• Title/Summary/Keyword: polymer structure

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Development of Precast Channel Structure Using Polymer Concrete (폴리머 콘크리트를 이용한 조립식 수로구조물 표준도 개발)

  • Park, Kwang-Soo;Shin, Su-Gyun;Kim, Kwan-Ho;Lee, Meyong-Won;Lee, Joon-Gu
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.157-160
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    • 2002
  • This study was developed high-quality a large size precast channel structure using polymer concrete to improve quality of the product as well as to enhance construction quality. Practical precast channel structure design and manufacture procedure for the high polymer concrete were described in this paper. Precast PC represent the fastest growing segment of the polymer concrete industry. The fast curing, high strength, and low impermeability permit thin section and rapid reuse of moulds. Precast channel structure will carry out structural experiment and analysis.

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The Effect of Interpenetrating Polymer Network upon Tracking Resistance of Epoxy Composite Materials (에폭시 복합재료의 내트래킹성에 미치는 상호침입망목의 효과)

  • 김탁용;이덕진;손인환;김명호;김경환;김재환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.225-229
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    • 1996
  • In this study, in order to develop outdoor insulating materials, SIN(simultaneous interpenetrating polymer network) was introduced to Epoxy resin and the environment resistance was investigated. The single network structure specimen(E series) formed of Epoxy resin alone and simultaneous interpenetrating polymer network specimen (EM series) in which epoxy resin was taken as the first network and methyl methacrylate resin as the second network were manufactured. Ten kinds of specimens were manufacture by filler (SiO$_2$) content. SEM were utilized in order to confirm their network structure changes, and AC voltage dielectric strength was measured. Also, UV-test and tracking test were carried out investigate the environment resistance characteristic. Therefore the variations of network structure were happened as a result of SEM test, and it was confirmed that simultaneous interpenetrating polymer network specimens were more excellent than single network structure specimens.

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Stability-Enhanced Liquid Crystal Mode for Flexible Display Applications

  • Jung, Jong-Wook;Jang, Se-Jin;Lee, You-Jin;Kim, Hak-Rin;Jin, Min-Young;Kim, Jae-Hoon
    • Journal of Information Display
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    • v.6 no.2
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    • pp.1-6
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    • 2005
  • We demonstrated stability-enhanced liquid crystal (LC) displays using pixel-isolated LC mode in which LC molecules are isolated in pixel by horizontal polymer layer and vertical polymer wall. The device shows good electro-optic properties against external point or bending pressure due to the polymer structures. The polymer wall acts as supporting structure from mechanical pressure and prevents the cell gap from bending. Moreover, the polymer layer acts as an adhesive to ensure a tight attachment of the two substrates. We present herein various methods for producing polymer structures by using an anisotropic phase separation from LC and polymer composites or patterned micro-structures for stable flexible liquid crystal displays.

Improved Efficiency of Polymer LEDs using Electron Transporting Layer

  • Kim, Jong-Lae;Kim, Jai-Kyeong;Cho, Hyun-Nam;Kim, Dong-Young;Hong, Sung-Il;Kim, Chung-Yup
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.125-126
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    • 2000
  • We report the use of fluorene based copolymers containing quinoline(POF66, PIF66) and pyridine(PFPV) units as electron transporting polymers for multi-layered LEDs. Double-layer device structure combining PIF66 as electron-transporting layer with the emissive MEHPPV showed a maximum quantum efficiency of 0.03%, which is 30 fold increased compared with ITO/MEHPPV/Al single-layer device. PFPV layer increased the quantum efficiency up to 0.1% in the device structure of ITO/(P-3:PVK)/PFPV/Al. The ETL with the electron deficient moiety improved the LED performance by the characteristics of electron transporting as well as hole blocking between emissive layer and metal cathode.

