• 한국염색가공학회지
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• 제22권1호
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• pp.37-42
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• 2010

ABS/MWNT nanocomposites were prepared by using MWNT wrapped with SAN through melt compounding. Effect of wrapping of MWNT by SAN on the morphology, mechanical and electrical properties of ABS/MWNT were analyzed. It was found that SAN could wrap MWNT effectively indicated by the increased thickness after wrapping, which is presumably due to helical structure of polyacrylonitrile component in a block copolymer of SAN. MWNT was observed to be dispersed more evenly in ABS matrix by SAN wrapping, which resulted in improved tensile properties of the composites. On the other hand, there was little effect on the impact strength and electrical properties of ABS having inherently high impact strength.

• 공업화학
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• 제23권4호
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• pp.372-376
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• 2012

탄소나노튜브는 좋은 전기 기계적 및 열적 특성을 가진 복합 재료 분야에서 가장 이상적인 나노 충전재이다. 따라서 탄소나노튜브의 복합 재료는 전도성 재료, 고강도를 가지면서 가벼운 무게를 가지는 재료에 이용된다. 탄소나노튜브 복합재료의 주요 문제점은 탄소나노튜브의 나쁜 분산에 있다. 본 연구에서는 다중벽 탄소나노튜브(MWNT)를 물리적 방법으로 전처리하였다. 전처리 후, 고분자/MWNT nanocomposites는 용해 공정에 의해 분산되었다. 물리적 방법은 고분자 wrapping 방법에 의해 준비되었다. ABS/MWNT 복합 재료의 기계적 및 전기적 특성을 SAN과 함께 wrapping된 MWNT와 미처리된 MWNT와 혼합된 ABS의 속성을 비교하여 연구하였다. MWNT가 wrapping된 복합체의 인장강도는 증가하였으나 충격강도는 감소한 수치를 보였다. 전기적 물성의 향상에는 미처리시료와 비교해 볼 때 큰 효과가 없었다.

• Steel and Composite Structures
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• 제15권6호
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• pp.623-643
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• 2013

Concrete filled steel tubular members (CFST) become a popular choice for modern building construction due to their numerous structural benefits and at the same time aging of those structures and member deterioration are often reported. Therefore, actions like implement of new materials and strengthening techniques become essential to combat this problem. The application of carbon fibre reinforced polymer (CFRP) with concrete structures has been widely reported whereas researches related to strengthening of steel structures using fibre reinforced polymer (FRP) have been limited. The main objective of this study is to experimentally investigate the suitability of CFRP to strengthening of CFST members under flexure. There were three wrapping schemes such as Full wrapping at the bottom (fibre bonded throughout entire length of beam), U-wrapping (fibre bonded at the bottom throughout entire length and extended upto neutral axis) and Partial wrapping (fibre bonded in between loading points at the bottom) introduced. Beams strengthened by U-wrapping exhibited more enhancements in moment carrying capacity and stiffness compared to the beams strengthened by other wrapping schemes. The beams of partial wrapping exhibited delamination of fibre and were failed even before attaining the ultimate load of control beam. The test results showed that the presence of CFRP in the outer limits was significantly enhanced the moment carrying capacity and stiffness of the beam. Also, a non linear finite element model was developed using the software ANSYS 12.0 to validate the analytical results such as load-deformation and the corresponding failure modes.

• Carbon letters
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• 제20권
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• pp.53-61
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• 2016

The reportedly synergistic effects of carbon nanotubes (CNTs) and graphene hybrids have prompted strong demand for an efficient modifier to enhance their dispersion. Here, we investigated the ability of poly(acrylonitrile) (PAN) to overcome the van der Waals interaction of multi-walled CNTs (MWCNTs) and graphene by employing a simple wrapping process involving ultrasonication and subsequent centrifugation of PAN/MWCNT/graphene solutions. The physical wrapping of MWCNTs and graphene with PAN was investigated for various PAN concentrations, in an attempt to simplify and improve the polymer-wrapping process. Transmission electron microscopy analysis confirmed the wrapping of the MWCNTs and graphene with PAN layers. The interaction between the graphitic structure and the PAN molecules was examined using proton nuclear magnetic resonance, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and Raman spectroscopy. The obtained results revealed that the cyano groups of the PAN molecules facilitated adhesion of the PAN molecules to the MWCNTs and graphene for polymer wrapping. The resulting enhanced dispersion of MWCNTs and graphene was verified from zeta potential and shelf-life measurements.

• 한국초전도ㆍ저온공학회논문지
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• 제16권1호
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• pp.14-18
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• 2014

The mechanical, electrical and thermal characteristics of insulating materials may significantly affect the performance and reliability of electrical devices using superconductors. General method to provide insulating layer between coated conductors is wrapping coated conductor with Kapton tape. But uniform and compact wrapping without failure or delamination in whole coverage for long length conductor is not a simple task and need careful control. Coating of insulating layer directly on coated conductor is desirable for providing compact insulating layer rather than wrapping insulating layers around conductor. Ceramic added polymer has been widely used as an insulating material for electric machine because of its good electrical insulating properties as well as excellent heat resistance and fairy good mechanical properties. The insulating layer of coated conductor should have high breakdown voltage and possesses suitable mechanical strength and maintain adhesiveness at the cryogenic temperature where it is used and withstand stress from thermal cycling. The insulating and mechanical properties of polymer can be improved by adding functional filler. In this study, insulating layer has been made by adding ceramic particles such as $SiO_2$ to a polymer resin. The size, amount and morphology of added ceramic powder was controlled and their effect on dielectric property of the final composite was measured and discussed for optimum composite fabrication.

