• 제목/요약/키워드: polyester binder

검색결과 59건 처리시간 0.021초

폴리에스터 폴리머 콘크리트의 워커빌리티 특성 (Workability Characteristics of Polyester Polymer Concrete)

  • 연규석;김광우;이봉학
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1991년도 봄 학술발표회 논문집
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    • pp.87-92
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    • 1991
  • Since the material property of binder in polyester polymer concrete has a viscous mechanism, the workability of polyester polymer concrete mixture showed different characteristics from that of cement concretes. Therefore, this study was devised to evaluate workability characteristics of polyester polymer concrete using slump and flow tests. Study results showed that the test temperature and ST/UP ratio were the most dominantly affecting factor on the viscosity of binder, and viscosity of the binder was strongly correlated with the workability of polyester polymer concrete mixture.

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Fluorene 단위 구조를 함유한 감광성 고분자의 합성 및 LCD 컬러필터용 카본블랙 포토레지스트로의 응용 (Synthesis of Fluorene-containing Photosensitive Polymer and Its Application to the Carbon Black-based Photoresist for LCD Color-Filter)

  • 김주성;박겸재;이동근;배진영
    • 폴리머
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    • 제35권1호
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    • pp.87-93
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    • 2011
  • 본 연구에서는 LCD 컬러필터 레지스트용 fluorene 단위 구조를 가지는 다기능 바인더 고분자를 개발하여 카본블랙 기반 감광성 레지스트(CBR)를 제조하고 블랙 매트릭스(BM)에 적용하였다. 다기능 바인더 고분자를 얻기 위해 bisphcnol fluorene epoxy acrylate를 함유한 불포화 폴리에스터(BFEA-polyester)를 합성하였으며 이는 $^1H$ NMR, GPC 및 FTIR을 이용하여 분석하였다. 합성된 BFEA-polyester 바인더 고분자를 상업용 아크릴 바인더와 비교 평가하기 위하여 각각 CBR 제조 후 BM 리소그래피 테스트를 수행하였다. 그 결과, 본 연구에서 합성된 BFEA-polyester 바인더 고분자는 적합한 광경화 반응성과 알칼리 용해성을 가질 뿐만 아니라 기존 아크릴 바인더보다 더 우수한 공정 마진, 패턴 특성 및 유리 가판에 대한 접착력을 나타내었다.

산업부산물을 이용한 강섬유보강 폴리에스터 수지복합체의 제조 및 역학적 특성 (Fabrication and Mechanical properties of Steel Fiber Reinforced Polyester Resin Composites Utilizing by-Products (Fly Ash))

  • 박승범;윤의식
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1992년도 봄 학술발표회 논문집
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    • pp.35-40
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    • 1992
  • Results of an experimental study on the manufacture, the workability and mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products are presented in this paper. The fly ash polyester resin composites using steel fiber, fly ash and calcium carbonic acid (CaCo3), unsaturated polyester resin, styrene monomer, cobalt octate and methyl ethyl ketone peroxide, fine and coarse aggregates are prepared with various filler~binder rations, binder rates and mixing conditions. As a test results, the workability of steel fiber reinforced polyester resin composites are considerably dropped with increasing fly ash-binder ratio and steel fiber volume. And compressive, flexural strength and bending toughness of the composites are remarkably improved with augmenting fiber contents.

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MMA 개질 폴리머 콘크리트의 작업성 및 역학적 성질 (Workability and Strength Properties of MMA-Modified Polyester Polymer Concrete)

  • 연규석;주명기;유근우;최종윤;김남길
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.769-774
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    • 2002
  • In this study, methyl methacrylate (MMA)- modified polyester polymer concrete, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the fundamental properties of the polymer concrete such as workability and strength were surveyed. The experimental results showed that the workability was remarkably improved as the MMA contents increased, and the filler-binder ratio was turned out to be important factor for the workability. Slump prediction equation was derived by the regression analysis based on MMA content and filler-binder ratio. Furthermore, early-age strength was greater when the MMA content were increased in the range of 20-40 % but the strength rather showed a tendency of decrease when the MMA content was 50 %.