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Copolymerization of Ethylene and Cycloolefin with Metallocene Catalyst : III. Effect of ${\alpha}$-Olefin Addition (메탈로센 촉매를 이용한 에틸렌과 시클로올레핀의 공중합 : III. ${\alpha}$-올레핀 첨가의 영향)

  • Lee, Dong-Ho;Lee, Jo-Hoon;Kim, Hyun-Joon;Kim, Woo-Sik;Min, Kyung-Eun;Park, Lee-Soon;Seo, Kwan-Ho;Kang, Inn-Kyu
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.468-475
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    • 2001
  • For copolymerization of ethylene and norbornene initiated by various metallocene catalysts such as $rac-Et(Ind)_2ZrCl_2,\;rac-Me_2Si(Ind)_2ZrCl_2,\;rac-Me_2Si(Cp)_2ZrCl_2,\;and\;(n-BuCp)_2ZrCl_2$ with modified methylaluminoxane(MMAO) cocatalyst, the ${\alpha}$-olefins such as 1-hexene(H), 1-octene and 1-decene were added as a 3rd monomer. In this situation, the effects of the polymerization condition, the catalyst structure as well as the structure and the amount of added ${\alpha}$-olefin on the catalyst activity as well as the properties and structure of polymer were examined. As results, it was found that the catalyst activity and thermal property of polymer depended on not only catalyst structure but also ${\alpha}$-olefin structure. For $rac-Et(Ind)_2ZrCl_2/MMAO$ catalyst system, it was possible to get high activity and controllable $T_g$ of polymer. Among ${\alpha}$-olefins, H as a 3rd monomer exhibited the maximum enhancement in catalyst activity.

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Design of Electroluminescent Polymer for Polymer Light Emitting Diode

  • Chen, Show-An
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.19-20
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    • 2006
  • We report the design of electroluminescent conjugated polymers for high efficiency, turn-on voltage, color Tuning, and easy processing. Three approaches for the design are reported, being: (1) single chain consideration, (2) supramolecular structure consideration, and (3) conformation manipulation. Two polymer systems are to be reported, being fluorene-based and carbazole-based conjugated polymers.

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Mechanical Properties and Failure Mechanism of the Polymer Composite with 3-Dimensionally Stitched Woven Fabric

  • Lee, Geon-Woong;Park, Joong-Sik;Lee, Sang-Soo;Park, Min;Kim, Junkyung;Choe, Chul-Rim;Soonho Lim
    • Macromolecular Research
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    • v.11 no.2
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    • pp.98-103
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    • 2003
  • The mechanical properties and failure mechanisms of through-the-thickness stitched plain weave glass fabric/polyurethane foam/epoxy composites were studied. Hybrid composites were fabricated using resin infusion process (RIP). Stitched sandwich composite increased drastically the flexural properties as compared with the unstitched fabrics. The breaking of stitching yarns was observed during the flexural test and this failure mode yielded relatively high flexural properties. Composites with stitched sandwich structure improved the mechanical properties with increasing the number of stitching yarns. From this study, it was concluded that proper combination of stitching density and types of stitching fiber is important factor for through-the-thickness stitched composite panels.

Morphology and Crystallization in Mixtures of Poly(methyl methacrylate)-Poly(pentafluorostyrene)-Poly(methyl methacrylate) Triblock Copolymer and Poly(vinylidene fluoride)

  • Kim, Geon-Seok;Kang, Min-Sung;Choi, Mi-Ju;Kwon, Yong-Ku;Lee, Kwang-Hee
    • Macromolecular Research
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    • v.17 no.10
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    • pp.757-762
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    • 2009
  • The micro domain structures and crystallization behavior of the binary blends of poly(methyl methacrylate)-b-poly(pentafluorostyrene)-b-poly(methyl methacrylate) (PMMA-PPFS-PMMA) triblock copolymer with a low molecular weight poly(vinylidene fluoride) (PVDF) were investigated by small-angle X-ray scattering (SAXS), small-angle light scattering (SALS), transmission electron microscopy (TEM), optical microscopy, and differential scanning calorimetry (DSC). A symmetric, PMMA-PPFS-PMMA triblock copolymer with a PPFS weight fraction of 33% was blended with PVDF in N,N-dimethylacetamide (DMAc). In the wide range of PVDF concentration between 10.0 and 30.0 wt%, PVDF was completely incorporated within the PMMA micro domains of PMMA-PPFS-PMMA without further phase separation on a micrometer scale. The addition of PVDF altered the phase morphology of PMMA-PPFS-PMMA from well-defined lamellar to disordered. The crystallization of PVDF significantly disturbed the domain structure of PMMA-PPFS-PMMA in the blends, resulting in a poorly-ordered morphology. PVDF displayed unique crystallization behavior as a result of the space constraints imposed by the domain structure of PMMA-PPFS-PMMA. The pre-existing microdomain structures restricted the lamellar orientation and favored a random arrangement of lamellar crystallites.