• Ocean Systems Engineering
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• 제8권4호
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• pp.409-426
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• 2018

This paper presents the strengthening of tubular joint by wrapping Carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP). In this study, total number of layers, stacking sequence and length of wrapping are the different parameters involved when fiber reinforced polymers (FRP) composites are used for strengthening. For this, parameters where varied and results were compared with the reference joint. The best stacking sequence was identified which has the highest value in ultimate load with lesser deflections. For determining the best stacking sequence, numerical investigation was performed on CFRP composites; length of wrapping and number of layers were fixed. Later, the studies were focused on CFRP and GFRP strengthened joint by varying the total number of layers and length of wrapping. An attempt was done to propose a parametric equation from multiple regression analysis, which can be used for CFRP strengthened joints. Hashin failure criteria was used to check the failure of composites. Results revealed that FRP was having a greater influence in the load bearing capacity of joints, and in reducing the deflections and stresses of joint under axial compressive loads. It was also seen that, CFRP was far better than GFRP in reducing the stresses and deflection.

• 공업화학
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• 제25권6호
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• pp.581-585
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• 2014

Reduced graphene oxide (RGO)를 수용성 고분자인 poly(styrene sulfonate) (PSS)로 wrapping한 수분산성 그래핀 치환체인 G-PSS와 전도성 고분자인 poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT/PSS)의 복합화에 관하여 연구하였다. G-PSS의 존재 하에서 PEDOT/PSS의 제자리 화학 중합 반응을 수행하여 복합체(GP)를 얻었다. 생성물의 XPS, IR 및 Raman 분석을 통하여 모노머인 EDOT의 중합이 원활하게 진행되어 PEDOT/PSS가 생성됨과 동시에 그래핀과 복합화되었다는 것을 확인할 수 있었다. 또한 GP는 $4.46{\times}10^2S/m$의 전도도를 나타냈으며, 0.5%의 농도까지 물에 분산이 되어 G-PSS보다 전기적 특성 및 수분산성 모두 우수하였다.

• International Journal of Concrete Structures and Materials
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• 제18권1E호
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• pp.29-34
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• 2006

Elastic modulus, tensile and bond capacities are important factors for developing an effective reinforcing action of a flexural member as a reinforcing material for concrete structures. Reinforcement must have enough bond capacity to prevent the relative slip between concrete and reinforcement. This paper presents an experimental study to clarify the bond capacity of prestressed carbon fiber reinforced polymer(CFRP) rod manufactured by an automatic assembly robot. The bond characteristics of CFRP rods with different pitch of helical wrapping were analyzed experimentally. As the result, all types of CFRP rods show a high initial stiffness and good ductility. The mechanical properties of helical wrapping of the CFRP rods have an important effect on the bond of these rods to concrete after the bond stress reached the yield point. The stress-slip relationship analyzed from the pull-out test of embedded cables within concrete was linear up to maximum bond capacity. The deformation within the range of maximum force seems very low and was reached after approximately 1 mm. The average bond capacity of CF20, CF30 and CF40 was about 12.06 MPa, 12.68 MPa and 12.30 MPa, respectively. It was found that helical wrapping was sufficient to yield bond strengths comparable to that of steel bars.

• Earthquakes and Structures
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• 제9권1호
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• pp.29-48
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• 2015

The main purpose of this work is to compare different criteria for the seismic strengthening of RC framed buildings in order to find the optimal combinations of these retrofitting techniques. To this end, a numerical investigation is carried out with reference to the town hall of Spilinga (Italy), an RC framed structure with an L-shaped plan built at the beginning of the 1960s. Five structures are considered, derived from the first by incorporating: carbon fibre reinforced polymer (FRP)-wrapping of all columns; base-isolation, with high-damping-laminated-rubber bearings (HDLRBs); added damping, with hysteretic damped braces (HYDBs); FRP-wrapping of the first storey columns combined with base-isolation or added damping. A three-dimensional fibre model of the primary and retrofitted structures is considered; bilinear and trilinear laws idealize, respectively, the behaviour of the HYDB, providing that the buckling be prevented, and the FRP-wrapping, without resistance in compression, while the response of the HDLRB is simulated by using a viscoelastic linear model. The effectiveness of the retrofitting solutions is tested with nonlinear dynamic analyses based on biaxial accelerograms, whose response spectra match those in the Italian seismic code.

• 한국구조물진단유지관리공학회 논문집
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• 제24권6호
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• pp.153-160
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• 2020

지진동 하의 구조 시스템에서 기둥은 가장 중요한 구조 요소 중 하나이다. 이러한 관계로, 철근콘크리트(RC) 기둥의 내진 성능에 FRP 보강이 미치는 영행을 평가하기 위하여 광범위한 실험 연구가 이루어졌다. 이 중 상당수는 CFRP 또는 GFRP로 보강된 원형 단면 또는 정사각형 단면의 RC 기둥의 지진 거동에 집중하였다. 단면의 형태가 FRP 보강으로 인한 구속 효과에 영향을 미치기 때문에, 보강 효과와 최종 파괴 패턴이 형상에 따라 상이할 수 있다. 본 연구에서는 현무암 섬유를 함유한 BFRP 시트와 복합섬유 패널로 보강한 직사각형 단면을 가진 RC 기둥의 지진 거동을 살펴보기 위하여 반복하중 실험을 수행하였다. 실험 결과는 보강 효과가 크지 않았음을 보여주는데, BFRP 시트와 복합섬유 패널에 의한 구속 효과의 증가가 미미했음을 의미하며, 이는 기둥 단면 형상에 일부 기인하는 것으로 판단된다.