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마이크로캡슐을 이용한 방향가공시 바인더 농도 및 섬유 종류에 따른 물성 (Effect of Binder's Concentration and Fiber Type on Mechanical Properties of Fragrant Fabrics)

  • 김혜림;송화순
    • 한국의류학회지
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    • 제28권7호
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    • pp.1029-1036
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    • 2004
  • The fragrant fabrics were prepared by treatment with eucalyptus microcapsules. 100% cotton fabric, 100% polyester fabric and 100% wool fabric were used as test specimens. Using pad-dry-cure method, microcapsules were attached on each specimen by acrylic binder under conditions of varying concentration. Surface property, stiffness, and air permeability of fragrant fabrics were evaluated. As increasing concentration of binder, add-on yield was increased. Add-on yield was decreased with increasing laundering cycle, especially in polyester fabric. As the concentration of binder was increased, the properties of stiffness and air permeability were decreased. Also it fumed out that pad-dry-cure method was not suitable to polyester fabric.

불포화폴리에스테르 수지의 형태에 따른 폴리머 모르타르 복합재료의 내열수성 (Hot Water Resistance of Polymer Mortar Composites Depending on Unsaturated Polyester Resin Types)

  • 황의환;송민규;김용연
    • 공업화학
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    • 제29권2호
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    • pp.201-208
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    • 2018
  • 올소-타입 불포화폴리에스테르 수지와 이소-타입 불포화폴리에스테르 수지를 합성하여 폴리머 모르타르 복합재료의 폴리머 결합재로 사용하였다. 불포화폴리에스테르 수지의 희석제로는 스티렌 모노머와 아크릴로니트릴을 사용하였고, 경화제로 methyl ethyl ketone peroxide (MEKPO), 가속제로 cobalt octoate (CoOc)를 사용하였다. 수지의 형태와 희석제의 종류에 따라 4종의 불포화폴리에스테르 수지를 제조하여 공시체 제조의 폴리머 결합재로 사용하였다. 폴리머 결합재의 첨가량에 따라 총 16종의 폴리머 모르타르 공시체를 제작하여 내열수성 시험을 행한 후 압축 및 휨강도시험, 세공분석 및 SEM 분석을 실시하였다. 시험결과, 이소-타입 불포화폴리에스테르 수지를 폴리머 결합재로 사용한 공시체가 올소-타입 불포화폴리에스테르 수지를 사용한 공시체보다 더 우수한 강도를 나타내었다. 내열수성시험 후에 측정한 총세공량과 세공의 평균직경은 시험 전에 측정한 값에 비하여 감소되었다. 내열수성시험 전에 관찰한 사진에서 폴리머 결합재와 충전재 및 잔골재가 co-matrix 상으로 견고하게 결합되어 있었으나 내열수성시험 후에 관찰한 사진에서는 폴리머 결합재가 대부분 분해되어 있는 것을 관찰할 수 있었다.

실크 세리신을 이용한 폴리에스테르의 쾌적가공 (The Skin Care Finishing of Polyester by Silk Sericin)

  • 한대만;배도규
    • 한국잠사곤충학회지
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    • 제41권3호
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    • pp.185-195
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    • 1999
  • This study was carried out to improve the skin care property of the polyester fabric by finishing with sericin. It was known that skin care function, anti-oxidation, anti-tyrosinase activity and anti-elastase activity can be achieved from sericin finish. But, the moisture regain of the finished fabric was measured simply, because the major cause of the discomfort from polyester fabric has been anounced to be wetness. The effects of various treatment conditions on the properties of the finished fabric were measured, and obtained results were as follows: 1. The moisture regain at 40$^{\circ}C$ 90% RH were increased with the sericin uptake increasing. while it was not significant for the effects on the moisture regain depending on the treatment conditions like the degree of polymerization and treatment concentration of the binder. The moisture release of the fabric having sericin uptake 1%, 2% was faster than non treated fabric. The change of the moisture regain of the finished fabric from 40$^{\circ}C$ 90% RH to room temperature was 4∼5 times higher than that of knitted cotton fabric. 2. The frictional static charge was decreased with the degree of polymerization of the binder increasing. While the sericin uptake and treatment concentration of the binder were not significant. 3. The whiteness value of the fabric was slightly decreased by finishing with sericin and binder. In that cases, W values of the finished fabrics were above 90 while that depending on the degree of polymerization of the binder was not significant. 4. The major cause of the yellowness of the finished fabric was proved to be catalyst. The yellowness of the finished fabric with sulfur containing catalyst was lower than that with amine group containing catalyst. 5. The effects of the treatment concentrations of the cross-linking agent, catalyst and drying time on the wash durability were not significant.

