• Title/Summary/Keyword: polyester binder

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Workability Characteristics of Polyester Polymer Concrete (폴리에스터 폴리머 콘크리트의 워커빌리티 특성)

  • 연규석;김광우;이봉학
    • Proceedings of the Korea Concrete Institute Conference
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    • 1991.04a
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    • pp.87-92
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    • 1991
  • Since the material property of binder in polyester polymer concrete has a viscous mechanism, the workability of polyester polymer concrete mixture showed different characteristics from that of cement concretes. Therefore, this study was devised to evaluate workability characteristics of polyester polymer concrete using slump and flow tests. Study results showed that the test temperature and ST/UP ratio were the most dominantly affecting factor on the viscosity of binder, and viscosity of the binder was strongly correlated with the workability of polyester polymer concrete mixture.

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Synthesis of Fluorene-containing Photosensitive Polymer and Its Application to the Carbon Black-based Photoresist for LCD Color-Filter (Fluorene 단위 구조를 함유한 감광성 고분자의 합성 및 LCD 컬러필터용 카본블랙 포토레지스트로의 응용)

  • Kim, Joo-Sung;Park, Kyung-Je;Lee, Dong-Guen;Bae, Jin-Young
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.87-93
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    • 2011
  • We developed a fluorene-containing multifunctional binder polymer for LCD color filter resist, and employing the binder polymer, carbon black based black photoresist (CBR) was prepared in order to apply it to the black matrix (BM). To obtain the multifunction of the binder polymer, we synthesized bisphenol fluorene epoxy acrylate-containing unsaturated polyester and identified the binder polymer structure with $^1H$ NMR, GPC and FTIR. The corresponding BFEA-polyester binder polymer was compared with the commercially available acryl binder toward the application to the CBR. From the BM lithography test, we found that the synthesized BFEA-polyester binder had better photocrosslinking capability and alkali solubility. In addition, the newly developed binder gave a good process margin, good resolution and adhesion property on a glass substrate.

Fabrication and Mechanical properties of Steel Fiber Reinforced Polyester Resin Composites Utilizing by-Products (Fly Ash) (산업부산물을 이용한 강섬유보강 폴리에스터 수지복합체의 제조 및 역학적 특성)

  • 박승범;윤의식
    • Proceedings of the Korea Concrete Institute Conference
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    • 1992.04a
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    • pp.35-40
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    • 1992
  • Results of an experimental study on the manufacture, the workability and mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products are presented in this paper. The fly ash polyester resin composites using steel fiber, fly ash and calcium carbonic acid (CaCo3), unsaturated polyester resin, styrene monomer, cobalt octate and methyl ethyl ketone peroxide, fine and coarse aggregates are prepared with various filler~binder rations, binder rates and mixing conditions. As a test results, the workability of steel fiber reinforced polyester resin composites are considerably dropped with increasing fly ash-binder ratio and steel fiber volume. And compressive, flexural strength and bending toughness of the composites are remarkably improved with augmenting fiber contents.

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Workability and Strength Properties of MMA-Modified Polyester Polymer Concrete (MMA 개질 폴리머 콘크리트의 작업성 및 역학적 성질)

  • 연규석;주명기;유근우;최종윤;김남길
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.769-774
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    • 2002
  • In this study, methyl methacrylate (MMA)- modified polyester polymer concrete, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the fundamental properties of the polymer concrete such as workability and strength were surveyed. The experimental results showed that the workability was remarkably improved as the MMA contents increased, and the filler-binder ratio was turned out to be important factor for the workability. Slump prediction equation was derived by the regression analysis based on MMA content and filler-binder ratio. Furthermore, early-age strength was greater when the MMA content were increased in the range of 20-40 % but the strength rather showed a tendency of decrease when the MMA content was 50 %.

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Effect of Binder's Concentration and Fiber Type on Mechanical Properties of Fragrant Fabrics (마이크로캡슐을 이용한 방향가공시 바인더 농도 및 섬유 종류에 따른 물성)

  • 김혜림;송화순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.7
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    • pp.1029-1036
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    • 2004
  • The fragrant fabrics were prepared by treatment with eucalyptus microcapsules. 100% cotton fabric, 100% polyester fabric and 100% wool fabric were used as test specimens. Using pad-dry-cure method, microcapsules were attached on each specimen by acrylic binder under conditions of varying concentration. Surface property, stiffness, and air permeability of fragrant fabrics were evaluated. As increasing concentration of binder, add-on yield was increased. Add-on yield was decreased with increasing laundering cycle, especially in polyester fabric. As the concentration of binder was increased, the properties of stiffness and air permeability were decreased. Also it fumed out that pad-dry-cure method was not suitable to polyester fabric.

Hot Water Resistance of Polymer Mortar Composites Depending on Unsaturated Polyester Resin Types (불포화폴리에스테르 수지의 형태에 따른 폴리머 모르타르 복합재료의 내열수성)

  • Hwang, Eui-Hwan;Song, Min-Kyu;Kim, Yong-Yeon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.201-208
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    • 2018
  • The ortho- and iso- type unsaturated polyester resins were synthesized and used as a polymer binder of the polymer mortar composite. Styrene monomer and acrylonitrile were used as a diluent for the unsaturated polyester resin. Methyl ethyl ketone peroxide (MEKPO) and cobalt octoate (CoOc) were used as a curing agent and an accelerator, respectively. Four kinds of unsaturated polyester resins were prepared according to types of the resin and diluent, and used as a polymer binder in the preparation of the specimen. A total of 16 polymer mortar specimens were prepared according to the added amount of the polymer binder and subjected to a hot water resistance test, followed by compressive and flexural strength tests, and pore and SEM analyses. As a result, it was found that the strength of the specimen using the iso-type unsaturated polyester resin as the polymer binder was better than that of using the ortho-type unsaturated polyester resin. The total pore volume and diameter measured after the hot water resistance test were reduced compared to the values before the test. In the micrographs observed before the hot water resistance test, the polymer binder, filler and fine aggregate were firmly combined to the co-matrix, but the polymer binder was mostly decomposed in the micrographs observed after the test.

