• 제목/요약/키워드: polymer synthesis and characterization

검색결과 305건 처리시간 0.094초

Pentiptycene Diacetylene의 합성 (Synthesis of Pentiptycenediacetylene)

  • 한정민;권형준
    • 통합자연과학논문집
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    • 제2권2호
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    • pp.69-72
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    • 2009
  • Pentiptycenediacetylene is very useful precursor materials for the synthesis of conducting polymer materials. The incorporation of rigid three-dimensional pentiptycene moieties into conjugated polymer backbones would offer several design advantages. They prevent ${\pi}$-stacking of the polymer backbones and thereby maintain high fluorescence quantum yields and spectroscopic stability in thin films. The pentiptycenediactylene was synthesized and characterized by 1H- and 13C-NMR spectroscopy.

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4개의 폴리카프로락톤 가지 코어를 가지는 스타형 폴리카프로락톤의 합성 및 분석 (Synthesis and characterization of Star Shape Polycaprolactone containing 4-Arm Polycaprolactone Core)

  • An, Sung-Guk;Cho, Chang-Gi
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.199-202
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    • 2002
  • The synthesis of materials with controlled composition and architectures continues to be a focus of considerable current research. Dendritic multiarm polymers such as dendrimer, hyperbranched polymer, and star polymers are three dimensional macromolecules, in which a large number of linear arms of similar molecular weight and narrow molecular weight distribution emanate from a central core. (omitted)

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Synthesis and Characterization of Cationic and Anionic Cyclodextrin Oligomers and Their Use in Layer-by-Layer Film Formation

  • Yang, Sung Yun;Hoonor, Rekha;Jin, Hye-Seung;Kim, Jeongkwon
    • Bulletin of the Korean Chemical Society
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    • 제34권7호
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    • pp.2016-2022
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    • 2013
  • Ionically modified ${\beta}$-cyclodextrins, which have excellent water-solubility, have been interested in purification technology as well as drug carrier system. The present study summarizes the synthesis and characterization of cationic and anionic ${\beta}$-cyclodextrin (${\beta}$-CyD) products using by polycondensation. The oligo (${\beta}$-CyD)s are synthesized from ${\beta}$-CyD, epichlorohydrin (EP) and choline chloride (CC; for cationic polymer) or chloroacetic acid (CAA; for anionic polymer) through one step polycondenstaion process. Unlike the previous studies, we successfully purified the ionic ${\beta}$-CyD condensation products from the ${\beta}$-CyD reaction mixtures and accomplished a great level of structural analysis. The detailed structural analysis of these ionic ${\beta}$-CyD compounds is done by $^1H$ NMR, MALDI-TOF as well as GPC analysis and confirms the formation of oligomers with a few units of ${\beta}$-CyD. We found that the sequence of reactant addition also could effect on the molecular weight of the resulting product as well as the molar ratio of the reactants. Finally, we used the cationic and anionic ${\beta}$-CyD oligomers for fabricating multilayer films by layer-layer process.