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온도와 결합재의 점도가 경량 폴리에스터 모르터의 컨시스턴시에 미치는 영향 (Effects of Temperature and Binder Viscosity on Consistency of Lightweight Polyester Mortars)

  • 이윤수;;;연규석
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 봄 학술발표회논문집(II)
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    • pp.713-718
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    • 1998
  • This paper deals with the consistency of fresh lightweight polyester mortars as high-performance or multifunctional building materials. Fresh lightweight polyester mortars using an unsaturated polyester resin, lightweight fillers and aggregate are mixed with various mix proportions, and tested for slump-flow and slump as a measure of consistency. At 10, 20 and 3$0^{\circ}C$, the influences of mix proportioning factors on the slump-flow and slump of the lightweight polyester mortars are examined, and the empirical equations for the slump predictions are successfully proposed.

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경량 폴리머 콘크리트의 난연성 및 동결융해 저항성 (Incombustibility and Freezing-Thawing Resistance of Lightweight Polymer Concrete)

  • 채경희;최예환;연규석;이윤수;주명기
    • 한국농공학회지
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    • 제45권1호
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    • pp.45-54
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    • 2003
  • The effects of binder content and silica sand content on the durability characteristics of lightweight polymer concretes are examined. As a result, the flame lingering times using unsaturated polyester resin and non-combustible polyester resin were 60∼120 and 0∼4 seconds respectively, and the combustion lengths were 9∼11 mm and 0∼3 mm, respectively. Thus it is believed that the lightweight polymer concrete was incombustible and the light weight polymer concrete in which non-combustible material was added was perfectly non-combustible. The percent of original mass of lightweight polymer concrete, according to the freezing-thawing experiment, was below 0.3 %, which was much less than that of cement concrete. The pluse velocity, for the case of the binder content 28 %, showed the minimum decreasing rate for the lightweight polymer concrete with silica sand content of 50 %. The higher the binder content, the greater the durability. That is much higher than other material and believed that the freezing-thawing was suppressed by a low absorption.

강섬유 보강 플라이애쉬.폴리에스터 수지복합체의 역학적 특성에 관한 실험적 연구 (An Experimental Study on the Mechanical Properties of Steel Fiber Reinforced Fly Ash.Polyester Resin Composites)

  • 박승범;조영찬
    • 콘크리트학회지
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    • 제5권4호
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    • pp.156-166
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    • 1993
  • 본 연구는 산업폐기물인 플라이애쉬를 충전재로 사용한 강섬유보강 폴리에스터 수지 복합체의 워커빌리티 및 그 역학적 특성을 구명하고, 그 제조방법을 실험적으로 검토한 것이다. 동복합체는 강섬유, 충전재(플라이애쉬, 중질탄산칼슘), 불포화 폴리에스터수지(스티타이렌 모노머), 경화촉진제(코발트옥테이트), 촉매(MEKPO) 및 굵은 골재와 잔골재를 사용하여 제조하였고, 배합조건별로 그 특성을 검토하였다. 연구결과, 플라이애쉬$\cdot$폴리에스터 수지복합체의 경우, 플라이애쉬-결합재비의 증가에 따라 압축, 인장, 휨강도 및 경화수축은 현저히 개선되었고 강섬유 보강 플라이애쉬$\cdot$폴리에스터 수지복합체의 경우 워커빌리티는 플라이해쉬-결합재비 및 강섬유혼입율 증가에 따라 저하하였으나, 압축, 휨강도 및 휨인성은 섬유혼입율 증가에 따라 현저히 증가되었다.