The Skin Care Finishing of Polyester by Silk Sericin (실크 세리신을 이용한 폴리에스테르의 쾌적가공)

  • 한대만;배도규
    • Journal of Sericultural and Entomological Science
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    • v.41 no.3
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    • pp.185-195
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    • 1999
  • This study was carried out to improve the skin care property of the polyester fabric by finishing with sericin. It was known that skin care function, anti-oxidation, anti-tyrosinase activity and anti-elastase activity can be achieved from sericin finish. But, the moisture regain of the finished fabric was measured simply, because the major cause of the discomfort from polyester fabric has been anounced to be wetness. The effects of various treatment conditions on the properties of the finished fabric were measured, and obtained results were as follows: 1. The moisture regain at 40$^{\circ}C$ 90% RH were increased with the sericin uptake increasing. while it was not significant for the effects on the moisture regain depending on the treatment conditions like the degree of polymerization and treatment concentration of the binder. The moisture release of the fabric having sericin uptake 1%, 2% was faster than non treated fabric. The change of the moisture regain of the finished fabric from 40$^{\circ}C$ 90% RH to room temperature was 4∼5 times higher than that of knitted cotton fabric. 2. The frictional static charge was decreased with the degree of polymerization of the binder increasing. While the sericin uptake and treatment concentration of the binder were not significant. 3. The whiteness value of the fabric was slightly decreased by finishing with sericin and binder. In that cases, W values of the finished fabrics were above 90 while that depending on the degree of polymerization of the binder was not significant. 4. The major cause of the yellowness of the finished fabric was proved to be catalyst. The yellowness of the finished fabric with sulfur containing catalyst was lower than that with amine group containing catalyst. 5. The effects of the treatment concentrations of the cross-linking agent, catalyst and drying time on the wash durability were not significant.

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Effects of Temperature and Binder Viscosity on Consistency of Lightweight Polyester Mortars (온도와 결합재의 점도가 경량 폴리에스터 모르터의 컨시스턴시에 미치는 영향)

  • ;Ohama Yoshihiko;Demura Katsunori
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.713-718
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    • 1998
  • This paper deals with the consistency of fresh lightweight polyester mortars as high-performance or multifunctional building materials. Fresh lightweight polyester mortars using an unsaturated polyester resin, lightweight fillers and aggregate are mixed with various mix proportions, and tested for slump-flow and slump as a measure of consistency. At 10, 20 and 3$0^{\circ}C$, the influences of mix proportioning factors on the slump-flow and slump of the lightweight polyester mortars are examined, and the empirical equations for the slump predictions are successfully proposed.

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Incombustibility and Freezing-Thawing Resistance of Lightweight Polymer Concrete (경량 폴리머 콘크리트의 난연성 및 동결융해 저항성)

  • 채경희;최예환;연규석;이윤수;주명기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.1
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    • pp.45-54
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    • 2003
  • The effects of binder content and silica sand content on the durability characteristics of lightweight polymer concretes are examined. As a result, the flame lingering times using unsaturated polyester resin and non-combustible polyester resin were 60∼120 and 0∼4 seconds respectively, and the combustion lengths were 9∼11 mm and 0∼3 mm, respectively. Thus it is believed that the lightweight polymer concrete was incombustible and the light weight polymer concrete in which non-combustible material was added was perfectly non-combustible. The percent of original mass of lightweight polymer concrete, according to the freezing-thawing experiment, was below 0.3 %, which was much less than that of cement concrete. The pluse velocity, for the case of the binder content 28 %, showed the minimum decreasing rate for the lightweight polymer concrete with silica sand content of 50 %. The higher the binder content, the greater the durability. That is much higher than other material and believed that the freezing-thawing was suppressed by a low absorption.

An Experimental Study on the Mechanical Properties of Steel Fiber Reinforced Fly Ash.Polyester Resin Composites (강섬유 보강 플라이애쉬.폴리에스터 수지복합체의 역학적 특성에 관한 실험적 연구)

  • 박승범;조영찬
    • Magazine of the Korea Concrete Institute
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    • v.5 no.4
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    • pp.156-166
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    • 1993
  • The results of an experimental study on the manufacture and the mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products(fly ash) are presented in this paper. The composites using steel fiber, fly ash, unsaturated polyester resin, styrene monomer, catalyst (cobalt octate) and accelerator(methyl ethyl ketone peroxide), fine and coarse aggreates were prepared using various mixing conditions. As the test results show. the mechanical and physical properties, such as the compressive, tensile and flexural strengths, and the setting shrinkage of fly ash$\cdot$polyester resin composites were improved considerably by increasing the fly ash-binder ratio. And the workability of steel fiber reinforced fly ash$\cdot$polyester resin composites was reduced with increasing the fly ash-binder ratio and steel fiber content. Also, the compressive, flexural strength and toughness of the composites were remarkably increased by increasing steel fiber content.