air and leaf temperatures under the two shade structures can be measured it is doubtful if these are great enough to cause differences in plant growth under the two structures. Shade grown ginseng had a low fresh and dry weight and total chlorophyll content (ratio of a to b was 3 to 1) comparable to other shade species. There was no differences in fresh and dry weight and chlorophyll content of leaves from plants grown under the two shade structures. Maximum net photosynthesis of leaves was 0.175 g $CO_2\;m^{-2}\;hr^{-1}$ and light saturation level was about $200{\mu}E\;m^{-2}\;s^{-1},$ or about 10 per cent of full sunlight.

• 한국자원식물학회지
• /
• 제27권1호
• /
• pp.102-109
• /
• 2014

본 연구는 태양초 생산시 전처리와 산광 재료가 상품성과 건조 효율에 미치는 효과를 구명하기 위하여 실시하였다. 벌크, 하우스 밀폐, PE비닐밀봉 처리 등 전처리를 하였으며, 산광 재료로 대조구, 차광망 35%, 천막지, 백색부직포, 흑색부직포 등을 사용하였다. 벌크 후숙 처리구의 상품 수량이 300 g으로 가장 많았으며, 하우스 건조가 275 g이었으며, PE 밀봉 처리구가 112 g으로 가장 적었다. 적색도는 PE 밀봉 처리시 17.85로 가장 높았고 벌크 후숙 처리에서 가장 낮았으며, 각각의 처리 간에 유의성이 인정되었다. 고추의 수분 감모 속도는 대조구가 가장 빨랐으며, 차광망 처리구가 가장 늦었다. 상품 수량지수는 백색부직포가 대조구 100%에 비해 114%로 가장 높았다. 적색도는 흑색부직포와 천막지가 15.65로 다른 처리와 유의성을 나타냈다. 캡사이신 함량은 흑색부직포에서 $160mg{\cdot}100g^{-1}$로 가장 높았다. 비닐하우스 이용 태양초 생산시 비닐하우스 밀폐 전처리를 하고 백색부직포로 산광하면 대조구보다 건조기간은 2일 정도 지연되었으나 상품 수량은 14% 증가하였다. 본 실험에서 얻어진 결과는 태양초 생산 효율 증진뿐만 아니라 향후 연구에 도움이 되리라 기대된다.

• 폴리머
• /
• 제29권6호
• /
• pp.536-542
• /
• 2005

로크웰 경도시험 조건 중에서 시간과 관련이 있는 인자들이 경도측정 결과에 미치는 영향을 연구하였다. 대상 소재는 PE, PP PVC, PMMA이었으며 압입속도, 시험하중 유지시간, 그리고 계기판독 시점 등을 중심으로 시험한 결과 탄성이 큰 소재일수록 이들 인자들의 영향을 크게 받는 것으로 나타났다. 시험에 소요되는 시간 등을 고려하였을 때 최적 시험 조건은 각기 4, 15, 15초 이었으며 이 기준에 따라 순회 비교시험을 실시하였다. 순회 비교시험 결과 고분자소재의 경도를 제대로 측정하려면 부가하중을 제하하고 나서 계기판독 시점인 15초의 시간을 유지할 수 있는 기능이 중요한 것으로 나타났다. 황동 기준편으로 경도시험기를 간접 검증하는 것만으로는 탄성 회복력이 좋은 고분자 소재의 특성 때문에 경도 측정값의 신뢰도를 보증할 수 없는 것으로 나타났다.

