• Title/Summary/Keyword: polymer material

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Effect of polymer addition on air void content of fine grained concretes used in TRCC

  • Daskiran, Esma Gizem;Daskiran, Mehmet Mustafa;Gencoglu, Mustafa
    • Computers and Concrete
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    • v.20 no.2
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    • pp.165-176
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    • 2017
  • Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

Fabrication and Characterization of Ag Nanoparticle Dispersed Polymer Nanofiber and Ag Nanofiber Using Electrospinning Method (전기방사법을 이용한 Ag 나노입자 분산 고분자 나노파이버와 Ag 나노파이버 제조 및 특성 평가)

  • Kim, Hee-Taik;Hwang, Chi-Yong;Song, Han-Bok;Lee, Kun-Jae;Joo, Yeon-Jun;Hong, Seong-Jei;Kang, Nam-Kee;Park, Seong-Dae;Kim, Ki-Do;Cho, Yong-Ho
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.114-118
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    • 2008
  • Functional nanomaterial is expected to have improved capacities on various fields. Especially, metal nanoparticles dispersed in polymer matrix and metal nanofiber, one of the functional nanomaterials, are able to achieve improvement of property in the electric and other related fields. In this study, the fabrication of metal (Ag) nanoparticle dispersed nanofibers were attempted. The Ag nanoparticle dispersed polymer nanofiber and Ag nanofiber were fabricated by electrospinning method using electric force. First, PVP/$AgNO_3$ nanofibers were synthesized by electrospinning in $18{\sim}22kV$ voltage with the starting materials (Ag-nitrate) added polymer (PVP; poly (vinylpyrrolidone)). Then Ag nanoparticle dispersed polymer nanofibers were fabricated to reduce hydrogen reduction at $150^{\circ}C$ for 3hr. And Ag nanofibers were synthesized by the decomposited of PVP at $300{\sim}500^{\circ}C$ for 3hr. The nanofibers were analyzed by XRD, TGA, FE-SEM and TEM. The experimental results showed that the Ag nanofibers could be applied in many fields as an advanced material.

Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Effect of Allyl Modified/Silane Modified Multiwalled Carbon Nano Tubes on the Electrical Properties of Unsaturated Polyester Resin Composites

  • Swain, Sarojini;Sharma, Ram Avatar;Patil, Sandip;Bhattacharya, Subhendu;Gadiyaram, Srinivasa Pavan;Chaudhari, Lokesh
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.267-272
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    • 2012
  • Considering the properties of the carbon nano tubes (CNT), their inclusion into the polymer matrix vastly increases the properties of the resultant composite. However, this is not the case due to the poor interfacial adhesion of the CNT and the polymer matrix. The present approach focuses on increasing the interaction between the polymer matrix and the CNT through the chemical modification of the CNT resulting in allyl ester functionalized carbon nanotubes (ACNT) and silane functionalized carbon nano tubes (SCNT) which are capable of reacting with the polymer matrix during the curing reaction. The addition of ACNT/SCNT into unsaturated polyester resin (UPR) resulted in the improvement of the electrical properties of resulted nanocomposites in comparison to the CNT. The surface resistivity, volume resistivity, dielectric strength, dry arc resistivity, and the comparative tracking index of the nanocomposites were significantly improved in comparison to CNT. The chemical modification of CNT was confirmed via spectroscopy.

A SHIELDING EFFECTIVENESS of COATED CONDUCTIVE POLYMER for ELECTROMAGNETIC SHIELDING (전자파 차폐용 전도성 고분자 코팅재료의 차폐효율)

  • 최재옥;임윤석;장용무;서광석;구자윤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.624-627
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    • 2000
  • The shielding effectiveness of materials is determined by measuring the ratio of the incident electromagnetic power which passes through the material under test. To measure the shielding effectiveness materials made by conductive polymer, the flanged coaxial transmission-line holder based in ASTM D4935-89, was fabricated. This apparatus has dynamic range between 95dB and 120dB in frequency range of 50Mhz-2Ghz. Furthermore, this system can be utilized to measure the shielding effectiveness of materials produced by conductive polymer and can be adapted for shielding materials design.

