• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.61.2-61.2
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• 2015

In the past decades, green energy, such as solar energy, wind power, hydropower, biomass energy, geothermal energy, and so on, has been widely investigated and developed to solve energy shortage. Recently, organic solar cells have attracted much attention, because they have many advantages, including low-cost, flexibility, light weight, and easy fabrication [1-3]. Organic solar cells are as a potential candidate of the next generation solar cells. In this abstract, to improve the power conversion efficiency and the stability, the inverted polymer solar cells with various structures were developed [4-6]. The novel cell structures included the P3HT:PCBM inverted polymer solar cells with AZO nanorods array, with pentacene-doped active layer, and with extra P3HT interfacial layer and PCBM interfacial layer. These three difference structures could respectively improve the performance of the P3HT:PCBM inverted polymer solar cells. For the inverted polymer solar cells with AZO nanorods array as the electronic transportation layer, by using the nanorod structure, the improvement of carrier collection and carrier extraction capabilities could be expected due to an increase in contact area between the nanorod array and the active layer. For the inverted polymer solar cells with pentacene-doped active layer, the hole-electron mobility in the active layer could be balanced by doping pentacene contents. The active layer with the balanced hole-electron mobility could reduce the carrier recombination in the active layers to enhance the photocurrent of the resulting inverted polymer solar cells. For the inverted polymer solar cells with extra P3HT and PCBM interfacial layers, the extra PCBM and P3HT interfacial layers could respectively improve the electron transport and hole transport. The extra PCBM interfacial layer served another function was that led more P3HT moving to the top side of the absorption layer, which reduced the non-continuous pathways of P3HT. It indicated that the recombination centers could be further reduced in the absorption layer. The extra P3HT interfacial layer could let the hole be more easily transported to the MoO3 hole transport layer. The high performance of the novel P3HT:PCBM inverted polymer solar cells with various structures were obtained.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05b
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• pp.1-8
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• 2004

Ion-conducting polymer electrolyte membranes (PEMs) have recently used in developing fuel cell or solar cell for portable, mobile and residential applications [1]. Polymer electrolyte membrane fuel cell (PEMFC), direct methanol fuel cell (DMFC), alkaline electrolyte fuel cell (AFC) and dye-sensitized solar cell have been employing the ion-conducting PEMs to complete their electrical circuits to produce electricity.(omitted)

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.398-401
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• 2008

Inkjet printing is commonly used in the controlled deposition of solutions of functional materials in specific locations on a substrate, and it can provide easy and fast deposition of polymer films over a large area. which could become a way to manufacturer low cost solar cells. In the present study, inkjet printing technology is adopted to deposit functional layers of PEDOT/PSS solutions and P3HT/PCBM blends for organic solar cell. The results show that merging of separately deposited ink droplets into a continuous, pinhole-free organic thin film could be achieved by a balance between ink property and substrate treatment. As a result, a power conversion efficiency of 2.0% has been accomplished a solar cells applying inkjet technology.

• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2835-2838
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• 2013

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.123.2-123.2
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• 2007

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.9
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• pp.589-594
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• 2016

P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.318-318
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• 2010

We present the effect of interlayers of polymer tandem solar cells on their photovoltaic performance. P-type and n-type interlayers are essential for the series-connection of the subcells and enable to form the tandem cell architecture by the solution processing. In this study, we use PEDOT:PSS, nanocrystalline $TiO_2$, and blends of semiconducting polymers and fullerene derivatives as a hole transporting layer, electron transporting layer, and photoactive layers, respectively. We show that photovoltaic performances of polymer tandem solar cells depending on various PEDOT:PSS layers with the different electric conductivity and the various $TiO_2$ layer thickness.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.484.2-484.2
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• 2014

There are many efforts to improving the power conversion efficiencies (PCEs) of dye-sensitized solar cells (DSCs). Although DSCs have a low production cost, their low PCE and low thermal stability have limited commercial applications. This study describes the preparation of a novel multifunctional polymer gel electrolyte in which a cross-linking polymerization reaction is used to encapsulate $TiO_2$ nanoparticles toward improving the power conversion efficiency and long-term stability of a quasi-solid state DSC. A series of liquid junction dye-sensitized solar cells (DSCs) was fabricated based on polymer membrane encapsulated dye-sensitized $TiO_2$ nanoparticles, prepared using a surface-induced cross-linking polymerization reaction, to investigate the dependence of the solar cell performance on the encapsulating membrane layer thickness. The ion conductivity decreased as the membrane thickness increased; however, the long term-stability of the devices improved with increasing membrane thickness. Nanoparticles encapsulated in a thick membrane (ca. 37 nm), obtained using a 90 min polymerization time, exhibited excellent pore filling among $TiO_2$ particles. This nanoparticle layer was used to fabricate a thin-layered, quasi-solid state DSC. The thick membrane prevented short-circuit paths from forming between the counter and the $TiO_2$ electrode, thereby reducing the minimum necessary electrode separation distance. The quasi-solid state DSC yielded a high power conversion efficiency (7.6/8.1%) and excellent stability during heating at $65^{\circ}C$ over 30 days. These performance characteristics were superior to those obtained from a conventional DSC (7.5/3.5%) prepared using a $TiO_2$ active layer with the same thickness. The reduced electrode separation distance shortened the charge transport pathways, which compensated for the reduced ion conductivity in the polymer gel electrolyte. Excellent pore filling on the $TiO_2$ particles minimized the exposure of the dye to the liquid and reduced dye detachment.

• Proceedings of the Materials Research Society of Korea Conference
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• 2008.05a
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• pp.15.1-15.1
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• 2008

• Polymer Science and Technology
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• v.17 no.4
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• pp.430-435
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• 2006