• Journal of Plant Biotechnology
• /
• 제7권1호
• /
• pp.67-74
• /
• 2005

To overcome various disadvantages of conventional cul-ture vessels for micropropagation, a novel disposable vessel, the 'Vitron', made of a multi-layered $OTP^{(R)}$ film and supported by a polypropylene frame, was developed. The film possesses superior properties such as: high light transmittance, low water vapor transmittance and thermal stability and in particular, high gas-permeability. Single nodal explants, which were excised from the multiple shoots derived from shoot-tip culture, were cultured in Vitron and polycarbonate vessels on $3\%$ sugar-containing agar on MS medium and placed at 3000 ppm $CO_2$-enrichment at a low photosynthetic photon flux density (PPFD) ($45{\mu}mol\;m^{-2}\;s^{-1}$). The in vitro and ex vitro growth, and the net photosynthetic rate of in vitro and ex vitro plantlets were significantly enhanced in the Vitron compared to those cultured in a polycarbonate vessel. Explants that were cultured on the same MS medium under low PPFD at various $CO_2$ concentrations were also cultured at 3000 ppm $CO_2$- enrichment at various PPFD: 30, 45, 60, 75 and $90{\mu}mol\;m^{-2}\;s^{-1}$. The best in vitro and ex vitro growth obtained for 3000 ppm $CO_2$-enrichment at $75{\mu}mol\;m^{-2}\;s^{-1}$ PPFD. The novel Vitron vessel, when placed under the two conditions, may replace conventional culture vessels for the successful micropropagation of sweetpotato.

• 한국식품저장유통학회지
• /
• 제8권1호
• /
• pp.30-36
• /
• 2001

월동배추(품종 : 동풍)를 $0^{\circ}C$에서 저온저장중 선도 유지를 위하여 포장과 적입방법 개선에 대한 효과가 조사되었다. 저장과정중 배추의 상품성을 보았을 때 월동배추는 $0^{\circ}C$에 저온 저장한 경우 4개월 이상 저장, 출하가 가능한 것으로 여겨졌다. 포장용기간 저장성은 0.03mm 폴리에칠렌 플라스틱필름에 4포기씩 세로로 적입하여 플라스틱콘테이너에 저장한 경우가 기존의 폴리프로필렌 그물망과 철제파레트를 이용한 경우에 비하여 우수하게 나타났다. MAP 저장시 포장내의 가스 조성은 처리구간에 큰 유의적인 차이를 나타내지는 않았는데 대체로 산소 농도는 8.2~19.5% 정도, 이산화탄소는 0.35~8.58% 범위를 나타내었다. 저온저장중 비타민C, 환원당, 클로로필 색소는 계속 감소하였으며 폴리에틸렌 플라스틱필름과 콘테이너에 의한 MAP가 기존 저장방법에 비하여 10~20% 정도 선도 저하를 억제하는 효과를 가져왔다.

• 한국지반신소재학회논문집
• /
• 제2권1호
• /
• pp.27-37
• /
• 2003

섬유혼합토의 전단강도 및 마찰 특성에 영향을 미치는 요인으로는 혼합되는 흙의 입도분포와 흙입자의 형상 등과 같은 흙의 공학적 특성과 섬유의 형상, 길이, 직경, 인장강도, 탄성계수, 마찰계수, 섬유 혼합률 등과 같은 섬유의 물리적 역학적 특성 그리고 구속응력, 다짐상태 등의 외적 인자 등을 들 수 있다. 본 연구에서는 흙종류, 섬유종류, 섬유혼합률 그리고 다짐도에 따른 섬유혼합토의 마찰특성을 평가하기 위하여 일련의 전단마찰시험 및 인발시험을 수행하였다. 본 연구에서는 공학적으로 그 특성이 다소 불량한 두 가지 종류의 흙시료(통일분류법상 SM 및 ML)에 세 가지 종류의 폴리프로필렌 섬유(망사 38mm, 망사 60mm 및 단사 60mm)를 0.2% 및 0.3%의 혼합률로 혼합한 섬유혼합토를 다짐도 85% 및 95%로 조성하여 실험을 수행하였고, 보강재로는 지오그리드를 사용하였다.

• 한국정밀공학회지
• /
• 제33권5호
• /
• pp.333-339
• /
• 2016

In this paper, a fundamental experiment regarding the formation of porous 3D structures for personal safety products using 3D PPP (Porous Polymer Printing) was introduced for the first time. The filament was manufactured by mixing PP (Polypropylene) and CBA (Chemical Blowing Agent) with polymer extruder, and the diameter of the filament was approximately 1.75mm. The proposed 3D PPP method, combined with the conventional FDM (Fused Deposition Modeling) procedure, was influenced by process parameters, such as the nozzle temperature, printing speed and CBA density. In order to verify the best processing conditions, the depositing parameters were experimentally investigated for the porous polymer structure. These results provide parameters under which to form a multiple of 3D porous polymer structures, as well as various other 3D structures, and help to improve the mechanical shock absorption for personal safety products.