• Journal of Photoscience
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• 제10권1호
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• pp.97-104
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• 2003

The excitation wavelength dependence of laser ablation dynamics of an azobenzene-containing urethane-urea copolymer film was investigated by measuring the laser fluence dependence of etch depth, transient absorbance change at each excitation wavelength, and transient absorption spectra. Moreover expansion/contraction dynamics was studied by applying nanosecond time-resolved interferometry. The threshold was determined at several excitation wavelengths from etch depth measurement, while time-integrated absorbance was obtained under excitation conditions. The photon energy required to remove the topmost of surface layer of the film did not .depend on excitation wavelength, and the penetration depth of excitation pulse dominated the etch depth. When the excitation wavelength was longer than 500 nm, permanent swelling was clearly observed but not for shorter wavelength excitation. In the latter case, photoisomerization occurred during excitation and the following photoreduction may play an important role. On the basis of the observations made in this study, a photochemical and photothermal mechanisms can explain mostly the short and long wavelength excitation results, respectively.

• Journal of the Korean Wood Science and Technology
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• 제23권4호
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• pp.1-9
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• 1995

This study was carried out to experiment the dimensional stabilization of woods of red pine (Pinus densiflora S. et Z.) and sugi(Cryptomeria japonica D. Don) by vacuum impregnation of polyehtylene glycols(PEG) with mo. wt. 200, 400, 600, 1000; polypropylene glycols (PPG) with mo. wt. 425,725 ; PEG-acryloylates, and PPG-acryloylates synthesized, and then by water soaking. The results obtained are as follows: 1. The density of sapwood and heartwood was different from each other in both species. 2. The PEG and PEG-macromers with lower molecular weight by impregnation has increased the density of wood specimens more higher, thereby caused their higher volume expansion, and those with higher molecular weight than 600 has tended to down their density increment. 3. Before and after water soaking, the density decrease of specimen impregnated was high in woods impregnated with simple PEG and PPG, while lower in specimens impregnated with PEG-macromers and PPG-macromers. 4. So PEG-macromer was expected to hold the original dimension of decayed wood for antiques, but it was necessary to develop another penetration method as well as aqueous solvent.

• Geomechanics and Engineering
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• 제22권4호
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• pp.329-337
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• 2020

Polyacrylamide (PAM) possesses high water absorption capacity and a unique pH-dependent behavior that confer large potential to enhance the engineering performance of clays. In this study, calcium bentonite was treated with a nonionic PAM. Flexible-wall permeability test and the consolidation test were performed at different pH values to evaluate the effects of PAM treatment on the hydraulic and consolidation properties. Test results demonstrate that index properties are affected by the adsorbed PAM on clay surface: a decrease in specific gravity, a decrease in net zeta potential, and an increase in liquid limit are observed due to the PAM treatment. At a given pH, the compressibility of the treated clay is greater than that of the untreated clay. However, the compression indices of untreated and treated clays can be expressed as a single function of the initial void ratio, regardless of pH. Hydraulic conductivity is reduced by PAM treatment about 5 times at both neutral and alkaline pH conditions under similar void ratios, because of the reduction in size of the water flow channel by PAM expansion. However, at acidic pH, the hydraulic conductivity of the treated clay is slightly higher than the untreated clay. This reflects that the treated bentonite with PAM can be beneficially used in barrier system for highly alkaline residues.

• Composites Research
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• 제27권6호
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• pp.231-235
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• 2014

오토클레이브 성형은 성형제품의 품질은 우수하나 생산비용이 비싸다는 단점이 있다. 생산비용 중에서도 큰 비중을 차지하는 것이 성형툴의 제작공정이다. 따라서 본 연구에서는 생산비용 절감을 위한 선행 연구로서 성형툴의 재질 및 표면상태에 따라 L-shape 제품의 성형후 Spring-in을 Abaqus user subroutine을 이용하여 계산하였고, 열팽창계수와 마찰계수에 따른 결과를 나타내었다. 또한 성형툴 제작시 재질 및 표면상태의 기준점을 제시하여 생산비용을 줄이는데 기여하고자 한다.

• Journal of Advanced Marine Engineering and Technology
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• 제20권2호
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• pp.75-75
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• 1996

The rapid expansion for the auto-industry and the worldwide trend toward non-asbestos friction materials for brake lining force our industry to transfer into non-asbestos ones from asbestos-based friction materials. Furthermore, it is imperative for the friction materials to have technological excellence and lower production cost to be competitive in the world market. There is no known theoretical procedures to formulate friction materials. It, rather, depends on the trial and error process. Thus, it is quite clear how important it is to accumulate the know-how on the formulation and manufacturing the friction material. This study concerns the practical ways of conceptualizing the formulation and optimizing the manufacturing process. This study focused on the development of formulation for non-asbestos friction material as well as deriving the physical properties of the trial product to prove its validity and applicability. Elaboration of the formula and optimizing scheme of the manufacturing process to get better quality are also sought. Physical properties were obtained by constant velocity test dynamotest, hardness test and strength test. Differential scanning calorimeter was also used to analyze the thermal reactions of organic constituents, microstructures, bond effects, and degree of mixture.