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Development of Polymer Bushing for Overhead Line Switch (가공개폐기용 폴리머 부싱 개발)

  • 최경선;주종민;이철호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.787-790
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    • 2001
  • Polymer bushing used for overhead line switch was designed and investigated. Requirements of electrical ratings such as partial discharge, ac withstand voltage, impulse voltage and material properties were proposed in accordance with IEEE 386 and pre-standard (PS) 151-146∼147, 170∼180 of KEPCO. The polymer bushing consists of an internal epoxy bushing and external housing made of EPDM rubber. The rubber housing was molded with mold cone. Therefore, the polymer bushing offers several advantages like light weight, good sealing properties, easy installation and excellent performance in contamination. Electric field analysis was also introduced in order to verify the reliability of the design.

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Basic Mix Proportions of Antiwashout Underwater Polymer Cement Mortar as a Repair Material (보수재료로서 수중불분리 폴리머 시멘트 모르타르의 기초적 배합)

  • Jo, Young-Kug
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.193-194
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    • 2019
  • The purpose of this study is to design the basic mix proportions of antiwashout underwater polymer cement mortar as a repair material. The antiwashout underwater polymer cement mortars are prepared with various mix proportions using three type polymer dispersions without or with antifoamer. From the test results, the whole antiwashout underwater polymer cement mortars can be cast underwater without segregation like plain mortar. It is apparent that the flexural strength of antiwashout underwater SBR cement mortars with antifoamer at polymer- cement ratios of 5% and 10% is higher than that of plain mortar irregardless of a little low compressive strength.

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Flexural Properties of Reinforced Steel and GFRP Reinforced Polymer Concrete T-Beams (철근 및 GFRP 보강 폴리머 콘크리트 T형 보의 휨 특성)

  • Yeon Kyu Seok;Kweon Taek Jeong;Jeong jung Ho;Jin Xing Qi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.695-698
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    • 2004
  • Recently, the usage of polymer concrete mortar gathering an interest as a new construction material rapidly increases inside and outside of the country because it is an environment-friendly and endurable material. However, up to these days, the researches about the polymer composite have not been satisfactorily conducted. The polymer concrete is superior to the general cement materials in the properties of strength and durability while it is inferior in elastic modulus. Because that the members using the polymer concrete have therefore higher strength and ductility than the members of general cement concrete, an analysis equation of high-strength cement concrete can be referenced but it is not applied for the researches about the polymer concrete members. In this study, the flexural properties of T-shaped beam of the steel- and GFRP-reinforced polymer concrete are analyzed to examine the suggested analysis equation. Results of this experimental researches are to be used as the basic data in a structural design of the polymer concrete.

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Behavior of $Li^{+}$ in PAN/PVDF based Polymer Electrolyte for Lithium Polymer Battery (리튬 폴리머전지용 PAN/PVDF계 고분자 전해질의 리튬 이온 거동)

  • 이재안;김상기;김종욱;구할본;박계춘
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.540-543
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PAN/PVDF electrolytes as a function of a mixed ratio were reported for PAN/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PAN/PVDF, plasticizer and Li salt. The conductivity of PAN/PVDF electrolytes was $10^{-3}$S/cm. $PAN_{10}$$PVDF_{10}$$LiClO_4$$PC_{5}$$EC_{5}$ electrolyte has the better conductivity compared to others. The interfacial resistance behavior between the lithium electrode and PAN/PVDF based polymer electrolyte has also been investigated and compare with that between the lithium electrode and the PAN/PVDF based polymer electrolyte.

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Flashover Failure of Polymer Insulator in Distribution Lines (배전용 폴리머애자의 섬락고장)

  • 한재홍;이병성;김찬영;윤태상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.767-770
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    • 2000
  • This study was investigated for searching a cause of flashover failure of polymer insulator and preparing countermeasures. Hydrophobicity, microstructure and chemical structural change of polymer weathershed were studied by polymer characterization methods. In addition, the electrical properties such as power frequency dry flashover voltage/impulse voltage tests, contamination characteristics were carried out. The hydrophobicity of polymer weathershed was decreased significantly and cracks were observed on the surface. Also, the electrical characteristics did not satisfy the KEPCO specification. The failed polymer insulators showed the more leakage current than 4 years service-aged ones. From the result, it can be concluded that the flashover failure of polymer insulator was attributed to the surface aging and severe contamination.

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