• Journal of Advanced Marine Engineering and Technology
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• 제20권2호
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• pp.7-14
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• 1996

The rapid expansion for the auto-industry and the worldwide trend toward non-asbestos friction materials for brake lining force our industry to transfer into non-asbestos ones from asbestos-based friction materials. Furthermore, it is imperative for the friction materials to have technological excellence and lower production cost to be competitive in the world market. There is no known theoretical procedures to formulate friction materials. It, rather, depends on the trial and error process. Thus, it is quite clear how important it is to accumulate the know-how on the formulation and manufacturing the friction material. This study concerns the practical ways of conceptualizing the formulation and optimizing the manufacturing process. This study focused on the development of formulation for non-asbestos friction material as well as deriving the physical properties of the trial product to prove its validity and applicability. Elaboration of the formula and optimizing scheme of the manufacturing process to get better quality are also sought. Physical properties were obtained by constant velocity test dynamotest, hardness test and strength test. Differential scanning calorimeter was also used to analyze the thermal reactions of organic constituents, microstructures, bond effects, and degree of mixture.

• International Journal of Concrete Structures and Materials
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• 제18권3E호
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• pp.145-150
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• 2006

An experiment with the objective of providing guidelines for joint depth determination and timing of contraction joint sawcutting to avert uncontrolled cement concrete pavement cracking has been conducted. Theoretical analysis and laboratory tests were performed to help in understanding and analyzing the field observation. Using two-dimensional elastic fracture mechanics, the influence of several parameters on crack propagation was delineated by a parametric study, involving initial notch ratio, joint spacing, Young's modulus and thermal expansion coefficient of concrete, temperature gradient, and modulus of subgrade reaction. Bimaterials made of rock plus cement mortar and rock plus polymer mortar were applied to the concrete in a field test section, and they were subjected to fracture tests. These tests have shown that fracture mechanics is a powerful tool not only in judging the quality of the jointed cement concrete pavement but also in providing a criterion for crack propagation and delamination. Based on fracture mechanics, a method is proposed to determine the joint depth, sawcut timing, and spacing of the jointed cement concrete pavement. This method has successfully been applied to a test section in Seohaean expressway. This study also summarizes the research results obtained from a field test for jointed plain concrete pavement, which was also carried out on the Seohaean expressway.

• Applied Microscopy
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• 제43권4호
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• pp.155-163
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• 2013

Meta-kaolin (MK) and blast furnace slag (BS) were used as raw materials with NaOH and sodium silicate as alkali activators for making geo-polymers. The compressive strength with respect to the various pre-curing conditions was investigated. In order to improve the recycling rate of BS while still obtaining high compressive strength of the geo-polymers, it was necessary to provide additional CaO to the MK by adding BS. The specimens containing greater amounts of BS can be applied to fields that require high initial compressive strength. Alkali activator(s) are inevitably required to make geo-polymers useful. High temperature pre-curing plays an important role in improving compressive strength in geo-polymers at the early stage of curing. On the other hand, long-term curing produced little to no positive effects and may have even worsened the compressive strength of the geo-polymers because of micro-structural defects through volume expansion by high temperature pre-curing. Therefore, a pre-curing process at a medium range temperature of $50^{\circ}C$ is recommended because a continuous increase in compressive strength during the entire curing period as well as good compressive strength at the early stages can be obtained.

• Macromolecular Research
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• 제17권6호
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• pp.411-416
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• 2009

The color stabilization of antimicrobial blends was studied by using poly(hexamethylene guanidine) phosphate (PHMG) as a highly efficient biocidal and nontoxic agent. The Taguchi method was used to determine the optimum conditions for the blending of PHMG in polypropylene (PP) matrix. To improve the yellowing phenomena, two kinds of stabilizer were used together: tetrakis[methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate)](IN1010) from phenol and tris(2,4-di-t-butylphenylphosphite) (IF168) from phosphorus. According to blend composition and mixing condition, six factors were chosen, with five levels being set for each factor. The orthogonal array was selected as the most suitable for fabricating the experimental design, L25, with 6 columns and 25 variations. The-smaller-the-better was used as an optimization criterion. The optimum conditions for these parameters were 10 phr for PHMG, 2 phr for IN1010, 1 phr for IF168, 10 min for mixing time, $210^{\circ}C$ for mixing temperature, and 30 rpm for rotation speed. Under these conditions, the yellowness index of the blend was 1.52. The processibility of the blends was investigated by Advanced Rheometric Expansion System (ARES). The blend with 0.5 w% PHMG content, diluted with PP, exhibited an antimicrobial characteristic in the shake flask method.

• 한국건설순환자원학회논문집
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• 제3권1호
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• pp.65-71
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• 2007

Since pop-outs are occurred recently on concrete surface occasionally, it is needed to find out accurate causes and to suggest appropriate methods. On this study, it is investigated the occurrence mechanism of pop-outs caused by electric arc furnace Oxidizing slags as fine aggregate for concrete. As a result, it is investigated the cause of pop-outs that extremely small quantities of free CaO and free MgO in the electric furnace slag react with water to produce $Ca(OH)_2$ and $Mg(OH)_2$, so that their volumes are expanded and erupted about two times. As a resolution, it is needed to remove the potential cause of expansion by replacing the deteriorated concrete section up to the depth to secure the safe of structural element with repairing polymer mortar, especially more than 50MPa.